N2O production by high energy auroral electron precipitation

[1] The Fourier transform spectrometer on SCISAT-1 observed enhanced concentrations of N2O above 50 km in February of 2004 and 2006 in the wintertime polar region. These anomalously high concentrations are associated with the transport of high levels of NOx in the polar night region from the upper mesosphere and lower thermosphere in both cases following sudden warming events in the middle of January. The NOx is produced by auroral electron precipitation. Simulations using a middle atmosphere chemistry climate model show significant amounts of N2O are produced in the upper mesosphere from the reaction of NO2 and ground state atomic nitrogen. Thus, N2O acts as a signature of energetic electron precipitation. The model results exhibit polar-night-confined descent of NOx in the wake of sudden warmings and other dynamical regimes when the polar vortex intensifies at high latitudes in the mesosphere.

[1]  T. Clarmann,et al.  Enhancement of N 2 O during the October–November 2003 solar proton events , 2008 .

[2]  M. Schlesinger,et al.  Atmospheric response to NOy source due to energetic electron precipitation , 2005 .

[3]  P. Bernath,et al.  Enhanced NOx in 2006 linked to strong upper stratospheric Arctic vortex , 2006 .

[4]  J. Zawodny,et al.  Stratospheric effects of energetic particle precipitation in 2003–2004 , 2005 .

[5]  J. Fyfe,et al.  Arctic polar vortex variability in the Canadian middle atmosphere model , 2001 .

[6]  A. Hedin Extension of the MSIS Thermosphere Model into the middle and lower atmosphere , 1991 .

[7]  Guy Brasseur,et al.  Aeronomy of the Middle Atmosphere: Chemistry and Physics of the Stratosphere and Mesosphere , 1984 .

[8]  Peter F. Bernath,et al.  Atmospheric chemistry experiment (ACE): mission overview , 2004, SPIE Optics + Photonics.

[9]  Manuel López-Puertas,et al.  Enhancement of N2O during the October–November 2003 solar proton events , 2008 .

[10]  Paul J. Crutzen,et al.  Photochemical coupling between the thermosphere and the lower atmosphere: 1. Odd nitrogen from 50 to 120 km , 1982 .

[11]  D. Weisenstein,et al.  Kinetics of reactions of ground state nitrogen atoms (4S3/2) with NO and NO2 , 1994 .

[12]  L. Callis Odd nitrogen formed by energetic electron precipitation as calculated from TIROS data , 1997 .

[13]  A. J. Miller,et al.  Downward-Propagating Temperature Anomalies in the Preconditioned Polar Stratosphere. , 2002 .

[14]  Kevin Hamilton,et al.  Middle Atmosphere Simulated with High Vertical and Horizontal Resolution Versions of a GCM: Improvements in the Cold Pole Bias and Generation of a QBO-like Oscillation in the Tropics , 1999 .

[15]  Y. Ono,et al.  Determination of the rate constant of reaction of ground-state CI and H atoms with H2S using resonance fluorescence in a discharge flow , 1983 .

[16]  K. Krüger,et al.  The remarkable 2003–2004 winter and other recent warm winters in the Arctic stratosphere since the late 1990s , 2005 .

[17]  J. Holton,et al.  The Role of Gravity Wave Induced Drag and Diffusion in the Momentum Budget of the Mesosphere , 1982 .

[18]  Robert H. Holzworth,et al.  Mathematical representation of the auroral oval , 1975 .

[19]  J. MacDougall,et al.  Winter warmings, tides and planetary waves: comparisions between CMAM (with interactive chemistry) and MFR-MetO observations and data , 2006 .

[20]  J. C. McConnell,et al.  Simulation of the October–November 2003 solar proton events in the CMAM GCM: Comparison with observations , 2005 .

[21]  J. Gledhill The range-energy relation for 0.1-600 keV electrons , 1973 .

[22]  C. Brühl,et al.  Multimodel projections of stratospheric ozone in the 21st century , 2007 .

[23]  L. Polvani,et al.  A New Look at Stratospheric Sudden Warmings. Part II: Evaluation of Numerical Model Simulations , 2007 .

[24]  Paul J. Crutzen,et al.  The effect of particle precipitation events on the neutral and ion chemistry of the middle atmosphere: II. Odd hydrogen , 1981 .

[25]  D. Baker,et al.  An extreme distortion of the Van Allen belt arising from the ‘Hallowe'en’ solar storm in 2003 , 2004, Nature.

[26]  D. Keuer,et al.  Variability of the mesospheric wind field at middle and Arctic latitudes in winter and its relation to stratospheric circulation disturbances , 2002 .

[27]  C. McLandress,et al.  The GCM Response to Current Parameterizations of Nonorographic Gravity Wave Drag , 2005 .

[28]  C. Rodger,et al.  Ionospheric evidence of thermosphere‐to‐stratosphere descent of polar NOX , 2006 .

[29]  James M. Russell,et al.  The evolution of the stratopause during the 2006 major warming: Satellite data and assimilated meteorological analyses , 2008 .

[30]  J. Russell,et al.  Large increase of NO2 in the north polar mesosphere in January–February 2004: Evidence of a dynamical origin from GOMOS/ENVISAT and SABER/TIMED data , 2007 .

[31]  T. Shepherd,et al.  Response of the Middle Atmosphere to CO2 Doubling: Results from the Canadian Middle Atmosphere Model , 2007 .

[32]  Florian A. Potra,et al.  The kinetic preprocessor KPP*/a software environment for solving chemical kinetics , 2002 .

[33]  J. C. McConnell,et al.  Doubled CO2‐induced cooling in the middle atmosphere: Photochemical analysis of the ozone radiative feedback , 2004 .

[34]  D. Baker,et al.  Solar atmospheric coupling by electrons (SOLACE): 2. Calculated stratospheric effects of precipitating electrons, 1979–1988 , 1998 .

[35]  K. Labitzke Temperature Changes in the Mesosphere and Stratosphere Connected with Circulation Changes in Winter , 1972 .

[36]  Y. Ono,et al.  Determination of the rate constant of reaction of N(4S32) with NO2 using resonance fluorescence in a discharge flow system , 1982 .