On the Origin of Living Polymerization over o-Fluorinated Post-titanocene Catalysts

[1]  H. Möller,et al.  The origin of living polymerization with an o-fluorinated catalyst: NMR spectroscopic characterization of chain-carrying species. , 2012, Chemistry.

[2]  N. Zhu,et al.  Scalar coupling across [C-H···F-C] interactions in (σ-aryl)-chelating post-metallocenes. , 2012, Chemistry.

[3]  V. Villani,et al.  Fluorine Interactions in a Post‐Metallocene Titanium Catalyst: An ab initio Study , 2011 .

[4]  H. Terao,et al.  FI catalysts for olefin polymerization--a comprehensive treatment. , 2011, Chemical reviews.

[5]  H. Möller,et al.  Noncovalent Interactions in o-Fluorinated Post-titanocene Living Ethylene Polymerization Catalyst , 2010 .

[6]  M. Białek Effect of catalyst composition on chain‐end‐group of polyethylene produced by salen‐type complexes of titanium, zirconium, and vanadium , 2010 .

[7]  Xiulan Xie,et al.  Conformational dynamics of bis(BF2)‐2,2′‐bidipyrrins revealed by through‐space 13C19F and 19F19F couplings , 2009, Magnetic resonance in chemistry : MRC.

[8]  T. Fujita,et al.  Development and application of FI catalysts for olefin polymerization: unique catalysis and distinctive polymer formation. , 2009, Accounts of chemical research.

[9]  Z. Guan,et al.  Nickel(II) and Palladium(II) Polymerization Catalysts Bearing a Fluorinated Cyclophane Ligand: Stabilization of the Reactive Intermediate(1) , 2009 .

[10]  S. Mecking,et al.  Extremely narrow-dispersed high molecular weight polyethylene from living polymerization at elevated temperatures with o-F substituted Ti enolatoimines. , 2008, Journal of the American Chemical Society.

[11]  M. C. Chan Weak attractive ligand-polymer and related interactions in catalysis and reactivity: impact, applications, and modeling. , 2008, Chemistry, an Asian journal.

[12]  G. Coates,et al.  Living alkene polymerization : New methods for the precision synthesis of polyolefins , 2007 .

[13]  E. P. Talsi,et al.  Activation of Bis(pyrrolylaldiminato) and (Salicylaldiminato)(pyrrolylaldiminato) Titanium Polymerization Catalysts with Methylalumoxane , 2007 .

[14]  I. Agranat,et al.  The Effects of Fluorine and Chlorine Substituents across the Fjords of Bifluorenylidenes: Overcrowding and Stereochemistry , 2006 .

[15]  R. Grubbs,et al.  Rate acceleration in olefin metathesis through a fluorine-ruthenium interaction. , 2006, Journal of the American Chemical Society.

[16]  G. McIntyre,et al.  Neutron and X-ray diffraction and spectroscopic investigations of intramolecular [C-H...F-C] contacts in post-metallocene polyolefin catalysts: modeling weak attractive polymer-ligand interactions. , 2006, Chemistry.

[17]  M. Mitani,et al.  Fluorinated bis(phenoxy–imine) Ti complexes with MAO: Remarkable catalysts for living ethylene and syndioselective living propylene polymerization , 2005 .

[18]  E. P. Talsi,et al.  Active Intermediates in Ethylene Polymerization over Titanium Bis(phenoxyimine) Catalysts , 2005 .

[19]  K. Takai,et al.  Synthesis of bis(phenoxyimine) Ti alkyl complexes and observation of living species by 1H nmr spectroscopy , 2005 .

[20]  M. Leskelä,et al.  Bis(salicylaldiminato)titanium Complexes Containing Bulky Imine Substituents: Synthesis, Characterization and Ethene Polymerization Studies , 2005 .

[21]  T. Braun,et al.  C-F or C-H bond activation and C-C coupling reactions of fluorinated pyridines at rhodium: synthesis, structure and reactivity of a variety of tetrafluoropyridyl complexes. , 2004, Dalton transactions.

[22]  L. Cavallo,et al.  Living propene polymerization with bis(phenoxyimine) group 4 metal catalysts: New strategies and old concepts , 2004 .

[23]  G. Britovsek,et al.  Iron catalyzed polyethylene chain growth on zinc: a study of the factors delineating chain transfer versus catalyzed chain growth in zinc and related metal alkyl systems. , 2004, Journal of the American Chemical Society.

[24]  T. Fujita,et al.  Observation and identification of the catalytically active species of bis(phenoxy-imine) group 4 transition metal complexes for olefin polymerization using 1H NMR spectroscopy , 2004 .

[25]  H. Terao,et al.  FI catalysts: new olefin polymerization catalysts for the creation of value-added polymers. , 2004, Chemical record.

[26]  R. Schrock,et al.  Zirconium and Hafnium Complexes that Contain the Electron-Withdrawing Diamido/Donor Ligands [(2,6-X2C6H3NCH2)2C(2-C5H4N)(CH3)]2- (X = Cl or F). An Evaluation of the Role of Ortho Halides in 1-Hexene Polymerization , 2003 .

[27]  T. Nakano,et al.  Unprecedented living olefin polymerization derived from an attractive interaction between a ligand and a growing polymer chain. , 2003, Chemistry.

[28]  M. Mitani,et al.  Ethylene and propylene polymerization behavior of a series of bis(phenoxy–imine)titanium complexes , 2003 .

[29]  N. Zhu,et al.  Observation of intramolecular C-H..F-C contacts in non-metallocene polyolefin catalysts: model for weak attractive interactions between polymer chain and noninnocent ligand. , 2003, Angewandte Chemie.

[30]  V. C. Gibson,et al.  Advances in non-metallocene olefin polymerization catalysis. , 2003, Chemical reviews.

[31]  G. Coates,et al.  Catalysts for the living insertion polymerization of alkenes: access to new polyolefin architectures using Ziegler-Natta chemistry. , 2002, Angewandte Chemie.

[32]  N. Kashiwa,et al.  FI Catalysts: A New Family of High Performance Catalysts for Olefin Polymerization , 2002 .

[33]  T. Nakano,et al.  Living polymerization of ethylene catalyzed by titanium complexes having fluorine-containing phenoxy-imine chelate ligands. , 2002, Journal of the American Chemical Society.

[34]  N. Kashiwa,et al.  Living Polymerization of Ethylene with a Titanium Complex Containing Two Phenoxy-Imine Chelate Ligands. , 2001, Angewandte Chemie.

[35]  G. Coates,et al.  A new catalyst for highly syndiospecific living olefin polymerization: homopolymers and block copolymers from ethylene and propylene. , 2001, Journal of the American Chemical Society.

[36]  M. Szwarc Living polymers. Their discovery, characterization, and properties , 1998 .

[37]  R. Fröhlich,et al.  Internal Fluorocarbon Coordination as a Tool for the Protection of Active Catalytic Sites: Experimental Characterization of the Zr···F−C Interaction in the Group 4 Metallocene(butadiene)/B(C6F5)3 Betaine Ziegler Catalyst Systems , 1997 .

[38]  A. Mele,et al.  Through‐Space 7JHF and 6JCF Spin–Spin Couplings in 2′,3′‐Dideoxy‐4′‐fluoroalkylnucleosides. The Role of Sugar Ring Conformation and Solvent Effect , 1997 .

[39]  M. Mcpartlin,et al.  Tripodal amido-titanium and -zirconium complexes containing a trisilylsilane-derived ligand framework , 1996 .

[40]  L. Gade,et al.  TRIPODAL AMIDO LIGANDS CONTAINING AN ACTIVE LIGAND PERIPHERY , 1995 .

[41]  G. Gribble,et al.  Stereodynamics of 1-tert-butyl-8-fluoronaphthalene. Restricted tert-butyl rotation about an sp3-sp2 carbon-carbon bond. An unusually high barrier to isolated methyl rotation. Through-space-spin-spin coupling to fluorine , 1993 .

[42]  O. Webster Living Polymerization Methods , 1991, Science.

[43]  L. Sutcliffe,et al.  The “through-space” mechanism in spin spin coupling , 1975 .