Annealing shallow Si/SiO2 interface traps in electron-beam irradiated high-mobility metal-oxide-silicon transistors

Electron-beam (e-beam) lithography is commonly used in fabricating metal-oxide-silicon (MOS) quantum devices but creates defects at the Si/SiO2 interface. Here, we show that a forming gas anneal is effective at removing shallow defects (≤4 meV below the conduction band edge) created by an e-beam exposure by measuring the density of shallow electron traps in two sets of high-mobility MOS field-effect transistors. One set was irradiated with an electron-beam (10 keV, 40 μC/cm2) and was subsequently annealed in forming gas while the other set remained unexposed. Low temperature (335 mK) transport measurements indicate that the forming gas anneal recovers the e-beam exposed sample's peak mobility (14 000 cm2/Vs) to within a factor of two of the unexposed sample's mobility (23 000 cm2/Vs). Using electron spin resonance (ESR) to measure the density of shallow traps, we find that the two sets of devices are nearly identical, indicating the forming gas anneal is sufficient to anneal out shallow defects generated ...

[1]  Charles Tahan,et al.  Electron spin resonance and spin–valley physics in a silicon double quantum dot , 2013, Nature Communications.

[2]  Probing band-tail states in silicon metal-oxide-semiconductor heterostructures with electron spin resonance , 2011, 1110.0757.

[3]  Michelle Y. Simmons,et al.  Silicon quantum electronics , 2012, 1206.5202.

[4]  Charge sensing in enhancement mode double-top-gated metal-oxide-semiconductor quantum dots , 2009, 0909.3547.

[5]  Shinichi Tojo,et al.  Electron spin coherence exceeding seconds in high-purity silicon. , 2011, Nature materials.

[6]  Spin resonance of 2D electrons in a large-area silicon MOSFET , 2007, 0710.1216.

[7]  Shyam Shankar,et al.  Spin relaxation and coherence times for electrons at the Si/SiO2 interface , 2009, 0912.3037.

[8]  J. P. Dehollain,et al.  A two-qubit logic gate in silicon , 2014, Nature.

[9]  D. DiVincenzo,et al.  Quantum computation with quantum dots , 1997, cond-mat/9701055.

[10]  J. R. Wendt,et al.  Electrostatically defined silicon quantum dots with counted antimony donor implants , 2015 .

[11]  T. Ma,et al.  Quantitative inelastic tunneling spectroscopy in the silicon metal-oxide-semiconductor system , 1997 .

[12]  Gerhard Klimeck,et al.  Spin-valley lifetimes in a silicon quantum dot with tunable valley splitting , 2013, Nature Communications.

[13]  J. R. Wendt,et al.  Enhancement-mode double-top-gated metal-oxide-semiconductor nanostructures with tunable lateral geometry , 2009 .

[14]  Andrew G. Glen,et al.  APPL , 2001 .

[15]  Andrew S. Dzurak,et al.  A single-atom electron spin qubit in silicon , 2012, Nature.

[16]  K. Eng,et al.  Observation of percolation-induced two-dimensional metal-insulator transition in a Si MOSFET , 2008, 0811.1394.

[17]  J. Bokor,et al.  Suppression of microwave rectification effects in electrically detected magnetic resonance measurements , 2012 .

[18]  B. E. Kane A silicon-based nuclear spin quantum computer , 1998, Nature.

[19]  G. G. Stokes "J." , 1890, The New Yale Book of Quotations.

[20]  L. Hollenberg,et al.  Single-shot readout of an electron spin in silicon , 2010, Nature.

[21]  M Xiao,et al.  Measurement of the spin relaxation time of single electrons in a silicon metal-oxide-semiconductor-based quantum dot. , 2010, Physical review letters.

[22]  James D. Plummer,et al.  Rapid thermal annealing of interface states in aluminum gate metal‐oxide‐silicon capacitors , 1985 .

[23]  F. Stern,et al.  Electronic properties of two-dimensional systems , 1982 .

[24]  G. Pica,et al.  Surface code architecture for donors and dots in silicon with imprecise and nonuniform qubit couplings , 2015, 1506.04913.