Enhancing interlaminar fracture characteristics of woven CFRP prepreg composites through CNT dispersion

The inter-ply characteristics of polymeric prepreg composites influence their interlaminar fracture toughness and the overall performance. This article embarks on engineering the inter-ply interfaces of carbon fiber reinforced polymer (CFRP) composites. A novel and practical technique for dispersion of multi-walled carbon nanotubes (MWCNTs) onto woven CFRP prepreg is presented. The interlaminar fracture toughness of these CFRP lay-ups was evaluated experimentally and compared with the regular (without any CNTs) specimen. Double cantilever beam and end notch flexure tests were conducted for interlaminar fracture studies. It was observed that the addition of MWCNTs in between the CFRP prepreg plies helps in strengthening the interface. There existed an optimum percentage in which these nanofillers should be added. The presence of nanotubes increased fiber bridging within the ply interfaces, which in turn controlled the inter-ply crack propagation. The findings and the mechanisms are discussed using the test data, SEM pictures, schematics, and scans of the fractured surfaces.

[1]  A. Bismarck,et al.  Carbon nanotube-based hierarchical composites: a review , 2010 .

[2]  Zhipei Sun,et al.  Nanotube–Polymer Composites for Ultrafast Photonics , 2009 .

[3]  Bodo Fiedler,et al.  FUNDAMENTAL ASPECTS OF NANO-REINFORCED COMPOSITES , 2006 .

[4]  Ajit K. Roy,et al.  Engineered interfaces in fiber reinforced composites , 1999 .

[5]  Bhanu Pratap Singh,et al.  Growth of carbon nanotubes on carbon fibre substrates to produce hybrid/phenolic composites with improved mechanical properties , 2008 .

[6]  Tomohiro Yokozeki,et al.  Matrix cracking behaviors in carbon fiber/epoxy laminates filled with cup-stacked carbon nanotubes (CSCNTs) , 2007 .

[7]  K. Unnikrishnan,et al.  Toughening of epoxy resins , 2006 .

[8]  Shaw-Ming Lee Mode II Interlaminar Crack Growth Process in Polymer Matrix Composites , 1999, Proceedings of the Eighth Japan-U.S. Conference on Composite Materials.

[9]  Pierre J. A. Minguet,et al.  Comparison of Delamination Characterization for IM7/8552 Composite Woven and Tape Laminates , 2003 .

[10]  John D. Whitcomb,et al.  Characterization of Mode I and mixed-mode delamination growth in T300/5208 graphite/epoxy , 1985 .

[11]  D. Ratna Modification of epoxy resins for improvement of adhesion: a critical review , 2003 .

[12]  M. Santare,et al.  Interlaminar shear strength of glass fiber reinforced epoxy composites enhanced with multi-walled carbon nanotubes , 2008 .

[13]  Yiu-Wing Mai,et al.  Dispersion and alignment of carbon nanotubes in polymer matrix: A review , 2005 .

[14]  C. Papaspyrides,et al.  The effect on the mechanical properties of carbon/epoxy composites of polyamide coatings on the fibers , 1999 .

[15]  Liyong Tong,et al.  3D Fibre Reinforced Polymer Composites , 2002 .

[16]  M. Hojo,et al.  Prestandardization study on mode II interlaminar fracture toughness test for cfrp in japan , 1995 .

[17]  Masahiro Arai,et al.  Mode I and mode II interlaminar fracture toughness of CFRP laminates toughened by carbon nanofiber interlayer , 2008 .

[18]  Israel Herszberg,et al.  Effect of weaving damage on the tensile properties of three-dimensional woven composites , 2002 .

[19]  Alkiviadis S. Paipetis,et al.  Enhanced Fracture Properties of Carbon Reinforced Composites by the Addition of Multi-Wall Carbon Nanotubes , 2009 .

[20]  Xujin Bao,et al.  Mechanical behaviour of advanced composite laminates embedded with carbon nanotubes: review , 2009, International Conference on Smart Materials and Nanotechnology in Engineering.

[21]  S. Tjong,et al.  Interlaminar Fracture Properties of Carbon Fibre/Epoxy Matrix Composites Interleaved with Polyethylene Terephthalate (Pet) Films , 2001 .

[22]  J. Coleman,et al.  Small but strong: A review of the mechanical properties of carbon nanotube–polymer composites , 2006 .

[23]  Liyong Tong,et al.  Effect of Long Multi-walled Carbon Nanotubes on Delamination Toughness of Laminated Composites , 2008 .

[24]  U. Sundararaj,et al.  Big returns from small fibers: A review of polymer/carbon nanotube composites , 2004 .

[25]  K. Gruenberg,et al.  Improved fracture toughness of carbon fiber composite functionalized with multi walled carbon nanotubes , 2008 .

[26]  M. Hojo,et al.  Mode I and Mode II Delamination Growth of Interlayer Toughened Carbon/Epoxy (T800H/3900-2) Composite System , 1995 .

[27]  Ignace Verpoest,et al.  Influence of carbon nanotube reinforcement on the processing and the mechanical behaviour of carbon fiber/epoxy composites , 2009 .

[28]  A. Mouritz,et al.  A mechanistic interpretation of the comparative in-plane mechanical properties of 3D woven, stitched and pinned composites , 2010 .

[29]  Luo Yu Xu,et al.  Effect of the Interfacial Interleaf to the Interlaminar Fracture and Intralaminar Fracture of a New BMI Matrix Composites System , 1994 .

[30]  Masaki Hojo,et al.  Modes I and II interlaminar fracture toughness and fatigue delamination of CF/epoxy laminates with self-same epoxy interleaf , 2006 .

[31]  R. Velmurugan,et al.  Influence of in-plane fibre orientation on mode I interlaminar fracture toughness of stitched glass/polyester composites , 2008 .

[32]  Hui-Ming Cheng,et al.  Micro-hardness and Flexural Properties of Randomly-oriented Carbon Nanotube Composites , 2003 .

[33]  P. Ajayan,et al.  Multifunctional composites using reinforced laminae with carbon-nanotube forests , 2006, Nature materials.

[34]  Tomohiro Yokozeki,et al.  Mechanical properties of CFRP laminates manufactured from unidirectional prepregs using CSCNT-dispersed epoxy , 2007 .

[35]  P. Moldenaers,et al.  Assessing the strengths and weaknesses of various types of pre-treatments of carbon nanotubes on the properties of polymer/carbon nanotubes composites: A critical review , 2010 .

[36]  D. Lagoudas,et al.  Processing and Characterization of Epoxy/SWCNT/Woven Fabric Composites , 2006 .

[37]  Y. Mai,et al.  Engineered interfaces in fiber reinforced composites , 1998 .

[38]  Jingli Shi,et al.  Fabrication and mechanical/conductive properties of multi-walled carbon nanotube (MWNT) reinforced carbon matrix composites , 2005 .

[39]  T. Uchida,et al.  A comparison of reinforcement efficiency of various types of carbon nanotubes in polyacrylonitrile fiber , 2005 .

[40]  Satoshi Kobayashi,et al.  Experimental characterization of the effects of stacking sequence on the transverse crack behavior in quasi-isotropic interleaved CFRP laminates , 2000 .

[41]  S. Chatterjee Analysis of Test Specimens for Interlaminar Mode II Fracture Toughness, Part 1. Elastic Laminates , 1991 .

[42]  S. Chatterjee Analysis of Test Specimens for Interlaminar Mode II Fracture Toughness, Part 2. Effects of Adhesive Layers and Material Nonlinearities , 1991 .

[43]  Adrian P. Mouritz,et al.  Review of applications for advanced three-dimensional fibre textile composites , 1999 .

[44]  T. Chou,et al.  Advances in the science and technology of carbon nanotubes and their composites: a review , 2001 .

[45]  Y. Mai,et al.  Numerical and experimental studies on the fracture behavior of rubber-toughened epoxy in bulk specimen and laminated composites , 2002 .

[46]  P. Jar,et al.  Analysis of specimen thickness effect on interlaminar fracture toughness of fibre composites using finite element models , 2003 .

[47]  J. Hodgkinson,et al.  9 – Interlaminar fracture toughness , 2000 .