Effect of temperature on corrosion behaviour of X70 steel in high pressure CO2/SO2/O2/H2O environments

Abstract The corrosion study of the pipeline steel is extremely important for the safety of CO2 pipeline. The present work studied the effect of temperature on the corrosion behaviour of X70 steel in high pressure CO2/SO2/O2/H2O mixtures. Weight loss method was utilised to measure the corrosion rate. Environmental scanning electron microscopy and focused ion beam technology were employed to observe the morphology of product scales. X-ray diffraction was used to analyse the composition of product scales. The porosity of product scales was measured, and the exhaust gas was detected by gas chromatography. Results showed that the corrosion rate increased with the increasing temperature and then started to decline with temperature with the peak corrosion rate at 348 K. Results also showed that there was hydrogen that existed in the exhausted gas, indicating that the hydrogen evolution reaction was contained in the corrosion cathodic process.

[1]  Weidou Ni,et al.  The upper limit of moisture content for supercritical CO2 pipeline transport , 2012 .

[2]  Chao Xu,et al.  Impact of SO2 concentration on the corrosion rate of X70 steel and iron in water-saturated supercritical CO2 mixed with SO2 , 2011 .

[3]  W. Ni,et al.  Corrosion Behavior of X70 Steel in the Supercritical CO2 mixed with SO2 and Saturated Water , 2011 .

[4]  Arne Dugstad,et al.  Corrosion of transport pipelines for CO2–Effect of water ingress , 2011 .

[5]  Yoon-Seok Choi,et al.  Effect of impurities on the corrosion behavior of CO2 transmission pipeline steel in supercritical CO2-water environments. , 2010, Environmental science & technology.

[6]  Svend Tollak Munkejord,et al.  Thermo- and fluid-dynamical modelling of two-phase multi-component carbon dioxide mixtures , 2010 .

[7]  F. M. Song,et al.  A comprehensive model for predicting CO2 corrosion rate in oil and gas production and transportation systems , 2010 .

[8]  A. Veawab,et al.  Corrosion in CO2 Capture Process Using Blended Monoethanolamine and Piperazine , 2009 .

[9]  R. Idem,et al.  Corrosion Behavior of Carbon Steel in the Monoethanolamine-H2O-CO2-O2-SO2 System , 2009 .

[10]  Y. R. Feng,et al.  Effect of temperature on CO2 corrosion of carbon steel , 2009 .

[11]  Q. Yu,et al.  Effect of H2S on stress corrosion cracking and hydrogen permeation behaviour of X56 grade steel in atmospheric environment , 2009 .

[12]  M. Mølnvik,et al.  Thermo- and fluid-dynamical modeling of two-phase multicomponent carbon dioxide mixtures , 2009 .

[13]  James J. Dooley,et al.  Comparing Existing Pipeline Networks with the Potential Scale of Future U.S. CO2 Pipeline Networks , 2009 .

[14]  Q. Yu,et al.  Hydrogen permeation and corrosion behaviour of high strength steel 35CrMo under cyclic wet–dry conditions , 2008 .

[15]  Li Yan,et al.  Mass transfer and kinetics study on the sulfite forced oxidation with manganese ion catalyst , 2007 .

[16]  S. Nešić Key issues related to modelling of internal corrosion of oil and gas pipelines - A review , 2007 .

[17]  R. Newman,et al.  Deterioration in critical pitting temperature of 904L stainless steel by addition of sulfate ions , 2006 .

[18]  Mona J. Mølnvik,et al.  Thermodynamic Models for Calculating Mutual Solubilities in H2O–CO2–CH4 Mixtures , 2006 .

[19]  Xianjin Yang,et al.  Study on corrosion properties of pipelines in simulated produced water saturated with supercritical CO2 , 2006 .

[20]  Shihuai Wang,et al.  INTEGRATED CO2 CORROSION - MULTIPHASE FLOW MODEL , 2004 .

[21]  S. Nešić,et al.  Mechanistic Model for Prediction of the Top of the Line Corrosion Risk , 2003 .

[22]  Karsten Pruess,et al.  CO2-H2O mixtures in the geological sequestration of CO2. I. Assessment and calculation of mutual solubilities from 12 to 100°C and up to 600 bar , 2003 .

[23]  Srdjan Nesic,et al.  A mechanistic model for carbon dioxide corrosion of mild steel in the presence of protective iron carbonate films - Part 3: Film growth model , 2003 .

[24]  Aage Stangeland,et al.  A Mechanistic Model for Carbon Dioxide Corrosion of Mild Steel in the Presence of Protective Iron Carbonate Films—Part 2: A Numerical Experiment , 2003 .

[25]  Aage Stangeland,et al.  A Mechanistic Model for Carbon Dioxide Corrosion of Mild Steel in the Presence of Protective Iron Carbonate Films—Part 1: Theory and Verification , 2003 .

[26]  J. Marco,et al.  Fe-Mn-Al-C Alloys: a Study of Their Corrosion Behaviour in SO2 Environments , 2002 .

[27]  J. Marco,et al.  Fe–Mn–Al–C Alloys: a Study of Their Corrosion Behaviour in SO2 Environments , 2002 .

[28]  Stein Olsen,et al.  An Electrochemical Model for Prediction of Corrosion of Mild Steel in Aqueous Carbon Dioxide Solutions , 1996 .

[29]  H. Saricimen,et al.  Initial stages of atmospheric corrosion of steel in the Arabian Gulf , 1991 .

[30]  C. D. Waard,et al.  Carbonic Acid Corrosion of Steel , 1975 .

[31]  Robert C. Weast,et al.  Handbook of chemistry and physics : a readyreference book of chemical and physical data , 1972 .

[32]  Hans L. J. Bäckström The chain reaction theory of negative catalysis , 1927 .