Focus on the cold and ultracold chemistry of atoms, ions and molecules

Understanding and controlling the interactions of matter at cold and ultracold temperatures is of paramount importance in several fields of contemporary physics and beyond. Recent progress has helped shedding light onto central questions, such as how particles interact in a regime in which quantum effects significantly contribute or even dominate the interparticle interactions, and how this new insight can be used to advance applications, such as quantum chemistry, precision measurements, fundamental physics, quantum simulation and quantum information processing (QIP). For this research, different systems are used including atomic and molecular ensembles, as well as hybrid systems, such as ion-atom mixtures. This focus issue puts a spotlight on recent advances in the field of cold and ultracold chemistry. The original contributions to this issue [1–22] represent a broad spectrum of experimental and theoretical work in this truly interdisciplinary research area at the interface between physics and chemistry. Core research questions in this issue revolve around the study and control of cold and ultracold collisions involving atoms, molecules and ions. Apart from that, also the efficient production of cold and ultracold molecules remains a hot topic. In the following, we put these advances into perspective.

[1]  D. Comparat,et al.  Efficient rotational cooling of a cold beam of barium monofluoride , 2022, New Journal of Physics.

[2]  M. Lemeshko,et al.  A simple model for high rotational excitations of molecules in a superfluid , 2022, New Journal of Physics.

[3]  J. Kłos,et al.  Prospects for assembling ultracold radioactive molecules from laser-cooled atoms , 2021, New Journal of Physics.

[4]  R. Gerritsma,et al.  Buffer gas cooling of ions in radio-frequency traps using ultracold atoms , 2021, 2109.15195.

[5]  G. Groenenboom,et al.  Ab initio study of the reactivity of ultracold RbSr + RbSr collisions , 2021, New Journal of Physics.

[6]  Anna Dawid,et al.  Controlling the dynamics of ultracold polar molecules in optical tweezers , 2021, New Journal of Physics.

[7]  S. Cornish,et al.  Molecule–molecule and atom–molecule collisions with ultracold RbCs molecules , 2021, New Journal of Physics.

[8]  J. Hutson,et al.  Complexes formed in collisions between ultracold alkali-metal diatomic molecules and atoms , 2021, New Journal of Physics.

[9]  F. Merkt,et al.  Cold ion chemistry within a Rydberg-electron orbit: test of the spectator role of the Rydberg electron in the He(n) + CO → C(n′) + O + He reaction , 2021, New Journal of Physics.

[10]  B. Iritani,et al.  Ultracold 88Sr2 molecules in the absolute ground state , 2021, New Journal of Physics.

[11]  Hua Guo,et al.  Determining reaction pathways at low temperatures by isotopic substitution: the case of BeD + + H2O , 2021, New Journal of Physics.

[12]  G. Meijer,et al.  A new design for a traveling-wave Zeeman decelerator: I. Theory , 2021, New Journal of Physics.

[13]  G. Meijer,et al.  A new design for a traveling-wave Zeeman decelerator: II. Experiment , 2021, New Journal of Physics.

[14]  O. Dulieu,et al.  Characterization of the lowest electronically excited-state ro-vibrational level of 23Na87Rb , 2021, New Journal of Physics.

[15]  J. Kłos,et al.  Relativistic aspects of orbital and magnetic anisotropies in the chemical bonding and structure of lanthanide molecules , 2021, New Journal of Physics.

[16]  T. Langen,et al.  A laser cooling scheme for precision measurements using fermionic barium monofluoride (137Ba19F) molecules , 2021, 2106.13177.

[17]  M. Tomza Interaction potentials, electric moments, polarizabilities, and chemical reactions of YbCu, YbAg, and YbAu molecules , 2021, 2105.11426.

[18]  C. Rich,et al.  Collisions in a dual-species magneto-optical trap of molecules and atoms , 2021, New Journal of Physics.

[19]  S. Cornish,et al.  Preparation of one 87Rb and one 133Cs atom in a single optical tweezer , 2021, New Journal of Physics.

[20]  G. Meijer,et al.  Optical cycling of AlF molecules , 2021, New Journal of Physics.

[21]  Jian-Wei Pan,et al.  Magnetic Feshbach resonances in collisions of 23Na40K with 40K , 2021, New Journal of Physics.

[22]  K. Ni,et al.  Assembly of a Rovibrational Ground State Molecule in an Optical Tweezer. , 2021, Physical review letters.

[23]  J. Denschlag,et al.  Direct observation of swap cooling in atom–ion collisions , 2020, New Journal of Physics.

[24]  W. Ketterle,et al.  Observation of Collisions between Two Ultracold Ground-State CaF Molecules. , 2020, Physical review letters.

[25]  M. Tomza,et al.  Cold hybrid ion-atom systems , 2017, Reviews of Modern Physics.

[26]  M. R. Tarbutt,et al.  Laser cooling of molecules , 2018, Contemporary Physics.

[27]  Jun Ye,et al.  Cold molecules: Progress in quantum engineering of chemistry and quantum matter , 2017, Science.

[28]  M. Rosa Laser-cooling molecules , 2004 .