The Quarter-Century Anniversary of Carbon Nanotube Research.

Nanotube Research In the 25 years since the 1991 report on helical nanotubes of carbon by Dr. Sumio Iijima, carbon nanotubes (CNTs), the nanoscale tubules composed of sp carbon networks, have been one of the most intensively studied materials. On November 15−18, 2016, the International Symposium on Carbon Nanotube in Commemoration of its Quarter-Century Anniversary (CNT25) was held in Tokyo, Japan. Over 350 participants from the Americas, Asia-Pacific, and Europe attended this 4 day symposium to celebrate the 25 year anniversary and discuss the past, present, and future of carbon nanotube research as well as the development of industrial applications. Three keynote lectures (by Sumio Iijima, Morinobu Endo, and Steven Louie), 40 invited talks, and ca. 60 posters covered most of the active topics in CNT research and development from the preparation and handling (synthesis, sorting, dispersing, and filling), characterization (spectroscopy and electron microscopy), and property (electronic, optical, quantum, mechanical, and magnetic) to applications (electronics, energy, composites, and biomedicine) and safety. A deeper understanding of the role of catalysts shines a ray of light toward the structure-controlled synthesis of single-walled CNTs (SWNTs). Although the sorting of SWNTs is evolving from chirality-dependent toward handedness-dependent separations, transmission electron microscopybased techniques have become increasingly powerful and reach atomic resolution for various carbon-based structures. Singlewalled CNTs have shown great potential in future electronics and optoelectronics, particularly flexible devices, and CNT-based hybrid materials and systems are promising in energy and sustainability related applications.

[1]  E. S. Kim,et al.  Carbon Nanotube Macroelectronics for Active Matrix Polymer-Dispersed Liquid Crystal Displays. , 2016, ACS nano.

[2]  Rafael Yuste,et al.  Nanotools for neuroscience and brain activity mapping. , 2013, ACS nano.

[3]  M. Pasquali,et al.  Continuous and scalable fabrication of transparent conducting carbon nanotube films. , 2009, ACS nano.

[4]  Nripan Mathews,et al.  Laminated carbon nanotube networks for metal electrode-free efficient perovskite solar cells. , 2014, ACS nano.

[5]  R. Krupke,et al.  Length-Sorted, Large-Diameter, Polyfluorene-Wrapped Semiconducting Single-Walled Carbon Nanotubes for High-Density, Short-Channel Transistors. , 2016, ACS nano.

[6]  Husam N. Alshareef,et al.  Symmetrical MnO2-carbon nanotube-textile nanostructures for wearable pseudocapacitors with high mass loading. , 2011, ACS nano.

[7]  Wenqing Zhang,et al.  Enhanced thermoelectric performance of single-walled carbon nanotubes/polyaniline hybrid nanocomposites. , 2010, ACS nano.

[8]  Hongjie Dai,et al.  Supramolecular Chemistry on Water- Soluble Carbon Nanotubes for Drug Loading and Delivery , 2007 .

[9]  Yihe Zhang,et al.  Sulfur Embedded in a Mesoporous Carbon Nanotube Network as a Binder-Free Electrode for High-Performance Lithium-Sulfur Batteries. , 2016, ACS nano.

[10]  James F Rusling,et al.  Targeted killing of cancer cells in vivo and in vitro with EGF-directed carbon nanotube-based drug delivery. , 2009, ACS nano.

[11]  Phaedon Avouris,et al.  Thin film nanotube transistors based on self-assembled, aligned, semiconducting carbon nanotube arrays. , 2008, ACS nano.

[12]  Y. Shao-horn,et al.  Carbon nanotube/manganese oxide ultrathin film electrodes for electrochemical capacitors. , 2010, ACS nano.

[13]  Thomas D Young,et al.  Tools for the Microbiome: Nano and Beyond. , 2015, ACS nano.

[14]  Anusorn Kongkanand,et al.  Electron storage in single wall carbon nanotubes. Fermi level equilibration in semiconductor-SWCNT suspensions. , 2007, ACS nano.

[15]  W. Haensch,et al.  Toward high-performance digital logic technology with carbon nanotubes. , 2014, ACS nano.

[16]  Jinyong Wang,et al.  Why single-walled carbon nanotubes can be dispersed in imidazolium-based ionic liquids. , 2008, ACS nano.

[17]  G. Hu,et al.  Formation of active sites for oxygen reduction reactions by transformation of nitrogen functionalities in nitrogen-doped carbon nanotubes. , 2012, ACS nano.

[18]  Yi Shi,et al.  Preparation and characterization of flexible asymmetric supercapacitors based on transition-metal-oxide nanowire/single-walled carbon nanotube hybrid thin-film electrodes. , 2010, ACS nano.

[19]  A. Khademhosseini,et al.  Carbon-nanotube-embedded hydrogel sheets for engineering cardiac constructs and bioactuators. , 2013, ACS nano.

[20]  N. Lee,et al.  Stretchable, Transparent, Ultrasensitive, and Patchable Strain Sensor for Human-Machine Interfaces Comprising a Nanohybrid of Carbon Nanotubes and Conductive Elastomers. , 2015, ACS nano.

[21]  S. Iijima Helical microtubules of graphitic carbon , 1991, Nature.

[22]  Xuan Cao,et al.  Fully Screen-Printed, Large-Area, and Flexible Active-Matrix Electrochromic Displays Using Carbon Nanotube Thin-Film Transistors. , 2016, ACS nano.

[23]  Sang-Gook Kim,et al.  Extremely Elastic Wearable Carbon Nanotube Fiber Strain Sensor for Monitoring of Human Motion. , 2015, ACS nano.

[24]  Yang Xu,et al.  Cytotoxicity effects of graphene and single-wall carbon nanotubes in neural phaeochromocytoma-derived PC12 cells. , 2010, ACS nano.

[25]  A Scott,et al.  LEARNING TO LOVE CO2 , 2015 .