论文信息 - Statistical Mechanics of Cross‐Linked Polymer Networks I. Rubberlike Elasticity

Statistical Mechanics of Cross‐Linked Polymer Networks I. Rubberlike Elasticity

A model is proposed for the structure of a cross‐linked network, such as exists in a vulcanized rubber, which is amenable to statistical treatment. Expressions are derived for the structural entropy of the network, and for the entropy change on deformation. The latter is in agreement with the relationship derived by Wall and others by a different treatment.

P. Flory | J. Rehner

[1] P. Flory,et al. STATISTICAL MECHANICS OF CROSS-LINKED POLYMER NETWORKS II. SWELLING , 1943 .

[2] Hubert M. James,et al. Theory of the Elastic Properties of Rubber , 1943 .

[3] L. Treloar. Thermodynamic study of the elastic extension of rubber , 1942 .

[4] Paul J. Flory,et al. Molecular Size Distribution in Three Dimensional Polymers. I. Gelation1 , 1941 .

[5] R. Norrish,et al. The formation and structure of polymers of the insoluble cross-linked type , 1937 .

[6] Paul J. Flory,et al. Molecular Size Distribution in Linear Condensation Polymers1 , 1936 .

[7] W. Kuhn,et al. Beziehungen zwischen Molekülgröße, statistischer Molekülgestalt und elastischen Eigenschaften hochpolymerer Stoffe , 1936 .

[8] H. Staudinger,et al. The insoluble polystyrene , 1936 .

[9] K. Meyer,et al. Sur l'élasticité du caoutchouc , 1935 .

[10] E. Guth,et al. Zur innermolekularen, Statistik, insbesondere bei Kettenmolekiilen I , 1934 .

[11] W. Kuhn,et al. Über die Gestalt fadenförmiger Moleküle in Lösungen , 1934 .

[12] K. Meyer,et al. Die elastischen Eigenschaften der organischen Hochpolymeren und ihre kinetische Deutung , 1932 .

[13] Henry Eyring,et al. The Resultant Electric Moment of Complex Molecules , 1932 .