ANALYSIS OF IONIC IMPURITIES IN ELECTRICAL ROTATING MACHINES INSULATORS BY ANALYTICAL TECHNIQUES

The insulation used in electrical rotating machines is a major component that influences their operation parameters. It is therefore essential to identify the methods of investigation and new technological processes to improve quality of the insulation. Traces of transition metals have been found in the insulation of cables PE. These transition metals causes degradation of insulation, affect its insulating properties and can lead to undesired electrochemical processes under the electrical stress factor. Traces of transition metals in insulator can be determined only by means of atomic and nuclear techniques of high sensitivity and precision. In this paper are presented some analytical techniques that can be used in the analysis of insulators in order to establish the most suitable method to determine the concentrations of ionic impurities. By technique Inductively Coupled Plasma Mass Spectrometry – ICP-MS, were identified and quantitative determined in insulator the following chemical elements: Cu, Pb, Zn, Cr, Cd, Al, Ni, Co, Fe and Mn.

[1]  I. Popescu,et al.  Comparative Studies of Metal Air Pollution by Atomic Spectrometry Techniques and Biomonitoring with Moss and Lichens , 2012, Bulletin of Environmental Contamination and Toxicology.

[2]  I. Popescu,et al.  Analytical Applications Of Particle‐Induced X‐Ray Emission (PIXE) , 2007 .

[3]  A. Stefánsson,et al.  New methods for the direct determination of dissolved inorganic, organic and total carbon in natural waters by Reagent-Free Ion Chromatography and inductively coupled plasma atomic emission spectrometry. , 2007, Analytica chimica acta.

[4]  I. Popescu,et al.  Air pollution studies using PIXE and ICP methods , 2006 .

[5]  A. Pantelică,et al.  EDXRF versus INAA in a pollution control of soil , 2006 .

[6]  E. Steinnes Neutron Activation Techniques in Environmental Studies , 2004 .

[7]  M. Frontasyeva,et al.  Contamination of crop vegetation with trace elements from a fertilizer plant: An INAA study , 2004 .

[8]  I. Popescu,et al.  Particle Induced X-Ray Emission (PIXE) Analysis of Basella Alba L Leaves , 2000 .

[9]  J. Campbell,et al.  Quantitative PIXE microanalysis of thick specimens , 1993 .

[10]  W. Maenhaut Recent advances in nuclear and atomic spectrometric techniques for trace element analysis. A new look at the position of PIXE , 1990 .

[11]  I. Ioniţă,et al.  THE BEHAVIOR OF UNDERGROUND POWER CABLES UNDER THE ACTION OF STRESS FACTORS , 2014 .

[12]  A. Gheboianu,et al.  STUDIES ON ACCUMULATION OF HEAVY METALS FROM SUBSTRATE TO EDIBLE WILD MUSHROOMS , 2011 .

[13]  A. Gheboianu,et al.  Environmental samples analysis by atomic absorption spectrometry (AAS) and inductively coupled plasma-optical emission spectroscopy (ICP-AES) , 2009 .

[14]  I. Popescu,et al.  Applications of proton-induced X-ray emission technique in materials and environmental science , 2009 .

[15]  Andrzej A. Markowicz,et al.  Handbook of X-Ray Spectrometry , 2002 .

[16]  B. Welz Atomic absorption spectrometry , 1985 .

[17]  Eugene P. Bertin,et al.  Principles and Practice of X-Ray Spectrometric Analysis , 1970 .