An optimisation approach for increasing the profit of a commercial VGO hydrocracking process

In this paper, an optimisation approach is proposed to increase the profit of a commercial hydrocracking unit called Isomax. To represent the system, a full-lump kinetic model incorporating the flow rate of fresh vacuum gas oil (VGO), bed temperatures, recycle flow rate and the catalyst life is developed. This model is capable of predicting the yield of all products, and it improves with respect to the previous works by considering LPG and light gases, fresh VGO and recycle streams as separate lumps. After developing and validating the model, the profit function of the plant, including the value of the products, fresh feed and hydrogen, as well as energy expenses, is optimised by manipulating the bed temperatures, flow rate of fresh VGO and combined feed ratio (CFR) whilst all process limitations and operating constraints are taken into account. During two years of study and considering all mechanical and operational constraints, the results confirm that the decision variables, generated by the optimisation package, can increase the gross profit of the Isomax process to about 8.17%, which is equal to $5.6 million of net profit annually. © 2012 Canadian Society for Chemical Engineering

[1]  Jorge Ancheyta,et al.  Application of continuous kinetic lumping modeling to moderate hydrocracking of heavy oil , 2009 .

[2]  A. K. Aboul-Gheit Hydrocracking of vacuum gas oil (VGO) for fuels production. II: Reaction kinetics , 1989 .

[3]  Arshad Ahmad,et al.  Rotary cement kiln coating estimator: Integrated modelling of kiln with shell temperature measurement , 2011 .

[4]  Arshad Ahmad,et al.  Comparison of Lumping Approaches to Predict the Product Yield in a Dual Bed VGO Hydrocracker , 2011 .

[5]  Ignacio E. Grossmann,et al.  A simultaneous optimization approach for off-line blending and scheduling of oil-refinery operations , 2006, Comput. Chem. Eng..

[6]  Felipe López-Isunza,et al.  5-Lump kinetic model for gas oil catalytic cracking , 1999 .

[7]  Murray R. Gray,et al.  Kinetics of Hydrocracking and Hydrotreating of Coker and Oilsands Gas Oils , 2003 .

[8]  Surinder Parkash,et al.  Refining Processes Handbook , 2003 .

[9]  E. C. Sanford,et al.  Mild hydrocracking of bitumen-derived coker and hydrocracker heavy gas oils: kinetics, product yields, and product properties , 1989 .

[10]  Jinwen Chen,et al.  Review on criteria to ensure ideal behaviors in trickle-bed reactors , 2009 .

[11]  Haitham M. S. Lababidi,et al.  Optimization study of residuum hydrotreating processes , 2008 .

[12]  Jorge Ancheyta,et al.  Kinetics of asphaltenes conversion during hydrotreating of Maya crude , 2005 .

[13]  Ajay K. Dalai,et al.  Kinetics of Bitumen‐Derived Gas Oil Upgrading Using a Commercial NiMo/Al2O3 Catalyst , 2008 .

[14]  María T. Martínez,et al.  Hydrocracking of a Maya Residue. Kinetics and Product Yield Distributions , 1999 .

[15]  K. S. Balaraman,et al.  A Four Lump Kinetic Model for the Simulation of the Hydrocracking Process , 2005 .

[16]  Jiang Qingyin,et al.  Modeling and simulation for the hydrocracking reactor , 2008, 2008 27th Chinese Control Conference.

[17]  Jorge Ancheyta,et al.  Kinetic modeling of hydrocracking of heavy oil fractions: A review , 2005 .

[18]  G. P. Rangaiah,et al.  First-Principles, Data-Based, and Hybrid Modeling and Optimization of an Industrial Hydrocracking Unit , 2006 .

[19]  Zhikai Cao,et al.  Modeling and optimization of an industrial hydrocracking unit to improve the yield of diesel or kerosene , 2011 .

[20]  Zainuddin Abdul Manan,et al.  Modeling and optimization of an industrial hydrocracker plant , 2011 .

[21]  Arshad Ahmad,et al.  Kinetic Study on a Commercial Amorphous Hydrocracking Catalyst by Weighted Lumping Strategy , 2010 .

[22]  Arshad Ahmad,et al.  6-Lump Kinetic Model for a Commercial Vacuum Gas Oil Hydrocracker , 2010 .

[23]  Guadalupe de la Rosa,et al.  Kinetic and Thermodynamic Modeling of Cd+2 and Ni+2 Biosorption by Raw Chicken Feathers , 2011 .

[24]  S. Pushpavanam,et al.  Model discrimination in hydrocracking of vacuum gas oil using discrete lumped kinetics , 2008 .

[25]  Jasvinder Singh,et al.  Reaction pathways and product yields in mild thermal cracking of vacuum residues: A multi-lump kinetic model , 2005 .

[26]  Jing Guo,et al.  Modeling of trickle-bed reactors with exothermic reactions using cell network approach , 2008 .

[27]  Arshad Ahmad,et al.  4-Lump kinetic model for vacuum gas oil hydrocracker involving hydrogen consumption , 2010 .

[28]  Reginaldo Guirardello,et al.  Hydroconversion kinetics of Marlim vacuum residue , 2005 .