A novel fabrication method for TiC–Al2O3–Fe functional material under centrifugal acceleration

Abstract Compacted powders of titanium (Ti) and carbon (C) in form of pellets were exposed to a massive amount of heat generated from the thermite reaction of Fe2O3 and Al in a graphite–steel tube mounted in a developed centrifugal accelerator machine. The centrifugal force facilitated the formation of multi-component products during the process. Titanium carbide (TiC) product is joined to an Al2O3–Fe layer, which are the products of the thermite reaction. The existence of centrifugal acceleration had a significant effect on both metallurgical alloying and mechanical interlocking between different layers of the sample to form a functional material. A mathematical model developed for this experiment to describe the speed rate of iron infiltration inside the TiC product as well as viscosity rate variation was presented. The composition, microstructure and mechanical properties confirmed the model.

[1]  K. Das,et al.  Synthesis and characterization of TiC-reinforced iron-based composites Part I On synthesis and microstructural characterization , 2004 .

[2]  Weng-Sing Hwang,et al.  The Analysis of Molten Steel Flow in Billet Continuous Casting Mold , 1996 .

[3]  Sie Chin Tjong,et al.  Microstructural and mechanical characteristics of in situ metal matrix composites , 2000 .

[4]  G. Ksandopulo SHS in conditions of rotation: Thermal and concentration combustion limits for oxide systems taken as an example , 2011 .

[5]  U. Schubert,et al.  Synthesis of Inorganic Materials , 2012 .

[6]  J. Montemayor-Aldrete,et al.  High temperature activation energy for plastic deformation of titanium carbide single crystals as a function of the C : Ti atom ratio , 1997 .

[7]  V. I. Nikitin,et al.  In situ synthesis of Al–TiC in aluminum melt , 2005 .

[8]  V. Khatkar,et al.  Synthesis and characterization of in-situ reinforced Fe-TiC steel FGMs , 2008 .

[9]  K. Sun,et al.  Kinetics of thermite reaction in Al-Fe2O3 system , 2006 .

[10]  R. Orrú,et al.  Computer-aided manufacturing of centrifugal SHS coatings , 1996 .

[11]  Chun Yin,et al.  Microstructure transformation and mechanical properties of TiC–TiB2 ceramics prepared by combustion synthesis in high gravity field , 2012 .

[12]  O. Odawara Mass-Forced SHS Technology of Ceramic Materials , 2010 .

[13]  Mohd Hamdi,et al.  A NEW ATTEMPT TO ADAPT A MACHINE FOR SHS LINING CERAMICS INSIDE PIPES , 2012 .

[14]  J. Litwin,et al.  Mathematical Modeling of Particle Segregation During Centrifugal Casting of Metal Matrix Composites , 2012, Journal of Materials Engineering and Performance.

[15]  K. Das,et al.  Synthesis and characterization of TiC-reinforced iron-based composites Part II on mechanical characterization , 2004 .

[16]  Kornel Ehmann,et al.  Surface Texturing of Tribological Interfaces Using the Vibromechanical Texturing Method , 2009 .

[17]  Yu-Fei Wang,et al.  Finite element analysis of residual thermal stress in ceramic-lined composite pipe prepared by centrifugal-SHS , 2007 .

[18]  K. Das,et al.  A Review on the various synthesis routes of TiC reinforced ferrous based composites , 2002 .

[19]  R. Mahmoodian,et al.  The Effects of an Unexpected Ceramic Coating Phase at the Head of a Pipe on Joining and Postprocessing of a Ceramic-Lined Composite Pipe , 2012, JOM.

[20]  F. Baras,et al.  Models of SHS: An overview , 2007 .