The effect of AlN buffer layer on GaN grown on (111)-oriented Si substrates by MOCVD

GaN films were grown by metal organic chemical vapor deposition on (1 1 1)Si substrates, using AlN as a buffer layer. The influence of the AlN buffer layer growth temperature and growth duration on the morphology and preferred orientation of GaN films was studied. Drastic enhancement of epitaxial registration was observed with increasing buffer growth temperature. A sharp transition in the growth mode occurred at 760°C. For that temperature, an optimal buffer layer growth duration was found. The use of March parameter as a figure of merit in X-ray diffraction testing of textured GaN films is proposed.

[1]  M. Tischler,et al.  MOVPE Growth of High Electron Mobility AlGaN/GaN Heterostructures , 1995 .

[2]  D. W. Pashley The nucleation, growth, structure and epitaxy of thin surface films , 1965 .

[3]  R. Gaska,et al.  Visible-blind GaN Schottky barrier detectors grown on Si(111) , 1998 .

[4]  Lianshan Wang,et al.  Wurtzite GaN epitaxial growth on a Si(001) substrate using γ-Al2O3 as an intermediate layer , 1998 .

[5]  D. K. Bowen,et al.  High Resolution X-Ray Diffractometry And Topography , 1998 .

[6]  H. Amano,et al.  Metalorganic vapor phase epitaxial growth of a high quality GaN film using an AlN buffer layer , 1986 .

[7]  D. Bimberg,et al.  Low-pressure metal organic chemical vapor deposition of GaN on silicon(111) substrates using an AlAs nucleation layer , 1999 .

[8]  D. Buchanan,et al.  Nucleation of AlN on the (7×7) Reconstructed Silicon (1 1 1) Surface , 1998 .

[9]  B. Warren,et al.  X-Ray Diffraction , 2014 .

[10]  W. A. Dollase,et al.  Correction of intensities for preferred orientation in powder diffractometry: application of the March model , 1986 .

[11]  N. Bojarczuk,et al.  GaN based light emitting diodes grown on Si(111) by molecular beam epitaxy , 1997 .

[12]  K. S. Stevens,et al.  Photoconductive ultraviolet sensor using Mg‐doped GaN on Si(111) , 1995 .

[13]  Ullrich Pietsch,et al.  High-Resolution X-Ray Scattering from Thin Films and Multilayers , 1998 .

[14]  H. Amano,et al.  Growth of single crystalline GaN film on Si substrate using 3C-SiC as an intermediate layer , 1991 .

[15]  T. Sasaki Surface morphology of MOVPE-grown GaN on (0001) sapphire , 1993 .

[16]  Henryk Temkin,et al.  High quality GaN–InGaN heterostructures grown on (111) silicon substrates , 1996 .

[17]  Nobuhiko P. Kobayashi,et al.  GaN growth on Si(111) substrate using oxidized AlAs as an intermediate layer , 1997 .

[18]  Isamu Akasaki,et al.  The growth of single crystalline GaN on a Si substrate using AIN as an intermediate layer , 1993 .