Frequency down-conversion of solid-state laser sources to the mid-infrared spectral range using non-oxide nonlinear crystals

Abstract The development of parametric devices down-converting the laser frequency to the mid-infrared (3–30 µm) based on non-oxide nonlinear optical crystals is reviewed. Such devices, pumped by solid-state laser systems operating in the near-infrared, fill in this spectral gap where no such lasers exist, on practically all time scales, from continuous-wave to femtosecond regime. All important results obtained so far with difference-frequency generation, optical parametric oscillation, generation and amplification are presented in a comparative manner, illustrating examples of recent achievements are given in more detail, and some special issues such as continuum and frequency comb generation or pulse shaping are also discussed. The vital element in any frequency-conversion process is the nonlinear optical crystal and this represents one of the major limitations for achieving high energies and average powers in the mid-infrared although the broad spectral tunability seems not to be a problem. Hence, an overview of the available non-oxide nonlinear optical materials, emphasizing new developments such as wide band-gap, engineered (mixed), and quasi-phase-matched crystals, is also included.