Graphene-Enabled Adaptive Infrared Textiles.

Interactive clothing requires sensing and display functionalities to be embedded on textiles. Despite the significant progress of electronic textiles, the integration of optoelectronic materials on fabrics remains as an outstanding challenge. In this Letter, using the electro-optical tunability of graphene, we report adaptive optical textiles with electrically controlled reflectivity and emissivity covering the infrared and near-infrared wavelengths. We achieve electro-optical modulation by reversible intercalation of ions into graphene layers laminated on fabrics. We demonstrate a new class of infrared textile devices including display, yarn, and stretchable devices using natural and synthetic textiles. To show the promise of our approach, we fabricated an active device directly onto a t-shirt, which enables long-wavelength infrared communication via modulation of the thermal radiation from the human body. The results presented here provide complementary technologies which could leverage the ubiquitous use of functional textiles.

[1]  Ali Khademhosseini,et al.  A Textile Dressing for Temporal and Dosage Controlled Drug Delivery , 2017 .

[2]  Wei Zhang,et al.  Continuous and scalable manufacture of amphibious energy yarns and textiles , 2019, Nature Communications.

[3]  Haiwen Luan,et al.  Skin-integrated wireless haptic interfaces for virtual and augmented reality , 2019, Nature.

[4]  K. Mak,et al.  Optical spectroscopy of graphene: From the far infrared to the ultraviolet , 2012 .

[5]  Lijun Qu,et al.  Stretchable Conductive Fibers of Ultra-high Tensile Strain and Stable Conductance Enabled by Worm-shape Graphene Microlayer. , 2019, Nano letters.

[6]  Andrew Pavelchek,et al.  Long-wave infrared (10-μm) free-space optical communication system , 2004, SPIE Optics + Photonics.

[7]  A review , 2019 .

[8]  Coskun Kocabas,et al.  Observation of gate-tunable coherent perfect absorption of terahertz radiation in graphene , 2016, 1801.04640.

[9]  Lin Jia,et al.  Epidermal photonic devices for quantitative imaging of temperature and thermal transport characteristics of the skin , 2014, Nature Communications.

[10]  Lijun Qu,et al.  Multiscale Disordered Porous Fibers for Self-Sensing and Self-Cooling Integrated Smart Sportswear. , 2019, ACS nano.

[11]  Alex Y. Song,et al.  A dual-mode textile for human body radiative heating and cooling , 2017, Science Advances.

[12]  Yong-Seung Chi,et al.  Electromagnetic Shielding Effectiveness of Multifunctional Metal Composite Fabrics , 2008 .

[13]  E. O. Polat,et al.  Graphene-Enabled Optoelectronics on Paper , 2016, 1801.04616.

[14]  K. Novoselov,et al.  The mechanics of graphene nanocomposites: A review , 2012 .

[15]  Yoel Fink,et al.  Diode fibres for fabric-based optical communications , 2018, Nature.

[16]  Byoung Hun Lee,et al.  Robust and stretchable indium gallium zinc oxide-based electronic textiles formed by cilia-assisted transfer printing , 2016, Nature Communications.

[17]  YuHuang Wang,et al.  Dynamic gating of infrared radiation in a textile , 2019, Science.

[18]  Sam Emaminejad,et al.  Fully integrated wearable sensor arrays for multiplexed in situ perspiration analysis , 2016, Nature.

[19]  Jung Woo Lee,et al.  Rugged and breathable forms of stretchable electronics with adherent composite substrates for transcutaneous monitoring , 2014, Nature Communications.

[20]  intelligent textiles , 2022, The Fairchild Books Dictionary of Fashion.

[21]  Coskun Kocabas,et al.  Graphene-enabled electrically switchable radar-absorbing surfaces , 2015, Nature Communications.

[22]  Zongfu Yu,et al.  Enhancing far-field thermal emission with thermal extraction , 2013, Nature Communications.

[23]  Xuli Chen,et al.  Electrochromatic carbon nanotube/polydiacetylene nanocomposite fibres. , 2009, Nature nanotechnology.

[24]  Sheng Xu,et al.  Wearable thermoelectrics for personalized thermoregulation , 2019, Science Advances.

[25]  Alexander Schwarz Adaptive camouflage in the VIS and IR spectral range: main principles and mechanisms , 2015, SPIE Security + Defence.

[26]  Omer Salihoglu,et al.  Graphene-Based Adaptive Thermal Camouflage. , 2018, Nano letters.

[27]  R. Langley,et al.  Dual-Band Wearable Textile Antenna on an EBG Substrate , 2009, IEEE Transactions on Antennas and Propagation.

[28]  Nazmul Karim,et al.  Ultraflexible and robust graphene supercapacitors printed on textiles for wearable electronics applications , 2017 .

[29]  Michele Caldara,et al.  Optical monitoring of sweat pH by a textile fabric wearable sensor based on covalently bonded litmus-3-glycidoxypropyltrimethoxysilane coating , 2016 .

[30]  Q. Pei,et al.  A colour-tunable, weavable fibre-shaped polymer light-emitting electrochemical cell , 2015, Nature Photonics.

[31]  Zhiping Mao,et al.  Infrared stealth property based on semiconductor (M)-to-metallic (R) phase transition characteristics of W-doped VO2 thin films coated on cotton fabrics , 2014 .

[32]  Yi Cui,et al.  Personal thermal management by metallic nanowire-coated textile. , 2015, Nano letters.

[33]  Shanhui Fan,et al.  Radiative human body cooling by nanoporous polyethylene textile , 2016, Science.