Hydrothermal catalytic production of fuels and chemicals from aquatic biomass

One of the promising avenues for biomass processing is the use of water as a reaction medium for wet or aquatic biomass. This review focuses on the hydrothermal catalytic production of fuels and chemicals from aquatic biomass. Two different regimes for conversion of aquatic biomass in hydrothermal conditions are discussed in detail. The first is hydrothermal liquefaction, and the second is hydrothermal gasification. The goals of these processes are to produce liquid-fuel-range hydrocarbons and methane or hydrogen, respectively. The catalytic upgrading of biocrude resulting from noncatalytic liquefaction and the stability and degradation of catalysts in high temperature water are also discussed. The review concludes with a brief discussion of the outlook for and opportunities within the field of hydrothermal catalytic valorization of biomass. Copyright © 2012 Society of Chemical Industry

[1]  Michael Jerry Antal,et al.  Carbon-Catalyzed Gasification of Organic Feedstocks in Supercritical Water† , 1996 .

[2]  Phillip E. Savage,et al.  A perspective on catalysis in sub- and supercritical water , 2009 .

[3]  Li Chun,et al.  Production and characterization of bio-oil from hydrothermal liquefaction of microalgae Dunaliella tertiolecta cake , 2010 .

[4]  Yang Guo,et al.  Review of catalytic supercritical water gasification for hydrogen production from biomass , 2010 .

[5]  P. Savage,et al.  Hydrothermal decarboxylation and hydrogenation of fatty acids over Pt/C. , 2011, ChemSusChem.

[6]  Minghan Zhu,et al.  Hydrothermal reaction kinetics and pathways of phenylalanine alone and in binary mixtures. , 2012, ChemSusChem.

[7]  P. Savage,et al.  Triflate-catalyzed (trans)esterification of lipids within carbonized algal biomass. , 2012, Bioresource technology.

[8]  F. Krumeich,et al.  Synthetic natural gas by hydrothermal gasification of biomass: Selection procedure towards a stable catalyst and its sodium sulfate tolerance , 2007 .

[9]  Frédéric Vogel,et al.  Catalytic gasification of algae in supercritical water for biofuel production and carbon capture , 2009 .

[10]  S. Rogak,et al.  Solubility of Na2SO4, Na2CO3 and their mixture in supercritical water , 2004 .

[11]  P. Savage,et al.  Catalytic treatment of crude algal bio-oil in supercritical water: optimization studies , 2011 .

[12]  P. Savage,et al.  Catalytic hydrotreatment of crude algal bio-oil in supercritical water , 2011 .

[13]  Yutaka Dote,et al.  Recovery of liquid fuel from hydrocarbon-rich microalgae by thermochemical liquefaction , 1994 .

[14]  A. Kruse,et al.  Gasification of Pyrocatechol in Supercritical Water in the Presence of Potassium Hydroxide , 2000 .

[15]  Phillip E. Savage,et al.  Hydrothermal Liquefaction of a Microalga with Heterogeneous Catalysts , 2011 .

[16]  P. Savage,et al.  Chapter 8:Hydrothermal Processing of Biomass , 2010 .

[17]  Douglas C. Elliott,et al.  Chemical Processing in High-Pressure Aqueous Environments. 8. Improved Catalysts for Hydrothermal Gasification , 2006 .

[18]  I. Wender,et al.  Converting organic wastes to oil , 1972 .

[19]  P. Savage,et al.  Hydrothermal Gasification of Nannochloropsis sp. with Ru/C , 2012 .

[20]  Amanda Lea-Langton,et al.  Hydrothermal processing of microalgae using alkali and organic acids , 2010 .

[21]  W. Yuan,et al.  Catalytic denitrogenation of hydrocarbons through partial oxidation in supercritical water , 2006 .

[22]  K. Das,et al.  Effect of operating conditions of thermochemical liquefaction on biocrude production from Spirulina platensis. , 2011, Bioresource technology.

[23]  Edward N. Coppola,et al.  Catalytic Hydrothermal Conversion of Triglycerides to Non-ester Biofuels , 2010 .

[24]  W. Yuan,et al.  Catalytic desulfurization of residual oil through partial oxidation in supercritical water , 2005 .

[25]  Masaru Watanabe,et al.  Catalytic Hydrodesulfurization of Dibenzothiophene through Partial Oxidation and a Water−Gas Shift Reaction in Supercritical Water , 1998 .

[26]  Kristina M. Weyer,et al.  Theoretical Maximum Algal Oil Production , 2009, BioEnergy Research.

[27]  P. Biller,et al.  Potential yields and properties of oil from the hydrothermal liquefaction of microalgae with different biochemical content. , 2011, Bioresource technology.

[28]  D. Fabbri,et al.  Hydrothermal Treatment (HTT) of Microalgae: Detailed Molecular Characterization of HTT Oil in View of HTT Mechanism Elucidation , 2012 .

[29]  Phillip E. Savage,et al.  Biodiesel Production from Wet Algal Biomass through in Situ Lipid Hydrolysis and Supercritical Transesterification , 2010 .

[30]  Phillip E. Savage,et al.  Hydrothermal Liquefaction and Gasification of Nannochloropsis sp. , 2010 .

[31]  J. Crittenden,et al.  Effects of Metal Precursors on the Stability and Observed Reactivity of Pt/γ‐Al2O3 Catalysts in Aqueous Phase Reactions , 2012 .

[32]  Phillip E. Savage,et al.  Activated Carbons for Hydrothermal Decarboxylation of Fatty Acids , 2011 .

[33]  Dmitry Yu. Murzin,et al.  Heterogeneous Catalytic Deoxygenation of Stearic Acid for Production of Biodiesel , 2006 .

[34]  Phillip E. Savage,et al.  Catalytic hydrothermal deoxygenation of palmitic acid , 2010 .

[35]  P. T. Vasudevan,et al.  Biodiesel production—current state of the art and challenges , 2008, Journal of Industrial Microbiology & Biotechnology.

[36]  Masaru Watanabe,et al.  Catalytic effects of NaOH and ZrO2 for partial oxidative gasification of n-hexadecane and lignin in supercritical water☆ , 2003 .

[37]  Shicheng Zhang,et al.  Hydrothermal Liquefaction of Macroalgae Enteromorpha prolifera to Bio-oil , 2010 .

[38]  D. Elliott,et al.  Chemical processing in high-pressure aqueous environments : Low-temperature catalytic gasification , 1996 .

[39]  Sascha R.A. Kersten,et al.  Hydrothermal Treatment (HTT) of Microalgae: Evaluation of the Process As Conversion Method in an Algae Biorefinery Concept , 2012 .

[40]  Douglas C. Elliott,et al.  Catalytic hydrothermal gasification of biomass , 2008 .

[41]  Mark Crocker,et al.  Thermochemical conversion of biomass to liquid fuels and chemicals , 2010 .

[42]  J. Crittenden,et al.  Structural Changes of γ-Al2O3-Supported Catalysts in Hot Liquid Water , 2011 .

[43]  Chuanping Feng,et al.  Analysis of energy conversion characteristics in liquefaction of algae , 2004 .

[44]  K. Das,et al.  Comparative Evaluation of Thermochemical Liquefaction and Pyrolysis for Bio-Oil Production from Microalgae , 2011 .

[45]  Michimasa Kishimoto,et al.  Oil production from algal cells of Dunaliella tertiolecta by direct thermochemical liquefaction , 1995 .

[46]  Peigao Duan,et al.  Upgrading of crude algal bio-oil in supercritical water. , 2011, Bioresource technology.

[47]  Yutaka Dote,et al.  Studies on the direct liquefaction of protein-contained biomass: The distribution of nitrogen in the products , 1996 .

[48]  D. Pimentel,et al.  Ethanol Production Using Corn, Switchgrass, and Wood; Biodiesel Production Using Soybean and Sunflower , 2005 .

[49]  Yutaka Dote,et al.  Analysis of oil derived from liquefaction of Botryococcus Braunii , 1994 .

[50]  Phillip E. Savage,et al.  Catalytic hydrothermal hydrodenitrogenation of pyridine , 2011 .

[51]  E. Gloyna,et al.  Solubility of potassium hydroxide and potassium phosphate in supercritical water , 1995 .

[52]  Morgan Fröling,et al.  Thermochemical biofuel production in hydrothermal media: A review of sub- and supercritical water technologies , 2008 .

[53]  E. Becker Micro-algae as a source of protein. , 2007, Biotechnology advances.

[54]  P. Savage,et al.  Deoxygenation of benzofuran in supercritical water over a platinum catalyst , 2012 .

[55]  B. Dale,et al.  Global potential bioethanol production from wasted crops and crop residues , 2004 .

[56]  Yutaka Dote,et al.  Distribution of nitrogen to oil products from liquefaction of amino acids , 1998 .

[57]  W. Wiseman,et al.  Gulf of Mexico Hypoxia, A.K.A. “The Dead Zone” , 2002 .

[58]  N. Lewis,et al.  Powering the planet: Chemical challenges in solar energy utilization , 2006, Proceedings of the National Academy of Sciences.

[59]  J. Crittenden,et al.  Stability of Pt/γ-Al2O3 Catalysts in Model Biomass Solutions , 2012, Topics in Catalysis.

[60]  Michael A. Wilson,et al.  Catalytic upgrading of biorefinery oil from micro-algae , 2010 .

[61]  Toru Iida,et al.  Decomposition of a long chain saturated fatty acid with some additives in hot compressed water , 2006 .

[62]  Frédéric Vogel,et al.  SunCHem: an integrated process for the hydrothermal production of methane from microalgae and CO2 mitigation , 2009, Journal of Applied Phycology.

[63]  Derk Willem Frederik Brilman,et al.  Catalytic and Non-catalytic Supercritical Water Gasification of Microalgae and Glycerol , 2010 .

[64]  R. Smith,et al.  Catalytic decarboxylation of acetic acid with zirconia catalyst in supercritical water , 2001 .

[65]  Phillip E. Savage,et al.  Characterization of Product Fractions from Hydrothermal Liquefaction of Nannochloropsis sp. and the Influence of Solvents , 2011 .

[66]  Gregory E Schwarz,et al.  Differences in phosphorus and nitrogen delivery to the Gulf of Mexico from the Mississippi River Basin. , 2008, Environmental science & technology.

[67]  M. Shirai,et al.  Effect of Sulfur on Catalytic Gasification of Lignin in Supercritical Water , 2007 .

[68]  A. Corma,et al.  Synthesis of transportation fuels from biomass: chemistry, catalysts, and engineering. , 2006, Chemical reviews.

[69]  Philip Owende,et al.  Biofuels from microalgae—A review of technologies for production, processing, and extractions of biofuels and co-products , 2010 .