论文信息 - The mass spectra of (trimethylstannyl)x methanes: Occurrence of tin‐carbon double bonds

The mass spectra of (trimethylstannyl)x methanes: Occurrence of tin‐carbon double bonds

The mass spectra of (Me3Sn)nCH4−n, where n varies from 1 to 4, (Me3Sn)2CClX, where X equals H, Cl, Br or I, together with some tetraalkyltin compounds and Me3SnCCl3, are presented. Comparisons with mass spectra of the silicon analogs1 show a large number of similarities, including the appearance of allylic ions which require Group IV metal to carbon π-bonding. Multiple rearrangements are observed with the halogenated tin compounds which bring the α-halogen into direct bonding with the tin atom.

C. A. Wilkie | P. Lamothe | D. Dimmel

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