High‐temperature Brillouin scattering in fused quartz

Thermal Brillouin scattering has been studied in fused silica from room temperature, through the glass transition temperature (1200°C), and up to near the melting temperature of quartz (∼1700°C). The shear and longitudinal Brillouin shifts, the longitudinal linewidth, Pockel's coefficient, and the Landau‐Placzek ratio are measured. From these the behavior of the elastic moduli and absorption coefficient with temperature are obtained. A significant change in the temperature dependence of the moduli and Pockel's coefficient is found to occur above 500°C. In addition, by using the Landau‐Placzek ratio the first measurement in fused quartz of the equilibrium static compressibility above the glass transition has been obtained. Surprisingly little temperature dependence is observed.

[1]  F. Birch,et al.  Compressibility of rocks and glasses at high temperatures and pressures: seismological application , 1936 .

[2]  J. Marx,et al.  Temperature Dependence of the Elastic Moduli and Internal Friction of Silica and Glass , 1953 .

[3]  J. Bockris,et al.  Viscosity and the structure of molten silicates , 1954, Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences.

[4]  M. Fine,et al.  Low‐Temperature Internal Friction and Elasticity Effects in Vitreous Silica , 1954 .

[5]  O. Anderson,et al.  Ultrasonic Absorption in Fused Silica at Low Temperatures and High Frequencies , 1955 .

[6]  J. Bockris,et al.  THE COMPRESSIBILITIES OF THE SILICATES: THE Li$sub 2$O-SiO$sub 2$ SYSTEM , 1957 .

[7]  G. Dienes The temperature-dependence of the elastic moduli of vitreous silica , 1958 .

[8]  M. Goldstein Depolarized Components of Light Scattered by Glasses. I. Measurements on Twelve Optical Glasses , 1959 .

[9]  William Primak,et al.  Photoelastic Constants of Vitreous Silica and Its Elastic Coefficient of Refractive Index , 1959 .

[10]  T. Litovitz,et al.  Ultrasonic Viscoelastic Properties of Associated Liquids , 1960 .

[11]  K. Dransfeld,et al.  Excitation and Attenuation of Hypersonic Waves in Quartz , 1960 .

[12]  J. Bockris,et al.  The Compressibilities of Certain Molten Alkali Silicates and Borates , 1960 .

[13]  S. Spinner Temperature Dependence of Elastic Constants of Vitreous Silica , 1962 .

[14]  P. B. Macedo,et al.  Temperature Dependence of the High‐Frequency Moduli of Vitreous B2O3 , 1966 .

[15]  Robert W. Gammon,et al.  Rayleigh and Brillouin Scattering in Liquids: The Landau—Placzek Ratio , 1966 .

[16]  R. A. Miller,et al.  Determination of the individual strain-optic coefficients of glass by an ultrasonic technique. , 1968, Applied optics.

[17]  A. Pine,et al.  High-resolution low-level Brillouin spectroscopy in solids , 1968 .

[18]  H. Leidecker,et al.  Instrumental Effects on Brillouin Line Shapes , 1968 .

[19]  T. Litovitz,et al.  Brillouin Scattering: Viscoelastic Measurements in Liquids , 1968 .

[20]  Alan S. Pine,et al.  Brillouin Scattering Study of Acoustic Attenuation in Fused Quartz , 1969 .

[21]  O. D. Slagle,et al.  Adiabatic Compressibility of Molten Alumina , 1970 .

[22]  P. B. Macedo,et al.  Equilibrium Compressibilities and Density Fluctuations in K2O–SiO2 Glasses , 1973 .

[23]  W. F. Love Low-Temperature Thermal Brillouin Scattering in Fused Silica and Borosilicate Glass , 1973 .

[24]  H. Dardy,et al.  Temperature dependence of the isothermal compressibility of boron trioxide , 1974 .

[25]  H. Dardy,et al.  Light scattering from boron trioxide through the glass transition , 1974 .