Small-molecule solar cells—status and perspectives

In this paper we focus on the current status of organic solar cells based on small molecules. Since their discovery, much progress has been made, and the main steps are highlighted that led to the current state-of-the-art devices. However, organic solar cells still need to be improved further, and the main strategies for improving the power conversion efficiency, namely raising the open circuit voltage Voc and increasing the short circuit current density Jsc, are discussed. In theory, power conversion efficiencies of around 15% should be possible with a single heterojunction; for higher efficiencies, stacked solar cell concepts have to be employed.

[1]  O. Inganäs,et al.  A Conjugated Polymer for Near Infrared Optoelectronic Applications , 2007 .

[2]  Martin Pfeiffer,et al.  Organic p-i-n solar cells , 2004 .

[3]  Martin A. Green,et al.  Solar cell efficiency tables (version 2) , 1993 .

[4]  K. Triyana,et al.  Effects of Different Materials Used for Internal Floating Electrode on the Photovoltaic Properties of Tandem Type Organic Solar Cell , 2004 .

[5]  Gang Li,et al.  Accurate Measurement and Characterization of Organic Solar Cells , 2006 .

[6]  A. Cravino Origin of the open circuit voltage of donor-acceptor solar cells: Do polaronic energy levels play a role? , 2007 .

[7]  R. Franke,et al.  Long-term stability of tandem solar cells containing small organic molecules , 2008 .

[8]  C. Brabec,et al.  Origin of the Open Circuit Voltage of Plastic Solar Cells , 2001 .

[9]  S. Forrest,et al.  Organic solar cells with sensitivity extending into the near infrared , 2005 .

[10]  Barry P Rand,et al.  Mixed donor-acceptor molecular heterojunctions for photovoltaic applications. II. Device performance , 2005 .

[11]  Valentin D. Mihailetchi,et al.  Device Physics of Polymer:Fullerene Bulk Heterojunction Solar Cells , 2007 .

[12]  V. Mihailetchi,et al.  Compositional dependence of the performance of poly(p-phenylene vinylene) , 2005 .

[13]  Wilhelm Warta,et al.  Solar cell efficiency tables (version 30) , 2007 .

[14]  Brian A. Gregg,et al.  Organic and nano-structured composite photovoltaics: An overview , 2005 .

[15]  Martin Pfeiffer,et al.  Optimizing organic photovoltaics using tailored heterojunctions: A photoinduced absorption study of oligothiophenes with low band gaps , 2008 .

[16]  Christoph J. Brabec,et al.  Organic photovoltaics: technology and market , 2004 .

[17]  Uli Lemmer,et al.  Organic tandem solar cells comprising polymer and small-molecule subcells , 2006 .

[18]  Brian A. Gregg,et al.  Comparing organic to inorganic photovoltaic cells: Theory, experiment, and simulation , 2003 .

[19]  B. Harbecke,et al.  Coherent and incoherent reflection and transmission of multilayer structures , 1986 .

[20]  Hans-Werner Schmidt,et al.  Combinatorial study of the long-term stability of organic thin-film solar cells , 2002 .

[21]  P. Lalanne,et al.  Highly improved convergence of the coupled-wave method for TM polarization and conical mountings , 1996, Diffractive Optics and Micro-Optics.

[22]  Valentin D. Mihailetchi,et al.  Device model for the operation of polymer/fullerene bulk heterojunction solar cells , 2005 .

[23]  Christoph J. Brabec,et al.  Design of efficient organic tandem cells: On the interplay between molecular absorption and layer sequence , 2007 .

[24]  C. Tang Two‐layer organic photovoltaic cell , 1986 .

[25]  L. S. Roman,et al.  Modeling photocurrent action spectra of photovoltaic devices based on organic thin films , 1999 .

[26]  Neil C. Greenham,et al.  A microscopic model for the behavior of nanostructured organic photovoltaic devices , 2007 .

[27]  Weimin Zhang,et al.  Charge carrier formation in polythiophene/fullerene blend films studied by transient absorption spectroscopy. , 2008, Journal of the American Chemical Society.

[28]  Stephen R. Forrest,et al.  High photovoltage multiple-heterojunction organic solar cells incorporating interfacial metallic nanoclusters , 2002 .

[29]  Frederik C. Krebs,et al.  Degradation and stability of polymer and organic solar cells , 2008 .

[30]  K. Meerholz,et al.  Modern Trends in Organic Light-Emitting Devices (OLEDs) , 2006 .

[31]  A. Opitz,et al.  Ambipolar charge carrier transport in mixed organic layers of phthalocyanine and fullerene , 2006, cond-mat/0612555.

[32]  O. Inganäs,et al.  Correlation between oxidation potential and open-circuit voltage of composite solar cells based on blends of polythiophenes/ fullerene derivative , 2004 .

[33]  K. Schulze,et al.  Tailored heterojunctions for efficient thin-film organic solar cells: a photoinduced absorption study , 2007, SPIE Organic Photonics + Electronics.

[34]  F. Krebs,et al.  Stability/degradation of polymer solar cells , 2008 .

[35]  P-I-N Junction Organic Solar Cells , 2006 .

[36]  Karl Leo,et al.  Light trapping in organic solar cells , 2008 .

[37]  Bernard Kippelen,et al.  Analysis of improved photovoltaic properties of pentacene/C60 organic solar cells: Effects of exciton blocking layer thickness and thermal annealing , 2007 .

[38]  Norbert Koch,et al.  Organic electronic devices and their functional interfaces. , 2007, Chemphyschem : a European journal of chemical physics and physical chemistry.

[39]  Martin Pfeiffer,et al.  Efficient Vacuum‐Deposited Organic Solar Cells Based on a New Low‐Bandgap Oligothiophene and Fullerene C60 , 2006 .

[40]  Gang Li,et al.  Investigation of annealing effects and film thickness dependence of polymer solar cells based on poly(3-hexylthiophene) , 2005 .

[41]  D. Hertel,et al.  Photoconduction in amorphous organic solids. , 2008, Chemphyschem : a European journal of chemical physics and physical chemistry.

[42]  Stephen R. Forrest,et al.  Small molecular weight organic thin-film photodetectors and solar cells , 2003 .

[43]  Jan Genoe,et al.  Analytical model for the open-circuit voltage and its associated resistance in organic planar heterojunction solar cells , 2008 .

[44]  Christoph J. Brabec,et al.  Simulation of light intensity dependent current characteristics of polymer solar cells , 2004 .

[45]  Valentin D. Mihailetchi,et al.  Charge Transport and Photocurrent Generation in Poly(3‐hexylthiophene): Methanofullerene Bulk‐Heterojunction Solar Cells , 2006 .

[46]  Jan Birnstock,et al.  High-efficiency and low-voltage p‐i‐n electrophosphorescent organic light-emitting diodes with double-emission layers , 2004 .

[47]  P. Würfel Photovoltaic Principles and Organic Solar Cells , 2007 .

[48]  Wilhelm Warta,et al.  Solar cell efficiency tables (version 29) , 2007 .

[49]  Stephen R. Forrest,et al.  Asymmetric tandem organic photovoltaic cells with hybrid planar-mixed molecular heterojunctions , 2004 .

[50]  N. Armstrong,et al.  Titanyl phthalocyanine/C60 heterojunctions: Band-edge offsets and photovoltaic device performance , 2008 .

[51]  M. Yokoyama,et al.  Enhanced Photovoltaic Performance in Fullerene:Phthalocyanine Codeposited Films Deposited on Heated Substrate , 2004 .

[52]  A J Heeger,et al.  Efficiency enhancement in low-bandgap polymer solar cells by processing with alkane dithiols. , 2007, Nature materials.

[53]  O. V. Molodtsova,et al.  Electronic properties of the organic semiconductor interfaces CuPc∕C60 and C60∕CuPc , 2006 .

[54]  S. Olthof,et al.  Efficient p-i-n type organic solar cells incorporating 1,4,5,8-naphthalenetetracarboxylic dianhydride as transparent electron transport material , 2008 .

[55]  Stephen R. Forrest,et al.  Mixed donor-acceptor molecular heterojunctions for photovoltaic applications. I. Material properties , 2005 .

[56]  C. Brabec,et al.  2.5% efficient organic plastic solar cells , 2001 .

[57]  Hiroshi Fujiwara,et al.  Three‐layered organic solar cell with a photoactive interlayer of codeposited pigments , 1991 .

[58]  P. Heremans,et al.  Polythiophene based bulk heterojunction solar cells: morphology and its implications , 2006 .

[59]  Chang Ming Li,et al.  Degradation of small-molecule organic solar cells , 2006 .

[60]  Kristian O. Sylvester-Hvid Two-dimensional simulations of CuPc-PCTDA solar cells: the importance of mobility and molecular pi stacking. , 2006, The journal of physical chemistry. B.

[61]  Barry P Rand,et al.  4.2% efficient organic photovoltaic cells with low series resistances , 2004 .

[62]  P. Sullivan,et al.  The role of molecular architecture and layer composition on the properties and performance of CuPc-C60 photovoltaic devices , 2005 .

[63]  S. Barlow,et al.  A Comparative Study of Charge Mobility Measurements in a Diamine and in a Hexaazatrinaphthylene Using Different Techniques , 2008 .

[64]  Norbert Koch,et al.  Electronic structure and electrical properties of interfaces between metals and π-conjugated molecular films , 2003 .

[65]  Valentin D. Mihailetchi,et al.  Ultimate efficiency of polymer/fullerene bulk heterojunction solar cells , 2006 .

[66]  A. Opitz,et al.  Ambipolar Blends of Cu-Phthalocyanine and Fullerene : Charge Carrier Mobility, Electronic Structure and their Implications for Solar Cell Applications , 2007, 0709.3922.

[67]  P. Würfel Physics of solar cells : from principles to new concepts , 2005 .

[68]  C. Brabec,et al.  Flexible organic P3HT:PCBM bulk-heterojunction modules with more than 1 year outdoor lifetime , 2008 .

[69]  Jan Genoe,et al.  Solar cells utilizing small molecular weight organic semiconductors , 2007 .

[70]  Stephen R. Forrest,et al.  Efficient photon harvesting at high optical intensities in ultrathin organic double-heterostructure photovoltaic diodes , 2000 .

[71]  Christoph J. Brabec,et al.  Characterization of Organic Solar Cells: the Importance of Device Layout , 2007 .

[72]  Stephen R. Forrest,et al.  Offset energies at organic semiconductor heterojunctions and their influence on the open-circuit voltage of thin-film solar cells , 2007 .

[73]  K. Fostiropoulos,et al.  Zinc-phthalocyaninetetraphosphonic acid as a novel transparent-conducting-oxide passivation for organic photovoltaic devices , 2008 .

[74]  Nils-Krister Persson,et al.  Organic tandem solar cells—modelling and predictions , 2006 .

[75]  C. Tang,et al.  Organic Electroluminescent Diodes , 1987 .

[76]  Richard H. Friend,et al.  The origin of the open-circuit voltage in polyfluorene-based photovoltaic devices , 2002 .

[77]  Bernard Kippelen,et al.  Encapsulation of pentacene/C60 organic solar cells with Al2O3 deposited by atomic layer deposition , 2007 .

[78]  Helmut Neugebauer,et al.  Flexible, long-lived, large-area, organic solar cells , 2007 .

[79]  Christoph J. Brabec,et al.  Design Rules for Donors in Bulk‐Heterojunction Solar Cells—Towards 10 % Energy‐Conversion Efficiency , 2006 .

[80]  Ching Wan Tang,et al.  Organic electroluminescent devices with improved stability , 1996 .

[81]  K. Walzer,et al.  Highly efficient organic devices based on electrically doped transport layers. , 2007, Chemical reviews.

[82]  Bernard Kippelen,et al.  Efficient thin-film organic solar cells based on pentacene/C60 heterojunctions , 2004 .

[83]  Liduo Wang,et al.  Review of recent progress in solid-state dye-sensitized solar cells , 2006 .

[84]  N. E. Coates,et al.  Efficient Tandem Polymer Solar Cells Fabricated by All-Solution Processing , 2007, Science.

[85]  Christoph J. Brabec,et al.  The influence of materials work function on the open circuit voltage of plastic solar cells , 2002 .

[86]  J. Ferraris,et al.  Temperature and time dependence of heat treatment of RR-P3HT/PCBM solar cell , 2005 .

[87]  Barry P Rand,et al.  Near-infrared sensitive small molecule organic photovoltaic cells based on chloroaluminum phthalocyanine , 2007 .

[88]  V. Mihailetchi,et al.  Cathode dependence of the open-circuit voltage of polymer:fullerene bulk heterojunction solar cells , 2003 .

[89]  J. Inoue,et al.  Photovoltaic properties of multilayer organic thin films , 2007 .

[90]  Martin A. Green,et al.  Solar cell efficiency tables (Version 31) , 2008 .

[91]  H. Hoppea,et al.  Modeling the optical absorption within conjugated polymer / fullerene-based bulk-heterojunction organic solar cells , 2003 .

[92]  A. Walker,et al.  Dynamical Monte Carlo modelling of organic solar cells: the dependence of internal quantum efficiency on morphology. , 2005, Nano letters.

[93]  Martin Pfeiffer,et al.  Origin of open circuit voltage in planar and bulk heterojunction organic thin-film photovoltaics depending on doped transport layers , 2008 .

[94]  A. Kahn,et al.  Electronic structure, diffusion, and p-doping at the Au/F16CuPc interface , 2001 .

[95]  Stephen R. Forrest,et al.  Efficient bulk heterojunction photovoltaic cells using small-molecular-weight organic thin films , 2003, Nature.

[96]  L. Jay Guo,et al.  Choice of electrode geometry for accurate measurement of organic photovoltaic cell performance , 2008 .

[97]  Xiaoniu Yang,et al.  Nanoscale morphology of high-performance polymer solar cells. , 2005, Nano letters.

[98]  Brian S. Wherrett,et al.  Photon-recycling and optically driven plasma-expansion techniques applied to lifetime experiments on molecular-beam-epitaxy ZnSe , 1996 .

[99]  D. Gebeyehu,et al.  MIP-type organic solar cells incorporating phthalocyanine/fullerene mixed layers and doped wide-gap transport layers , 2004 .

[100]  Dieter Meissner,et al.  Nanoscale Morphology of Conjugated Polymer/Fullerene‐Based Bulk‐ Heterojunction Solar Cells , 2004 .

[101]  Barry P Rand,et al.  Organic Double‐Heterostructure Photovoltaic Cells Employing Thick Tris(acetylacetonato)ruthenium(III) Exciton‐Blocking Layers , 2005 .

[102]  M. Lux‐Steiner,et al.  On the function of a bathocuproine buffer layer in organic photovoltaic cells , 2006 .

[103]  Masahiro Hiramoto,et al.  Effect of Thin Gold Interstitial-layer on the Photovoltaic Properties of Tandem Organic Solar Cell , 1990 .

[104]  Xiang Zhou,et al.  Doped organic semiconductors: Physics and application in light emitting diodes , 2003 .

[105]  N. S. Sariciftci,et al.  Conjugated polymer-based organic solar cells. , 2007, Chemical reviews.

[106]  Valentin D. Mihailetchi,et al.  Light intensity dependence of open-circuit voltage of polymer: fullerene solar cells , 2005 .

[107]  Philippe Lalanne,et al.  Computation of the near-field pattern with the coupled-wave method for transverse magnetic polarization , 1998 .