New conjugated molecular scaffolds based on [2,2]paracyclophane as electron acceptors for organic photovoltaic cells.

Two conjugated molecules with a [2,2]paracyclophane core were designed as non-fullerene electron acceptors for photovoltaic cells. Using as the donor, a high power conversion efficiency (2.69%) is achieved for the blending thin film of with , which is relatively high for solution-processed OPVs based on small molecular non-fullerene acceptors and as the electron donor.

[1]  Z. Yin,et al.  Bandgap Tunable Zn1‐xMgxO Thin Films as Highly Transparent Cathode Buffer Layers for High‐Performance Inverted Polymer Solar Cells , 2014 .

[2]  Long Ye,et al.  Binary additives synergistically boost the efficiency of all-polymer solar cells up to 3.45% , 2014 .

[3]  Barry P Rand,et al.  8.4% efficient fullerene-free organic solar cells exploiting long-range exciton energy transfer , 2014, Nature Communications.

[4]  William N. White,et al.  Small molecule BODIPY dyes as non-fullerene acceptors in bulk heterojunction organic photovoltaics. , 2014, Chemical communications.

[5]  Long Ye,et al.  Bay-linked perylene bisimides as promising non-fullerene acceptors for organic solar cells. , 2014, Chemical communications.

[6]  Weiwei Li,et al.  Universal correlation between fibril width and quantum efficiency in diketopyrrolopyrrole-based polymer solar cells. , 2013, Journal of the American Chemical Society.

[7]  Gang Li,et al.  25th Anniversary Article: A Decade of Organic/Polymeric Photovoltaic Research , 2013, Advanced materials.

[8]  Christopher M. Proctor,et al.  A High‐Performing Solution‐Processed Small Molecule:Perylene Diimide Bulk Heterojunction Solar Cell , 2013, Advanced materials.

[9]  Johannes T. Margraf,et al.  Blending through-space and through-bond π-π-coupling in [2,2']-paracyclophane-oligophenylenevinylene molecular wires. , 2013, Journal of the American Chemical Society.

[10]  Ying Shu,et al.  Indan-1,3-dione electron-acceptor small molecules for solution-processable solar cells: a structure-property correlation. , 2013, Chemical communications.

[11]  Yongfang Li,et al.  A Solution‐Processable Electron Acceptor Based on Dibenzosilole and Diketopyrrolopyrrole for Organic Solar Cells , 2013 .

[12]  Jian Pei,et al.  Non-fullerene acceptors containing fluoranthene-fused imides for solution-processed inverted organic solar cells. , 2013, Chemical communications.

[13]  Qian Zhang,et al.  Solution-processed and high-performance organic solar cells using small molecules with a benzodithiophene unit. , 2013, Journal of the American Chemical Society.

[14]  Y. Geng,et al.  Interface-induced crystalline ordering and favorable morphology for efficient annealing-free poly(3-hexylthiophene): fullerene derivative solar cells. , 2012, ACS applied materials & interfaces.

[15]  Miao Xu,et al.  Enhanced power-conversion efficiency in polymer solar cells using an inverted device structure , 2012, Nature Photonics.

[16]  Fei Huang,et al.  Inverted polymer solar cells with 8.4% efficiency by conjugated polyelectrolyte , 2012 .

[17]  Yang Yang,et al.  Systematic investigation of benzodithiophene- and diketopyrrolopyrrole-based low-bandgap polymers designed for single junction and tandem polymer solar cells. , 2012, Journal of the American Chemical Society.

[18]  J. Brédas,et al.  Closely stacked oligo(phenylene ethynylene)s: effect of π-stacking on the electronic properties of conjugated chromophores. , 2012, Journal of the American Chemical Society.

[19]  Alex K.-Y. Jen,et al.  Recent advances in solution-processed interfacial materials for efficient and stable polymer solar cells , 2012 .

[20]  He Tian,et al.  Diketopyrrolopyrrole (DPP)-based materials for organic photovoltaics. , 2012, Chemical communications.

[21]  Peter Bäuerle,et al.  Small molecule organic semiconductors on the move: promises for future solar energy technology. , 2012, Angewandte Chemie.

[22]  Jean-Luc Brédas,et al.  Solution-Processed Organic Solar Cells with Power Conversion Efficiencies of 2.5% using Benzothiadiazole/Imide-Based Acceptors , 2011 .

[23]  Khai Leok Chan,et al.  Organic non-fullerene acceptors for organic photovoltaics , 2011 .

[24]  J. Anthony Small-Molecule, Nonfullerene Acceptors for Polymer Bulk Heterojunction Organic Photovoltaics† , 2011 .

[25]  Yongfang Li,et al.  Fullerene derivative acceptors for high performance polymer solar cells. , 2011, Physical chemistry chemical physics : PCCP.

[26]  Yongye Liang,et al.  A new class of semiconducting polymers for bulk heterojunction solar cells with exceptionally high performance. , 2010, Accounts of chemical research.

[27]  Fred Wudl,et al.  Strain and hückel aromaticity: driving forces for a promising new generation of electron acceptors in organic electronics. , 2010, Angewandte Chemie.

[28]  J. Roncali Molecular bulk heterojunctions: an emerging approach to organic solar cells. , 2009, Accounts of chemical research.

[29]  Edward Van Keuren,et al.  Endohedral fullerenes for organic photovoltaic devices. , 2009, Nature materials.

[30]  H. Y. Woo,et al.  Solvatochromism of distyrylbenzene pairs bound together by [2.2]paracyclophane: evidence for a polarizable "through-space" delocalized state. , 2005, Journal of the American Chemical Society.

[31]  G. Bazan,et al.  Bichromophoric paracyclophanes: models for interchromophore delocalization. , 2001, Accounts of chemical research.

[32]  Luping Yu,et al.  Rational designs of multifunctional polymers , 1993 .

[33]  heterojunctions,et al.  Polymer photovoltaic cells - enhanced efficiencies via a network of internal donor-acceptor heterojunctions , 2001 .