CO2 Technology Platform: An Important Tool for Environmental Problem Solving.

CO2 is a good solvent for many substances when compressed into its liquid or supercritical fluid state. Above the critical temperature and critical pressure (Tc =31 °C, Pc =73.8 bar, see Figure 1 for the phase diagram for CO2 ), CO2 has both gaslike viscosities and liquidlike densities. These moderate critical conditions allow CO2 to be used within safe commercial and laboratory operating conditions. Small changes in temperature and pressure cause dramatic changes in the density, viscosity, and dielectric properties of CO2 , making it a tunable solvent that can be tailored for various applications. Combined, these unique properties make CO2 a "solvent of choice" for the new millennium.

[1]  J. B. Cain,et al.  High-Pressure NMR of Polymers Dissolved in Supercritical Carbon Dioxide , 1997 .

[2]  John A. Hyatt,et al.  Liquid and supercritical carbon dioxide as organic solvents , 1984 .

[3]  J. DeSimone,et al.  Synthesis of poly(2,6-dimethylphenylene oxide) in carbon dioxide , 1996 .

[4]  J. DeSimone,et al.  Precipitation Polymerization of Acrylic Acid in Supercritical Carbon Dioxide , 1995 .

[5]  E. Beckman,et al.  Effect of structure on the cloud-point curves of silicone-based amphiphiles in supercritical carbon dioxide , 1993 .

[6]  Dean W. Matson,et al.  Rapid expansion of supercritical fluid solutions: solute formation of powders, thin films, and fibers , 1987 .

[7]  Shuiqin Zhou,et al.  Self-Assembly Behavior of a Diblock Copolymer of Poly(1,1-dihydroperfluorooctyl acrylate) and Poly(vinyl acetate) in Supercritical Carbon Dioxide , 1998 .

[8]  M. Z. Yates,et al.  Ambidextrous surfactants for water-dispersible polymer powders from dispersion polymerization in supercritical CO2 , 1999 .

[9]  Z. Guan,et al.  Synthesis of Fluoropolymers in Supercritical Carbon Dioxide , 1992, Science.

[10]  Masatoshi Yoshida,et al.  Role of initiator‐transfer agent‐terminator (iniferter) in radical polymerizations: Polymer design by organic disulfides as iniferters , 1982 .

[11]  D. Canelas,et al.  Dispersion polymerizations in carbon dioxide using siloxane-based stabilizers , 1996 .

[12]  D. Canelas,et al.  Dispersion Polymerization of Styrene in Supercritical Carbon Dioxide: Importance of Effective Surfactants , 1996 .

[13]  L. Helmick,et al.  Determination of the thermal stability of perfluoropolyalkyl ethers by tensimetry , 1992 .

[14]  E. Beckman,et al.  Highly carbon dioxide soluble surfactants, dispersants and chelating agents , 1996 .

[15]  J. DeSimone,et al.  Dispersion Polymerizations in Supercritical Carbon Dioxide , 1994, Science.

[16]  K. Matyjaszewski,et al.  Atom Transfer Radical Polymerization in Supercritical Carbon Dioxide , 1999 .

[17]  Dorian A. Canelas,et al.  Solution properties of a CO2-soluble fluoropolymer via small angle neutron scattering , 1996 .

[18]  Joseph M. DeSimone,et al.  Synthesis of Tetrafluoroethylene-Based, Nonaqueous Fluoropolymers in Supercritical Carbon Dioxide , 1995 .

[19]  E. Beckman,et al.  Crystallization of bisphenol a polycarbonate induced by supercritical carbon dioxide , 1987 .

[20]  E. Beckman,et al.  The incorporation of a fluorinated ether functionality into a polymer or surfactant to enhance C02-solubility , 1992 .

[21]  M. McHugh,et al.  Dissolving Perfluoropolymers in Supercritical Carbon Dioxide , 1995 .

[22]  H. D. Cochran,et al.  The Morphology of Block Copolymer Micelles in Supercritical Carbon Dioxide by Small-Angle Neutron and X-ray Scattering , 1997 .

[23]  M. Collins,et al.  A model solution for tracking pollution , 1994 .

[24]  J. DeSimone,et al.  Dispersion Polymerization of 1-Vinyl-2-pyrrolidone in Supercritical Carbon Dioxide , 2000 .

[25]  James W. Elkins,et al.  Decline in the Tropospheric Abundance of Halogen from Halocarbons: Implications for Stratospheric Ozone Depletion , 1996, Science.

[26]  Krzysztof Matyjaszewski,et al.  Polymers with Very Low Polydispersities from Atom Transfer Radical Polymerization , 1996, Science.

[27]  J. DeSimone,et al.  Light-Scattering Study of Diblock Copolymers in Supercritical Carbon Dioxide: CO2 Density-Induced Micellization Transition , 1998 .

[28]  Joseph M. DeSimone,et al.  Critical micelle density for the self-assembly of block copolymer surfactants in supercritical carbon dioxide , 2000 .

[29]  M. Z. Yates,et al.  Poly(vinyl acetate) and poly(vinyl acetate-co-ethylene) latexes via dispersion polymerizations in carbon dioxide , 1998 .

[30]  R. Steiner Carbon dioxide's expanding role , 1993 .

[31]  K. Johnston,et al.  Glass transitions of polymers with compressed fluid diluents : type II and III behavior , 1994 .

[32]  J. DeSimone,et al.  Free-radical telomerization of tetrafluoroethylene in supercritical carbon dioxide , 1995 .

[33]  E. Samulski,et al.  Fluorocarbons Dissolved in Supercritical Carbon Dioxide. NMR Evidence for Specific Solute−Solvent Interactions , 1998 .

[34]  Pablo G. Debenedetti,et al.  Effects of process conditions on crystals obtained from supercritical mixtures , 1989 .

[35]  H. D. Cochran,et al.  Neutron scattering characterization of homopolymers and graft-copolymer micelles in supercritical carbon dioxide , 1995 .

[36]  W. Chen,et al.  Solid-liquid separation via filtration , 1997 .

[37]  K. Johnston,et al.  Dispersion Polymerization of Methyl Methacrylate Stabilized with Poly(1,1-dihydroperfluorooctyl acrylate) in Supercritical Carbon Dioxide , 1995 .

[38]  S. Saito,et al.  Density dependence of the molar absorption coefficient—Application of the beer-lambert law to supercritical C02—Naphthalene mixture , 1993 .

[39]  Dorian A. Canelas,et al.  Design of Nonionic Surfactants for Supercritical Carbon Dioxide , 1996, Science.

[40]  R. Carbonell,et al.  Supercritical CO2 as a solvent for polymeric stone protective materials , 1999 .

[41]  F. Diaz,et al.  Polymerization by phase transfer catalysis—5. Polycarbonates from diphenols with aromatic side groups , 1987 .

[42]  Mark A. McHugh,et al.  Solubility of Polymers and Copolymers in Supercritical CO2 , 1996 .

[43]  C. Manke,et al.  Thermodynamics of Polymer Melts Swollen with Supercritical Gases , 1994 .

[44]  K. Johnston,et al.  Formation of poly(1,1,2,2-tetrahydroperfluorodecyl acrylate) submicron fibers and particles from supercritical carbon dioxide solutions , 1995 .

[45]  J. DeSimone,et al.  Solid-State Polymerization of Polycarbonates Using Supercritical CO2 , 1999 .

[46]  K. Johnston,et al.  Solubility of homopolymers and copolymers in carbon dioxide , 1998 .

[47]  B. Wolf,et al.  Solutions of poly(dimethylsiloxane) in supercritical CO2 : viscometric and volumetric behavior , 1994 .

[48]  E. Beckman,et al.  Design of highly CO_2-soluble chelating agents for carbon dioxide extraction of heavy metals , 1995 .