phase-integral method. III. Quantization conditions in the general case expressed in terms of complete elliptic integrals. Numerical illustration

In this paper we take up the quantal two-center problem where the Coulomb centers have arbitrary positive charges. In analogy with the symmetric case, treated in the second paper of this series, we use the knowledge on the quasiclassical dynamics to express the contour integrals in the first- and third-order approximations of the phase-integral quantization conditions, given in the first paper of this series of papers, in terms of complete elliptic integrals. For various values of the distance between these charges the accuracy of the formulas obtained is illustrated by comparison with available numerically exact results.

[1]  M. Lakshmanan,et al.  Quantal two-center Coulomb problem treated by means of the phase-integral method. I. General theory , 2000, nlin/0012055.

[2]  M. Lakshmanan,et al.  Quantal Two-Centre Coulomb Problem treated by means of the Phase-Integral Method II. Quantization Conditions in the Symmetric Case Expressed in Terms of Complete Elliptic Integrals. Numerical Illustration , 2000 .

[3]  Lakshmanan,et al.  Phase-integral approach to quantal two- and three-dimensional isotropic anharmonic oscillators. , 1994, Physical review. A, Atomic, molecular, and optical physics.

[4]  N. Fröman,et al.  Rotation of a rigid diatomic dipole molecule in a homogeneous electric field: I. Schrödinger equation. Quantization conditions according to phase-integral method , 1994, Philosophical Transactions of the Royal Society of London. Series A: Physical and Engineering Sciences.

[5]  M. Lakshmanan,et al.  Phase-integral calculation of the energy levels of a quantal anharmonic oscillator , 1981 .

[6]  M. Lakshmanan,et al.  On the energy levels of an isotropic anharmonic oscillator , 1980 .

[7]  M. P. Strand,et al.  Semiclassical quantization of the low lying electronic states of H2 , 1979 .

[8]  N. Fröman,et al.  On the application of the generalized quantal Bohr-Sommerfeld quantization condition to single-well potentials with very steep walls , 1978 .

[9]  N. F. Lane,et al.  Exact eigenvalues, electronic wavefunctions and their derivatives with respect to the internuclear separation for the lowest 20 states of the HeH2+ molecule , 1977 .

[10]  K. Watson,et al.  Theoretical investigation of the nonadiabatic interactions and the translational factors in proton-hydrogen collisions , 1975 .

[11]  W. Goddard,et al.  Charge-transfer process using the molecular-wave-function approach: The asymmetric charge transfer and excitation in Li + Na+ and Na + Li+ , 1974 .

[12]  R. Piacentini,et al.  Molecular treatment of the He2 +-H collisions , 1974 .

[13]  Paul F. Byrd,et al.  Handbook of elliptic integrals for engineers and scientists , 1971 .

[14]  Y. Prokoshkin,et al.  Measurements of stopped π- meson absorption probability by bound hydrogen nuclei , 1964 .

[15]  V. Soergel,et al.  Determination of the reaction rate piat rest- + p --> pio + n in hydrogenous materials , 1963 .

[16]  W. Pauli Über das Modell des Wasserstoffmolekülions , 1922 .