Effect of the Synthetic Method on the Properties of Ni-Based Hydrogen Oxidation Catalysts

The latest progress in alkaline anion-exchange membranes has led to the expectation that less costly catalysts than those of the platinum-group metals may be used in anion-exchange membrane fuel cell devices. In this work, we compare structural properties and the catalytic activity for the hydrogen-oxidation reaction (HOR) for carbon-supported nanoparticles of Ni, Ni3Co, Ni3Cu, and Ni3Fe, synthesized by chemical and solvothermal reduction of metal precursors. The catalysts are well dispersed on the carbon support, with particle diameter in the order of 10 nm, and covered by a layer of oxides and hydroxides. The activity for the HOR was assessed by voltammetry in hydrogen-saturated aqueous solutions of 0.1 mol dm–1 KOH. A substantial activation by potential cycling of the pristine catalysts synthesized by solvothermal reduction is necessary before these become active for the HOR; in situ Raman spectroscopy shows that after activation the surface of the Ni/C, Ni3Fe, and Ni3Co catalysts is fully reduced at 0 V, whereas the surface of the Ni3Cu catalyst is not. The activation procedure had a smaller but negative impact on the catalysts synthesized by chemical reduction. After activation, the exchange-current densities normalized with respect to the ECSA (electrochemically active surface area) were approximately independent of composition but relatively high compared to catalysts of larger particle diameter.

[1]  S. Sunde,et al.  NiCu mixed metal oxide catalyst for alkaline hydrogen evolution in anion exchange membrane water electrolysis , 2021, Electrochimica Acta.

[2]  S. Sunde,et al.  Ni/NiO nanosheets for alkaline hydrogen evolution reaction: In situ electrochemical-Raman study , 2020 .

[3]  B. J. Allen,et al.  Synthesis of CeOx‐Decorated Pd/C Catalysts by Controlled Surface Reactions for Hydrogen Oxidation in Anion Exchange Membrane Fuel Cells , 2020, Advanced Functional Materials.

[4]  Xiaoqing Pan,et al.  Size-dependent Ni-based electrocatalysts for selective CO2 reduction. , 2020, Angewandte Chemie.

[5]  Dario R. Dekel,et al.  The critical importance of ionomers on the electrochemical activity of platinum and platinum-free catalysts for anion-exchange membrane fuel cells , 2020, Sustainable Energy & Fuels.

[6]  M. Chatenet,et al.  Recent Advances in the Understanding of Nickel-Based Catalysts for the Oxidation of Hydrogen-Containing Fuels in Alkaline Media , 2020, ACS Catalysis.

[7]  S. Sunde,et al.  Platinum and Platinum Group Metal-Free Catalysts for Anion Exchange Membrane Fuel Cells , 2020 .

[8]  J. Goodenough,et al.  Graphitic‐Shell Encapsulation of Metal Electrocatalysts for Oxygen Evolution, Oxygen Reduction, and Hydrogen Evolution in Alkaline Solution , 2019, Advanced Energy Materials.

[9]  E. Savinova,et al.  On the Influence of the Extent of Oxidation on the Kinetics of the Hydrogen Electrode Reactions on Polycrystalline Nickel , 2019, Electrocatalysis.

[10]  T. Kardash,et al.  Highly active carbon-supported Ni catalyst prepared by nitrate decomposition with a sacrificial agent for the hydrogen oxidation reaction in alkaline medium , 2019, Journal of Electroanalytical Chemistry.

[11]  Dario R. Dekel,et al.  Composite Materials with Combined Electronic and Ionic Properties , 2019, Matter.

[12]  J. Olejníček,et al.  Cobalt Oxide Catalysts in the Form of Thin Films Prepared by Magnetron Sputtering on Stainless-Steel Meshes: Performance in Ethanol Oxidation , 2019, Catalysts.

[13]  O. Ersen,et al.  Bimetallic Phosphide (Ni,Cu)2P Nanoparticles by Inward Phosphorus Migration and Outward Copper Migration , 2019, Chemistry of Materials.

[14]  Dario R. Dekel,et al.  Stability Limits of Ni-Based Hydrogen Oxidation Electrocatalysts for Anion Exchange Membrane Fuel Cells , 2019, ACS Catalysis.

[15]  S. Shermukhamedov,et al.  On the feasibility of bifunctional hydrogen oxidation on Ni and NiCu surfaces , 2019, Electrochimica Acta.

[16]  FuLin Yang,et al.  Enhanced HOR catalytic activity of PGM-free catalysts in alkaline media: the electronic effect induced by different heteroatom doped carbon supports , 2019, Journal of Materials Chemistry A.

[17]  Dario R. Dekel,et al.  Predicting performance stability of anion exchange membrane fuel cells , 2019, Journal of Power Sources.

[18]  Wenzheng Li,et al.  Exploring the Composition–Activity Relation of Ni–Cu Binary Alloy Electrocatalysts for Hydrogen Oxidation Reaction in Alkaline Media , 2019, ACS Applied Energy Materials.

[19]  Dario R. Dekel,et al.  Palladium-ceria nanocatalyst for hydrogen oxidation in alkaline media: Optimization of the Pd–CeO2 interface , 2019, Nano Energy.

[20]  L. Zhuang,et al.  Ni(OH)2-Ni/C for hydrogen oxidation reaction in alkaline media , 2019, Journal of Energy Chemistry.

[21]  W. Mustain,et al.  Nitrogen‐doped Carbon–CoOx Nanohybrids: A Precious Metal Free Cathode that Exceeds 1.0 W cm−2 Peak Power and 100 h Life in Anion‐Exchange Membrane Fuel Cells , 2018, Angewandte Chemie.

[22]  Dario R. Dekel.  Unraveling mysteries of hydrogen electrooxidation in anion exchange membrane fuel cells , 2018, Current Opinion in Electrochemistry.

[23]  W. Mustain.  Understanding how high-performance anion exchange membrane fuel cells were achieved: Component, interfacial, and cell-level factors , 2018, Current Opinion in Electrochemistry.

[24]  Yun Wang,et al.  First-Principles Determination of Active Sites of Ni Metal-Based Electrocatalysts for Hydrogen Evolution Reaction. , 2018, ACS applied materials & interfaces.

[25]  V. Parmon,et al.  Nanostructured nickel nanoparticles supported on vulcan carbon as a highly active catalyst for the hydrogen oxidation reaction in alkaline media , 2018, Journal of Power Sources.

[26]  Dario R. Dekel,et al.  Hydrogen Oxidation on Ni-Based Electrocatalysts: The Effect of Metal Doping , 2018, Catalysts.

[27]  K. Artyushkova,et al.  Nickel–copper supported on a carbon black hydrogen oxidation catalyst integrated into an anion-exchange membrane fuel cell , 2018 .

[28]  J. Varcoe,et al.  A high conductivity ultrathin anion-exchange membrane with 500+ h alkali stability for use in alkaline membrane fuel cells that can achieve 2 W cm−2 at 80 °C , 2018 .

[29]  S. Specchia,et al.  Recent trends on the application of PGM-free catalysts at the cathode of anion exchange membrane fuel cells , 2018 .

[30]  Dario R. Dekel,et al.  Water – A key parameter in the stability of anion exchange membrane fuel cells , 2018, Current Opinion in Electrochemistry.

[31]  Dario R. Dekel,et al.  Electrocatalysts for Hydrogen Oxidation Reaction in Alkaline Electrolytes , 2018, ACS Catalysis.

[32]  Tianshou Zhao,et al.  Advances and challenges in alkaline anion exchange membrane fuel cells , 2018 .

[33]  V. Parmon,et al.  On the effect of temperature and surface oxidation on the kinetics of hydrogen electrode reactions on nickel in alkaline media , 2018 .

[34]  Dario R. Dekel.  Review of cell performance in anion exchange membrane fuel cells , 2018 .

[35]  Sanjeev Mukerjee,et al.  Experimental Proof of the Bifunctional Mechanism for the Hydrogen Oxidation in Alkaline Media. , 2017, Angewandte Chemie.

[36]  K. Artyushkova,et al.  Platinum group metal-free NiMo hydrogen oxidation catalysts: high performance and durability in alkaline exchange membrane fuel cells , 2017 .

[37]  Xianglan Xu,et al.  Mesoporous high surface area NiO synthesized with soft templates: Remarkable for catalytic CH4 deep oxidation , 2017 .

[38]  Q. Fu,et al.  A nickel nanocatalyst within a h-BN shell for enhanced hydrogen oxidation reactions† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c7sc01615h Click here for additional data file. , 2017, Chemical science.

[39]  M. Kraft,et al.  Nickel Nanoparticles Encapsulated in Few‐Layer Nitrogen‐Doped Graphene Derived from Metal–Organic Frameworks as Efficient Bifunctional Electrocatalysts for Overall Water Splitting , 2017, Advanced materials.

[40]  V. Parmon,et al.  Electrocatalysis of the hydrogen oxidation reaction on carbon-supported bimetallic NiCu particles prepared by an improved wet chemical synthesis , 2016 .

[41]  M. R. Tarasevich,et al.  Nonplatinum cathodic catalysts for fuel cells with alkaline electrolyte (Review) , 2016, Russian Journal of Electrochemistry.

[42]  Jun Yan,et al.  Corrigendum: Differential developmental requirement and peripheral regulation for dermal Vγ4 and Vγ6T17 cells in health and inflammation , 2016, Nature Communications.

[43]  Albertus D. Handoko,et al.  In Situ Raman Spectroscopy of Copper and Copper Oxide Surfaces during Electrochemical Oxygen Evolution Reaction: Identification of CuIII Oxides as Catalytically Active Species , 2016 .

[44]  Dionisios G. Vlachos,et al.  Nickel supported on nitrogen-doped carbon nanotubes as hydrogen oxidation reaction catalyst in alkaline electrolyte , 2016, Nature Communications.

[45]  Jiandu Lei,et al.  A Non-sulfided flower-like Ni-PTA Catalyst that Enhances the Hydrotreatment Efficiency of Plant Oil to Produce Green Diesel , 2015, Scientific Reports.

[46]  M. Maaza,et al.  Green synthesis of Co3O4 nanoparticles via Aspalathus linearis: Physical properties , 2015 .

[47]  V. Parmon,et al.  On the Effect of Cu on the Activity of Carbon Supported Ni Nanoparticles for Hydrogen Electrode Reactions in Alkaline Medium , 2015, Topics in Catalysis.

[48]  Tatsuya Shinagawa,et al.  Insight on Tafel slopes from a microkinetic analysis of aqueous electrocatalysis for energy conversion , 2015, Scientific Reports.

[49]  Anthony Kucernak,et al.  Nickel phosphide: the effect of phosphorus content on hydrogen evolution activity and corrosion resistance in acidic medium , 2014 .

[50]  T. Bligaard,et al.  Nickel-silver alloy electrocatalysts for hydrogen evolution and oxidation in an alkaline electrolyte. , 2014, Physical chemistry chemical physics : PCCP.

[51]  Jingguang G. Chen,et al.  Non-precious metal electrocatalysts with high activity for hydrogen oxidation reaction in alkaline electrolytes , 2014 .

[52]  Shouheng Sun,et al.  Monodisperse MPt (M = Fe, Co, Ni, Cu, Zn) nanoparticles prepared from a facile oleylamine reduction of metal salts. , 2014, Nano letters.

[53]  G. Jerkiewicz,et al.  Electrochemical Growth of Surface Oxides on Nickel. Part 2: Formation of β-Ni(OH)2 and NiO in Relation to the Polarization Potential, Polarization Time, and Temperature , 2013, Electrocatalysis.

[54]  D. Hall,et al.  The Electrochemistry of Metallic Nickel: Oxides, Hydroxides, Hydrides and Alkaline Hydrogen Evolution , 2013 .

[55]  D. J. Lockwood,et al.  Raman and infrared spectroscopy of α and β phases of thin nickel hydroxide films electrochemically formed on nickel. , 2012, The journal of physical chemistry. A.

[56]  S. Mukerjee,et al.  Fundamental Mechanistic Understanding of Electrocatalysis of Oxygen Reduction on Pt and Non-Pt Surfaces: Acid versus Alkaline Media , 2012 .

[57]  Gang Wu,et al.  High-Performance Electrocatalysts for Oxygen Reduction Derived from Polyaniline, Iron, and Cobalt , 2011, Science.

[58]  E. .. Mittemeijer,et al.  The lattice parameter of nanocrystalline Ni as function of crystallite size , 2011 .

[59]  G. Jerkiewicz,et al.  Electrochemical Growth of Surface Oxides on Nickel. Part 1: Formation of α-Ni(OH)2 in Relation to the Polarization Potential, Polarization Time, and Temperature , 2011 .

[60]  J. Grabis,et al.  Raman scattering in nanosized nickel oxide NiO , 2007 .

[61]  M. Biesinger,et al.  New interpretations of XPS spectra of nickel metal and oxides , 2006 .

[62]  M. Endo,et al.  The preparation of multi-walled carbon nanotubes with a Ni–P coating by an electroless deposition process , 2005 .

[63]  P. Shen,et al.  Anion exchange membrane fuel cells , 2005 .

[64]  O. Bayraktar,et al.  Temperature-programmed reduction of metal-contaminated fluid catalytic cracking (FCC) catalysts , 2004 .

[65]  C. Petit,et al.  Synthesis and XPS Characterization of Nickel Boride Nanoparticles , 2002 .

[66]  W. Bowers,et al.  In Situ Raman Spectroscopic Investigation of Aqueous Iron Corrosion at Elevated Temperatures and Pressures , 2000 .

[67]  F. Henn,et al.  X-ray diffraction and micro-Raman spectroscopy analysis of new nickel hydroxide obtained by electrodialysis , 2000 .

[68]  C. Lamy,et al.  Electrocatalytic oxidation of hydrogen on polycrystal and single-crystal nickel electrodes , 1990 .

[69]  D. Stirling,et al.  The location of nickel oxide and nickel in silica-supported catalysts: Two forms of “NiO” and the assignment of temperature-programmed reduction profiles , 1988 .

[70]  Nicholas W. Hurst,et al.  Temperature Programmed Reduction , 1982 .

[71]  H. Ewe,et al.  Struktur und eigenschaften von Raney-Nickel-katalysatoren mit zulegierungen für alkalische brennstoffzellen , 1974 .