Utilization of Spent Coffee Grounds with Hydrochloric Acid (HCl) as Electrolyte for Bio-Battery Applications

Coffee is a caffeinated beverage that is well known worldwide and its existence continues to grow. Only 10% of coffee is consumed and the rest become spent coffee grounds, previous research has shown that spent coffee grounds can be used as bio-absorbent, bio-diesel and bio-battery. In this study, we will synthesize bio-batteries made from spent coffee ground. This research will treat spent coffee grounds with hydrochloric acid (HCl) at a dilution concentration of 30%, 50%, and 70%, and dried at a temperature of 200°C; 300°C; and 400°C. The result indicated that the variation a HCL dissolution variation of 50% (with combination of all variation of drying) lasted up to 52 days with a maximum power of 0.024 W. Characterization using X-Ray Diffraction (XRD) at variation of 300°C,50% shows peak at 2θ = 28.92°, other variation shows 2θ = 28.32° (200°C,50%), and 2θ = 28.68° (400°C,50%). Morphology of the spent coffee ground (300°C,50%) observed using Scanning Electron Microscope (SEM) EDX, it shows that the structure is in the form of fused flakes like carbon with visible porosity. From these data, spent coffee grounds with treatment of HCl could be considered to be the next-generation electrolyte for batteries in the future.

[1]  Xuecheng Chen,et al.  Study of the Active Carbon from Used Coffee Grounds as the Active Material for a High-Temperature Stable Supercapacitor with Ionic-Liquid Electrolyte , 2020, Materials.

[2]  A. Pugazhendhi,et al.  A review on valorization of spent coffee grounds (SCG) towards biopolymers and biocatalysts production. , 2020, Bioresource technology.

[3]  Chun-Han Guo,et al.  Coffee-Ground-Derived Nanoporous Carbon Anodes for Sodium-Ion Batteries with High Rate Performance and Cyclic Stability , 2020 .

[4]  T. Rojo,et al.  Graphene-coffee waste derived carbon composites as electrodes for optimized lithium ion capacitors , 2020 .

[5]  Arif Surtono,et al.  Analisis Karakteristik Elektrik Onggok Singkong Fermentasi yang Diawetkan sebagai Pasta Bio-Baterai , 2020, Journal of Energy, Material, and Instrumentation Technology.

[6]  P. Sayan,et al.  Assessment of the thermal pyrolysis characteristics and kinetic parameters of spent coffee waste: a TGA-MS study , 2020, Energy Sources, Part A: Recovery, Utilization, and Environmental Effects.

[7]  Gurum Ahmad Pauzi,et al.  Analisis Karakteristik Elektrik Onggok Singkong sebagai Pasta Bio-Baterai , 2019, Jurnal Teori dan Aplikasi Fisika.

[8]  Y. Chueh,et al.  Coffee grounds-derived carbon as high performance anode materials for energy storage applications , 2019, Journal of the Taiwan Institute of Chemical Engineers.

[9]  Hwai Chyuan Ong,et al.  Pyrolysis characteristics and kinetic studies of horse manure using thermogravimetric analysis , 2019, Energy Conversion and Management.

[10]  R. Luque,et al.  Non-porous carbonaceous materials derived from coffee waste grounds as highly sustainable anodes for lithium-ion batteries , 2019, Journal of Cleaner Production.

[11]  T. Lim,et al.  Conversion of Spent Coffee Beans to Electrode Material for Vanadium Redox Flow Batteries , 2018, Batteries.

[12]  Masatoshi Todaka,et al.  Improvement of oxidation stability of biodiesel by an antioxidant component contained in spent coffee grounds , 2018 .

[13]  Deyu Wang,et al.  Pyrolytic carbon derived from spent coffee grounds as anode for sodium-ion batteries , 2018 .

[14]  F. Banat,et al.  Novel magnetic coffee waste nanocomposite as effective bioadsorbent for Pb(II) removal from aqueous solutions , 2018 .

[15]  Michael Kornaros,et al.  Spent coffee grounds make much more than waste: exploring recent advances and future exploitation strategies for the valorization of an emerging food waste stream , 2018 .

[16]  Yu nila,et al.  Pembuatan Bio Baterai Berbahan Dasar Kulit Pisang , 2017 .

[17]  M. Marques,et al.  Impacts of discarded coffee waste on human and environmental health. , 2017, Ecotoxicology and environmental safety.

[18]  Q. Guo,et al.  High capacitive performance of hollow activated carbon fibers derived from willow catkins , 2017 .

[19]  Dongfang Yang,et al.  Biomass derived carbon nanoparticle as anodes for high performance sodium and lithium ion batteries , 2016 .

[20]  Deyu Wang,et al.  Volumetric variation confinement: surface protective structure for high cyclic stability of lithium metal electrodes , 2016 .

[21]  S. Passerini,et al.  Apple‐Biowaste‐Derived Hard Carbon as a Powerful Anode Material for Na‐Ion Batteries , 2016 .

[22]  Hyun‐Joong Chung,et al.  SMART biochar technology—A shifting paradigm towards advanced materials and healthcare research , 2015 .

[23]  P. Savage,et al.  Trash to Treasure: From Harmful Algal Blooms to High-Performance Electrodes for Sodium-Ion Batteries. , 2015, Environmental science & technology.

[24]  M. Ozkan,et al.  Bio-Derived, Binderless, Hierarchically Porous Carbon Anodes for Li-ion Batteries , 2015, Scientific Reports.

[25]  Shouwu Guo,et al.  Sweet potato-derived carbon nanoparticles as anode for lithium ion battery , 2015 .

[26]  Jia Ding,et al.  High-density sodium and lithium ion battery anodes from banana peels. , 2014, ACS nano.

[27]  D. Xiao,et al.  Hierarchically porous nitrogen-rich carbon derived from wheat straw as an ultra-high-rate anode for lithium ion batteries , 2014 .

[28]  Fangfang Sun,et al.  A high-energy-density sugar biobattery based on a synthetic enzymatic pathway , 2014, Nature Communications.

[29]  M. Titirici,et al.  Rice husk-derived carbon anodes for lithium ion batteries , 2013 .

[30]  Philippe Poizot,et al.  Clean energy new deal for a sustainable world: from non-CO2 generating energy sources to greener electrochemical storage devices , 2011 .

[31]  Á. Caballero,et al.  Limitations of disordered carbons obtained from biomass as anodes for real lithium-ion batteries. , 2011, ChemSusChem.

[32]  Á. Caballero,et al.  Improving the Performance of Biomass-Derived Carbons in Li-Ion Batteries by Controlling the Lithium Insertion Process , 2010 .

[33]  J. Goodenough,et al.  Challenges for Rechargeable Li Batteries , 2010 .

[34]  Seong-Ho Yoon,et al.  Microstructure of carbon derived from mangrove charcoal and its application in Li-ion batteries , 2010 .

[35]  P. Bruce,et al.  Nanomaterials for rechargeable lithium batteries. , 2008, Angewandte Chemie.

[36]  M. Torem,et al.  BIOSORPTION OF CADMIUM BY GREEN COCONUT SHELL POWDER , 2006 .

[37]  T. Shibamoto,et al.  Antioxidative activities of fractions obtained from brewed coffee. , 2004, Journal of agricultural and food chemistry.

[38]  Minoru Inaba,et al.  Effects of Some Organic Additives on Lithium Deposition in Propylene Carbonate , 2002 .

[39]  P. M. E. Koffi,et al.  Characterization of rice, coffee and cocoa crops residues as fuel of thermal power plant in Côte d’Ivoire , 2021 .

[40]  K. Hashimoto Global Temperature and Atmospheric Carbon Dioxide Concentration , 2019, Global Carbon Dioxide Recycling.