Multiple shape transformations of composite hydrogel sheets.

Soft materials undergoing shape transformations in response to changes in ambient environment have potential applications in tissue engineering, robotics and biosensing. Generally, stimulus-responsive materials acquire two stable shapes corresponding to the "on" and "off" states of the external trigger. Here, we report a simple, yet versatile approach to induce multiple shape transformations of a planar hydrogel sheet, each triggered by a particular, well-defined external stimulus. The approach is based on the integration of small-scale multiple polymer components with distinct compositions in the composite gel sheet. In response to different stimuli, the structural components undergo differential swelling or shrinkage, which creates internal stresses within the composite hydrogel sheet and transforms its shape in a specific manner.

[1]  Leonid Ionov,et al.  Biomimetic 3D self-assembling biomicroconstructs by spontaneous deformation of thin polymer films , 2012 .

[2]  Ximin He,et al.  Synthetic homeostatic materials with chemo-mechano-chemical self-regulation , 2012, Nature.

[3]  Jingjing Zhang,et al.  Temperature-sensitive bending of bigel strip bonded by macroscopic molecular recognition , 2012 .

[4]  R. Hayward,et al.  Designing Responsive Buckled Surfaces by Halftone Gel Lithography , 2012, Science.

[5]  Seeram Ramakrishna,et al.  Advances in polymeric systems for tissue engineering and biomedical applications. , 2012, Macromolecular bioscience.

[6]  Z. Suo Mechanics of stretchable electronics and soft machines , 2012 .

[7]  Hwan Chul Jeon,et al.  Controlled origami folding of hydrogel bilayers with sustained reversibility for robust microcarriers. , 2012, Angewandte Chemie.

[8]  R. Hayward,et al.  Thermally responsive rolling of thin gel strips with discrete variations in swelling , 2012 .

[9]  Xia Tong,et al.  General Strategy for Making CO2-Switchable Polymers. , 2012, ACS macro letters.

[10]  Ximin He,et al.  Hydrogel-actuated integrated responsive systems (HAIRS): Moving towards adaptive materials , 2011 .

[11]  R. Kupferman,et al.  Geometry and Mechanics in the Opening of Chiral Seed Pods , 2011, Science.

[12]  Leonid Ionov,et al.  Soft microorigami: self-folding polymer films , 2011 .

[13]  Andrew G. Gillies,et al.  Optically-and Thermally-responsive Programmable Materials Based on Carbon Nanotube-hydrogel Polymer Composites , 2022 .

[14]  Peter Fratzl,et al.  Origami-like unfolding of hydro-actuated ice plant seed capsules. , 2011, Nature communications.

[15]  S. Venkataramani,et al.  Experimental study of shape transitions and energy scaling in thin non-Euclidean plates. , 2011, Physical review letters.

[16]  D. Gracias,et al.  Photolithographically patterned smart hydrogel based bilayer actuators , 2010 .

[17]  E. Sharon,et al.  The mechanics of non-Euclidean plates , 2010 .

[18]  Pei-Chun Lin,et al.  Harnessing Surface Wrinkle Patterns in Soft Matter , 2010 .

[19]  H. Mirzadeh,et al.  Solvent-, ion- and pH-specific swelling of poly(2-acrylamido-2-methylpropane sulfonic acid) superabsorbing gels , 2010 .

[20]  M. C. Stuart,et al.  Emerging applications of stimuli-responsive polymer materials. , 2010, Nature materials.

[21]  F. Barth,et al.  Biomaterial systems for mechanosensing and actuation , 2009, Nature.

[22]  D. Tyler,et al.  Stimuli-Responsive Polymer Nanocomposites Inspired by the Sea Cucumber Dermis , 2008, Science.

[23]  E. Sharon,et al.  Shaping of Elastic Sheets by Prescription of Non-Euclidean Metrics , 2007, Science.

[24]  C. Chu,et al.  Synthesis, characterization and controlled drug release of thermosensitive IPN-PNIPAAm hydrogels. , 2004, Biomaterials.

[25]  Igor Luzinov,et al.  Adaptive and responsive surfaces through controlled reorganization of interfacial polymer layers , 2004 .

[26]  E. Kumacheva,et al.  Multidye Nanostructured Material for Optical Data Storage and Security Labeling , 2004 .

[27]  Eugenia Kumacheva,et al.  A Multidye Nanostructured Material for Optical Data Storage and Security Data Encryption , 2004 .

[28]  C. Dawson,et al.  How pine cones open , 1997, Nature.

[29]  Zhibing Hu,et al.  Synthesis and Application of Modulated Polymer Gels , 1995, Science.

[30]  H. Kohut The curve of life , 1994 .

[31]  H. G. Schild Poly(N-isopropylacrylamide): experiment, theory and application , 1992 .

[32]  Tanaka,et al.  Critical kinetics of volume phase transition of gels. , 1985, Physical review letters.

[33]  K. Abe,et al.  Interpolymer complex between poly(ethylene oxide) and poly(carboxylic acid) , 1975 .