Calendar ageing and health diagnosis of supercapacitor

Abstract A new method of supercapacitor online health diagnosis based on an electric model and on experimental results obtained by calendar ageing tests is proposed. The calendar ageing of supercapacitor is mainly related to thermal and voltage constraints from the application. This ageing causes the degradation of supercapacitor performances which can finally lead to failures. In vehicle applications, the goal is to avoid these failures which may have serious consequences and high non-quality costs. The device survey and ageing state detection are a priority for anticipating the problems. This paper presents the case of calendar ageing tests on supercapacitors made of activated carbon and organic electrolyte. The ageing is performed at constant temperature (65 °C) under a 2.9 Vdc bias voltage. These tests permit to highlight online and in real-time the measurable external indicators of ageing.

[1]  R. Gallay,et al.  Pressure evolution in propylene carbonate based electrochemical double layer capacitors , 2006 .

[2]  R. Bonert,et al.  Characterization of double-layer capacitors (DLCs) for power electronics applications , 1998, Conference Record of 1998 IEEE Industry Applications Conference. Thirty-Third IAS Annual Meeting (Cat. No.98CH36242).

[3]  O. Briat,et al.  Impact of the ageing of supercapacitors in power cycling on the behaviour of hybrid electric vehicles applications , 2010, 2010 IEEE Vehicle Power and Propulsion Conference.

[4]  Dominique Massiot,et al.  Causes of supercapacitors ageing in organic electrolyte , 2007 .

[5]  Dirk Uwe Sauer,et al.  Ageing behaviour of electrochemical double layer capacitors: Part II. Lifetime simulation model for dynamic applications , 2007 .

[6]  Doron Aurbach,et al.  Carbon Electrodes for Double‐Layer Capacitors I. Relations Between Ion and Pore Dimensions , 2000 .

[7]  Dirk Uwe Sauer,et al.  Ageing behaviour of electrochemical double layer capacitors. Part I. Experimental study and ageing model , 2007 .

[8]  Amrane Oukaour,et al.  Supercapacitor ageing at constant temperature and constant voltage and thermal shock , 2010, Microelectron. Reliab..

[9]  Michael Holzapfel,et al.  An in situ Raman study of the intercalation of supercapacitor-type electrolyte into microcrystalline graphite , 2006 .

[10]  Masatoshi Uno,et al.  Accelerated Charge–Discharge Cycling Test and Cycle Life Prediction Model for Supercapacitors in Alternative Battery Applications , 2012, IEEE Transactions on Industrial Electronics.

[11]  Hamid Gualous,et al.  Thermal modeling and heat management of supercapacitor modules for vehicle applications , 2009 .

[12]  Pascal Venet,et al.  Study of Accelerated Aging of Supercapacitors for Transport Applications , 2010, IEEE Transactions on Industrial Electronics.

[13]  Roberto Faranda,et al.  A new parameters identification procedure for simplified double layer capacitor two-branch model , 2010 .

[14]  R.W. De Doncker,et al.  Analysis and evaluation of charge-balancing circuits on performance, reliability, and lifetime of supercapacitor systems , 2003, IEEE Transactions on Industry Applications.

[15]  R. Gallay,et al.  Carbon based double layer capacitors with aprotic electrolyte solutions: the possible role of intercalation/insertion processes , 2006 .

[16]  Rik W. De Doncker,et al.  Analysis and evaluation of charge balancing circuits on performance, reliability and lifetime of supercapacitor systems , 2003, 38th IAS Annual Meeting on Conference Record of the Industry Applications Conference, 2003..

[17]  Hamid Gualous,et al.  Frequency, thermal and voltage supercapacitor characterization and modeling , 2007 .

[18]  Rüdiger Kötz,et al.  Aging and failure mode of electrochemical double layer capacitors during accelerated constant load tests , 2010 .

[19]  P. Kurzweil,et al.  Electrochemical stability of organic electrolytes in supercapacitors: Spectroscopy and gas analysis of decomposition products , 2008 .

[20]  D. Linzen Analysis and Evaluation of Charge-Balancing Circuits on Performance, Reliability, and Lifetime of Supercapacitor System , 2005 .