Macroscopic self-standing SWCNT fibres as efficient electron emitters with very high emission current for robust cold cathodes

Abstract A novel of self-standing nanotube-based cold cathode is described. The electron emitter is a single macroscopic fibre spun from neat single wall carbon nanotubes and consists of an ensemble of nanotube bundles held together by van der Waals forces. Field emission measurements carried out using two different types of apparatus demonstrated the long working life of the realised cathode. The system is able to emit at very high current densities, up to 13 A/cm 2 , and shows very low values of both turn on and threshold field, 0.12 V/μm and 0.21 V/μm, respectively. Such easy to handle self-standing electron sources assure good performances and represent an enabling technology for a scalable production of cold cathodes.

[1]  I. Kinloch,et al.  Macroscopic fibers of well-aligned carbon nanotubes by wet spinning. , 2008, Small.

[2]  W. D. de Heer,et al.  Carbon Nanotubes--the Route Toward Applications , 2002, Science.

[3]  Guohua Cao,et al.  A carbon nanotube field emission cathode with high current density and long-term stability , 2009, Nanotechnology.

[4]  Vu Thien Binh,et al.  Hot nanotubes: stable heating of individual multiwall carbon nanotubes to 2000 k induced by the field-emission current. , 2002, Physical review letters.

[5]  Wei Zhou,et al.  True solutions of single-walled carbon nanotubes for assembly into macroscopic materials , 2009, Nature Nanotechnology.

[6]  Riichiro Saito,et al.  Electronic structure of chiral graphene tubules , 1992 .

[7]  Philip G. Collins,et al.  UNIQUE CHARACTERISTICS OF COLD CATHODE CARBON-NANOTUBE-MATRIX FIELD EMITTERS , 1997 .

[8]  Guohua Cao,et al.  Carbon Nanotube based X-ray Sources: Applications in Pre-Clinical and Medical Imaging. , 2011, Nuclear instruments & methods in physics research. Section A, Accelerators, spectrometers, detectors and associated equipment.

[9]  Sashiro Uemura,et al.  Field emission from carbon nanotubes and its application to electron sources , 1999 .

[10]  Micah J. Green,et al.  Spontaneous dissolution of ultralong single- and multiwalled carbon nanotubes. , 2010, ACS nano.

[11]  J. A. Briones-Leon,et al.  Millimeter-long carbon nanotubes: outstanding electron-emitting sources. , 2011, ACS nano.

[12]  R. Gomer,et al.  Field Emission and Field Ionization , 1961 .

[13]  R. Smalley,et al.  Single Wall Carbon Nanotube Fibers Extruded from Super-Acid Suspensions: Preferred Orientation, Electrical and Thermal Transport , 2004 .

[14]  Mool C. Gupta,et al.  Influences of the surface reactions on the field emission from multiwall carbon nanotubes , 2003 .

[15]  I. Brodie,et al.  Surface‐science aspects of vacuum microelectronics , 1995 .

[16]  Yeonsu Jung,et al.  High-performance field emission from a carbon nanotube carpet , 2012 .

[17]  Young Hee Lee,et al.  Patterned growth and field emission properties of vertically aligned carbon nanotubes , 2001 .

[18]  B. Chalamala,et al.  Current saturation mechanisms in carbon nanotube field emitters , 2000 .

[19]  Jun Chen,et al.  Mechanism responsible for initiating carbon nanotube vacuum breakdown. , 2004, Physical review letters.

[20]  C. Jin,et al.  Quantitative analysis of electron field-emission characteristics of individual carbon nanotubes: the importance of the tip structure. , 2006, The journal of physical chemistry. B.

[21]  P. Nordlander,et al.  Unraveling Nanotubes: Field Emission from an Atomic Wire , 1995, Science.

[22]  Carbon Nanotubes in Microelectronic Applications , 2004, cond-mat/0410360.

[23]  F. Kang,et al.  Enhanced field emission of open-ended, thin-walled carbon nanotubes filled with ferromagnetic nanowires , 2009 .

[24]  W. K. Choi,et al.  Field emission from a large area of vertically-aligned carbon nanofibers with nanoscale tips and controlled spatial geometry , 2010 .

[25]  B.-G. Yoon,et al.  Analysis of the slope of the Fowler–Nordheim plot for field emission from n-type semiconductors , 2003 .

[26]  Matteo Pasquali,et al.  Carbon nanotube-based neat fibers , 2008 .

[27]  K. Jiang,et al.  Measuring the stress in field-emitting carbon nanotubes , 2006 .

[28]  Myung Jong Kim,et al.  Macroscopic, Neat, Single-Walled Carbon Nanotube Fibers , 2002, Science.

[29]  Seung Hoon Nahm,et al.  Field emission properties from the tip and side of multi-walled carbon nanotube yarns , 2010 .

[30]  S. Orlanducci,et al.  Carbon nanotube/nanodiamond structures: An innovative concept for stable and ready-to-start electron emitters , 2009 .

[31]  László Forró,et al.  Field emission properties of multiwalled carbon nanotubes , 1998 .

[32]  Kiran Shankar Hazra,et al.  Dramatic enhancement of the emission current density from carbon nanotube based nanosize tips with extremely low onset fields. , 2009, ACS nano.

[33]  Aleksandr V. Eletskii Carbon nanotube-based electron field emitters , 2010 .

[34]  L. Chow,et al.  Electron emission from the side wall of an individual multiwall carbon nanotube , 2007 .

[35]  Honeycomb arrays of carbon nanotubes in alumina templates for field emission based devices and electron sources , 2010 .

[36]  K. Jiang,et al.  Efficient fabrication of field electron emitters from the multiwalled carbon nanotube yarns , 2006 .

[37]  Seiji Akita,et al.  Comparison of Field Emissions from Side Wall and Tip of an Individual Carbon Nanotube , 2005 .

[38]  F. Kang,et al.  Synthesis and Enhanced Field-Emission of Thin-Walled, Open-Ended, and Well-Aligned N-Doped Carbon Nanotubes , 2010, Nanoscale research letters.

[39]  Y. Saito,et al.  Field emission from carbon nanotubes and its application to electron sources , 2000 .

[40]  J. Ager,et al.  Electron emission from films of carbon nanotubes and ta-C coated nanotubes , 1999 .

[41]  Niels de Jonge,et al.  Carbon nanotube electron sources and applications , 2004, Philosophical Transactions of the Royal Society of London. Series A: Mathematical, Physical and Engineering Sciences.

[42]  L. Nordheim The Effect of the Image Force on the Emission and Reflexion of Electrons by Metals , 1928 .

[43]  J. J. Vilatela,et al.  Yarn‐Like Carbon Nanotube Fibers , 2010, Advanced materials.

[44]  M. Pasquali,et al.  Demonstration of an Acid-Spun Single-Walled Nanotube Fiber Cathode , 2012, IEEE Transactions on Plasma Science.

[45]  M. Terranova,et al.  Capacitive and analytical approaches for the analysis of field emission from carbon nanotubes in a sphere-to-plane diode , 2007 .

[46]  Mei Zhang,et al.  Field emission of electrons by carbon nanotube twist-yarns , 2007 .

[47]  Enge Wang,et al.  Physical origin of non-linearity in Fowler–Nordheim plots of aligned large area multi-walled nitrogen-containing carbon nanotubes , 2002 .

[48]  C. Shon,et al.  Development of New X-Ray Source Based on Carbon Nanotube Field Emission and Application to the Non Destructive Imaging Technology , 2009, IEEE Transactions on Nuclear Science.

[49]  S. Roth,et al.  Field emission characteristics of point emitters fabricated by a multiwalled carbon nanotube yarn , 2009, Nanotechnology.

[50]  Yong Zhu,et al.  Wavy Ribbons of Carbon Nanotubes for Stretchable Conductors , 2012 .

[51]  Silvia Orlanducci,et al.  Photoconductivity of packed homotype bundles formed by aligned single-walled carbon nanotubes. , 2008, Nano letters.

[52]  Zhong Lin Wang,et al.  In situ imaging of field emission from individual carbon nanotubes and their structural damage , 2002 .

[53]  M. Terranova,et al.  Density Functional Study of H-induced Defects as Nucleation Sites in Hybrid Carbon Nanomaterials , 2005 .

[54]  G. V. Torgashov,et al.  Electron field emission from nanofilament carbon films , 1995 .