Development of an advanced computer simulation technique for the modeling of rubber curing process

This research work is devoted to the development of an advanced computational technique for the simulation of the rubber curing process. The main novelty of the work is to cover the most important features that have not been addressed in the previous works. These include the use of incompatible meshes, thermal contact between rubber and mold, more accurate models for the description of the variation of rubber thermal properties with temperature and state-of-cure, use of a modified kinetic model and development of more robust auxiliary computer code. The general purpose finite element code ABAQUS has been used in conjunction with an in-house written subroutine (UMATHT) to solve the heat conduction equation and the rubber cure kinetics, simultaneously. It is used to simulate the curing process of a thick rubber article in the mold and the post-cure stage. The results were compared with experimentally measured data (temperature and state-of-cure) which confirmed the accuracy and applicability of the method.

[1]  Xiangqiao Yan,et al.  Finite Element Analysis of Tire Curing Process , 2003 .

[2]  A. Marzocca,et al.  Vulcanization kinetic of styrene–butadiene rubber by sulfur/TBBS , 2006 .

[3]  J. Vergnaud,et al.  Kinetic parameters of the overall reaction of scrap rubber vulcanization by 2% sulfur , 1982 .

[4]  B. Rochette,et al.  Effect of a variation in kinetic parameters (rate constant, activation energy) on the vulcanization of rubber sheets in injection molding process , 1985 .

[5]  Mir Hamid Reza Ghoreishy,et al.  Three-dimensional Finite Element Modeling of Rubber Curing Process , 2005 .

[6]  A. Isayev,et al.  Reduced Time Approach to Curing Kinetics, Part I: Dynamic Rate and Master Curve from Isothermal Data , 1993 .

[7]  W. J. Toth,et al.  Finite Element Evaluation of the State of Cure in a Tire , 1991 .

[8]  G. Nasr,et al.  Thermal and thermoelastic properties of fast extrusion furnace (FEF) carbon black loaded SBR vulcanizates , 1995 .

[9]  Leroy S. Fletcher,et al.  Thermal contact conductance of selected polymeric materials , 1996 .

[10]  D. Hands,et al.  The Thermal Diffusivity and Conductivity of Natural Rubber Compounds , 1977 .

[11]  K. A. Narh,et al.  Finite size gap effects on the modeling of thermal contact conductance at polymer-mold wall interface in injection molding , 2000 .

[12]  A. Marzocca,et al.  Some considerations concerning the dynamic mechanical properties of cured styrene–butadiene rubber/polybutadiene blends , 2000 .

[13]  Xiangqiao Yan A Numerical Modeling of Dynamic Curing Process of Tire by Finite Element , 2007 .

[14]  A. Marzocca,et al.  An analysis of the influence of the accelerator/sulfur ratio in the cure reaction and the uniaxial stress‐strain behavior of SBR , 2004 .

[15]  J. R. Maccallum,et al.  Derivation of Rate Equations used in Thermogravimetry , 1970, Nature.

[16]  A. Isayev,et al.  Nonisothermal Vulcanization of Rubber Compounds , 1988 .

[17]  A. Marzocca Finite element analysis of cure in a rubber cylinder , 1991 .