Cr-based bulk metallic glasses with ultrahigh hardness

This letter reports quaternary Cr-Co-Nb-B bulk metallic glasses (BMGs) with ultrahigh hardness and Young's moduli. Especially, Cr55Co24Nb7B14 BMG exhibits ultrahigh Vickers hardness and Young's modulus of 1605 and 278 GPa, respectively, and the highest specific Young's modulus of 37.0 × 106 N m/kg among all the developed BMGs so far. It is considered that the high hardness and Young's moduli for this kind of BMGs are intrinsically attributed to the strong interactions between metallic constituent elements and B.

[1]  S. Yoda,et al.  Hard metallic glass of tungsten-based alloy , 2004 .

[2]  S. Takeuchi,et al.  Microscopic Mechanism of Plastic Deformation in Metallic Glasses , 1987 .

[3]  Akira Takeuchi,et al.  Classification of Bulk Metallic Glasses by Atomic Size Difference, Heat of Mixing and Period of Constituent Elements and Its Application to Characterization of the Main Alloying Element , 2005 .

[4]  A. Inoue,et al.  FeNi-based bulk glassy alloys with superhigh mechanical strength and excellent soft-magnetic properties , 2006 .

[5]  A. Takeuchi,et al.  Bulk amorphous alloys with high mechanical strength and good soft magnetic properties in Fe–TM–B (TM=IV–VIII group transition metal) system , 1997 .

[6]  A. Inoue,et al.  Superhigh strength and good soft-magnetic properties of (Fe,Co)–B–Si–Nb bulk glassy alloys with high glass-forming ability , 2004 .

[7]  C. Liu,et al.  A new glass-forming ability criterion for bulk metallic glasses , 2002 .

[8]  S. Takeuchi,et al.  Fabrication of refractory metal based metallic glasses , 2007 .

[9]  C. Liu,et al.  Structural amorphous steels. , 2004, Physical review letters.

[10]  A. Inoue,et al.  Crystallization Temperature and Hardness of New Chromium-Based Amorphous Alloys , 1979 .

[11]  Y. Golovin,et al.  Serrated plastic flow during nanoindentation of a bulk metallic glass , 2001 .

[12]  Y. Li,et al.  Ductile Fe-Nb-B bulk metallic glass with ultrahigh strength , 2008 .

[13]  Tao Zhang,et al.  Co-based ternary bulk metallic glasses with ultrahigh strength and plasticity , 2011 .

[14]  W. Johnson,et al.  Structure and properties of transition-metal-metalloid glasses based on refractory metals , 1979 .

[15]  Robert O Ritchie,et al.  A damage-tolerant glass. , 2011, Nature materials.

[16]  D. Turnbull Under what conditions can a glass be formed , 1969 .

[17]  A. Yavari,et al.  Cobalt-based bulk glassy alloy with ultrahigh strength and soft magnetic properties , 2003, Nature materials.

[18]  A. Inoue Stabilization of metallic supercooled liquid and bulk amorphous alloys , 2000 .

[19]  A. Inoue,et al.  Enhancement of the fracture strength and glass-forming ability of CoFeTaB bulk glassy alloy , 2005, Journal of physics. Condensed matter : an Institute of Physics journal.

[20]  Gang Wang,et al.  Super Plastic Bulk Metallic Glasses at Room Temperature , 2007, Science.

[21]  Weihua Wang The elastic properties, elastic models and elastic perspectives of metallic glasses , 2012 .

[22]  J. Schroers,et al.  Critical cooling rate and thermal stability of Zr–Ti–Cu–Ni–Be alloys , 2001 .