Tributyltin distribution in the coastal environment of Peninsular Malaysia.

The occurrence of tributyltin (TBT) is reported in the coastal waters of a few selected sites in Peninsular Malaysia. Water, bivalves and sediment samples collected were analysed specifically for TBT using sensitive analytical methods which involved a solvent extraction procedure with appropriate clean-up followed by graphite furnace atomic absorption spectrometric measurements. The levels of TBT in the seawater in unexposed areas were found in the range from <3.4 to 20 ng litre(-1) as compared to coastal areas with high boat and ship activities where TBT levels in seawater were generally above 30 ng litre(-1), with the highest level found at 281.8 ng litre(-1). TBT levels in the tissues of random cockle and soft-shell clam samples from local markets were found in the range from <0.5 to 3.7 ng g(-1) wet weight. The levels of TBT found in green mussel samples both from the market (23.5 ng g(-1) wet weight) and those from a mussel farm (14.2 ng g(-1) wet weight) indicate slight accumulation of TBT. In sediments, TBT levels were found ranging from <0.7 ng g(-1) dry weight in unexposed coastal sites to as high as 216.5 ng g(-1) dry weight for a site within a port area.

[1]  H. Harino,et al.  Simultaneous determination of butyltin and phenyltin compounds in the aquatic environment by gas chromatography , 1992 .

[2]  J. Mckie Determination of total tin and tributyltin in marine biological materials by electrothermal atomic absorption spectrometry , 1987 .

[3]  P. Cusack,et al.  The Industrial Uses of Tin Chemicals , 1985 .

[4]  K. Fent,et al.  PHENYLTINS IN WATER, SEDIMENT, AND BIOTA OF FRESHWATER MARINAS , 1991 .

[5]  P. Quevauviller,et al.  Butyltin distribution in a sediment core from Arcachon harbour (France). , 1994, Environmental pollution.

[6]  P. Seligman,et al.  Degradation of Tributyltin in Marine and Estuarine Waters , 1986, OCEANS '86.

[7]  P. E. Gibbs,et al.  Reproductive Failure in Populations of the Dog-Whelk, Nucella Lapillus, Caused by Imposex Induced by Tributyltin from Antifouling Paints , 1986, Journal of the Marine Biological Association of the United Kingdom.

[8]  G. Olson,et al.  Determination of DI- and Tributyltin in Sediment and Microbial Biofilms Using Acidified Methanol Extraction, Sodium Borohydride Derivatization and Gas Chromatography with Flame Photometric Detection , 1989 .

[9]  L. Hall,et al.  Acute and sublethal effects of organotin compounds on aquatic biota: an interpretative literature evaluation. , 1985, Critical reviews in toxicology.

[10]  P. Quevauviller,et al.  Variability of butyltin determination in water and sediment samples from European coastal environments , 1990 .

[11]  P. Parrish,et al.  Bioaccumulation and Chronic Toxicity of Bis(tributyltin) Oxide (TBTO): Tests with a Saltwater Fish , 1981 .

[12]  M. Depledge,et al.  Accumulation of organotin in Littorina littorea and Mya arenaria from Danish coastal waters. , 1994, Environmental pollution.

[13]  W. Cullen,et al.  The quantitation of butyltin and cyclohexyltin compounds in the marine environment of British Columbia , 1990 .

[14]  P. E. Gibbs,et al.  Nassarius reticulatus (Nassariidae: Gastropoda) as an indicator of tributyltin pollution before and after TBT restrictions , 1993, Journal of the Marine Biological Association of the United Kingdom.

[15]  M. Gardner,et al.  Determination of organotins in natural waters by toluene extraction and graphite furnace AAS. , 1988, Talanta.

[16]  P. E. Gibbs,et al.  The Decline of the Gastropod Nucella Lapillus Around South-West England: Evidence for the Effect of Tributyltin from Antifouling Paints , 1986, Journal of the Marine Biological Association of the United Kingdom.

[17]  Peter F. Seligman,et al.  Distribution and fate of tributyltin in the United States marine environment , 1989 .

[18]  M. Astruc,et al.  Butyltin pollution in surface sediments of arcachon bay after ten years of restricted use of TBT ‐ based paints , 1991 .

[19]  M. Andreae,et al.  Determination of butyltin compounds in sediments using an improved aqueous ethylation method. , 1994, Talanta.

[20]  R. James Maguire Environmental aspects of tributyltin , 1987 .

[21]  J. Gómez-Ariza,et al.  Simultaneous speciation of butyltin and phenyltin compounds in the waters of south-west Spain. , 1992, The Analyst.

[22]  I. Davies,et al.  Accumulation of total tin and tributyltin in muscle tissue of farmed Atlantic salmon , 1987 .

[23]  M. Borel,et al.  Monitoring and assessement of butyltins in Atlantic coastal waters , 1989 .

[24]  J. E. Thain,et al.  Shell thickening in Crassostrea gigas: Organotin antifouling or sediment induced? , 1983 .

[25]  R. Laane,et al.  Butyltins in marine waters of The Netherlands in 1988 and 1989; Concentrations and effects , 1991 .

[26]  J. D. Paul,et al.  Accumulation of tin and tributyltin from anti-fouling paint by cultivated scallops (Pecten maximus) and Pacific oysters (Crassostrea gigas) , 1986 .

[27]  D. Smith,et al.  Determination of tributyltin in tissues and sediments by graphite furnace atomic absorption spectrometry. , 1988, Analytical chemistry.

[28]  R. Maguire,et al.  Degradation of the tri-n-butyltin species in water and sediment from Toronto Harbor , 1985 .

[29]  W. Langston,et al.  Tin and organotin in water, sediments, and benthic organisms of Poole Harbour , 1987 .

[30]  M. E. Waite,et al.  Inputs of tbt to the marine environment from shipping activity in the U.K. , 1988 .

[31]  R. Huggett,et al.  Measurement of tributyltin contamination of sediments and Crassostrea virginica in the southern chesapeake bay , 1993 .

[32]  M. Astruc,et al.  Extraction and determination of butylin compounds in shellfish by hydride generation—gas chromatography—quartz furnace atomic absorption spectrometry , 1994 .

[33]  M. Ochsenkühn-Petropoulou,et al.  Electrochemical speciation of organotin compounds in water and sediments. Application to sea water after ion-exchange separation , 1992 .