Nickel-Catalyzed β-Boration of α,β-Unsaturated Esters and Amides with Bis(pinacolato)diboron
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A nickel catalyst system for β-boration of α,β-unsaturated esters and amides with bis(pinacolato)diboron has been developed. The catalyst system enables the boration of di-, tri-, and tetrasubstituted substrates in good yields.