NANOMATERIALS AS OPTICAL LIMITERS

Optical limiters based on several different classes of nanomaterials are reviewed. The systems under consideration include metal and semiconductor nanoparticles and nanoscale carbon materials. For the latter, the optical limiting properties of carbon nanoparticles, fullerenes, and suspended and solubilized carbon nanotubes are summarized and compared. Mechanistic implications of the available experimental results are discussed in terms of the comparison between nonlinear scattering versus nonlinear absorption as the dominating optical limiting mechanism for different nanomaterials and for different physico-chemical states of a nanomaterial.

[1]  R. Sutherland,et al.  Nonlinear absorption study of a C60-toluene solution. , 1993, Optics letters.

[2]  W. Ji,et al.  LARGE NONLINEAR ABSORPTION IN COATED AG2S/CDS NANOPARTICLES BY INVERSE MICROEMULSION , 1998 .

[3]  Jason E. Riggs,et al.  Non-linear absorptions in pendant[60]fullerene–polystyrene polymers , 1997 .

[4]  François Hache,et al.  Optical limiting properties of singlewall carbon nanotubes , 2000 .

[5]  O. Durand,et al.  Picosecond-resolution study of nonlinear scattering in carbon black suspensions in water and ethanol. , 1998, Optics letters.

[6]  Ya‐Ping Sun,et al.  Preparation of polymer-protected semiconductor nanoparticles through the rapid expansion of supercritical fluid solution , 1998 .

[7]  A. Henglein Electronics of Colloidal Nanometer Particles , 1995 .

[8]  Ya‐Ping Sun,et al.  Preparations of Nickel, Cobalt, and Iron Nanoparticles through the Rapid Expansion of Supercritical Fluid Solutions (RESS) and Chemical Reduction , 1999 .

[9]  Kamjou Mansour,et al.  Organic Optical Limiter with a Strong Nonlinear Absorptive Response , 1996, Science.

[10]  Eklund,et al.  Solution properties of single-walled carbon nanotubes , 1998, Science.

[11]  A. Dogariu,et al.  Nonlinear response and optical limiting in inorganic metal cluster Mo 2 Ag 4 S 8 ( PPh 3 ) 4 solutions , 1998 .

[12]  Myoungsik Cha,et al.  Enhanced nonlinear absorption and optical limiting in semiconducting polymer/methanofullerene charge transfer films , 1995 .

[13]  Lee W. Tutt,et al.  Optical limiting performance of C60 and C70 solutions , 1992, Nature.

[14]  Jason E. Riggs,et al.  Optical limiting properties of suspended and solubilized carbon nanotubes , 2000 .

[15]  S. Hill,et al.  Optical limiting characteristics and mechanism of silver bromide nanosols , 1996 .

[16]  Richard C. Hollins,et al.  Materials for optical limiters , 1999 .

[17]  Alain Brun,et al.  Ultrafast induced excited state absorption in organically doped xerogels , 1999 .

[18]  Wei Ji,et al.  Synthesis and Optical Limiting Capability of Cubane-like Mixed Metal Clusters (n-Bu4N)3[MoAg3BrX3S4] (X = Cl and I) , 1994 .

[19]  A. Smirl,et al.  Picosecond reverse saturable absorption in King's complex [(C5H5)Fe(CO)]4 , 1992 .

[20]  François Hache,et al.  SINGLE-WALL CARBON NANOTUBES FOR OPTICAL LIMITING , 1999 .

[21]  Kamjou Mansour,et al.  Nonlinear optical properties of carbon-black suspensions (ink) , 1992 .

[22]  A. K. Sood,et al.  Optical limiting in single-walled carbon nanotube suspensions , 2000 .

[23]  G. Euliss,et al.  Nanosecond laser‐induced cavitation in carbon microparticle suspensions: Applications in nonlinear interface switching , 1991 .

[24]  C. Rao,et al.  FUNCTIONALISED CARBON NANOTUBES FROM SOLUTIONS , 1996 .

[25]  David J. Hagan,et al.  Investigation of an optical limiting mechanism in multiwalled carbon nanotubes , 2000 .

[26]  Jason E. Riggs,et al.  Organic and inorganic optical limiting materials. From fullerenes to nanoparticles , 1999 .

[27]  Jason E. Riggs,et al.  Optical Limiting Properties of [60]Fullerene Derivatives , 1997 .

[28]  Jason E. Riggs,et al.  Strong Luminescence of Solubilized Carbon Nanotubes , 2000 .

[29]  U. Narang,et al.  Multiphasic Nanostructured Composites for Photonics: Fullerene-Doped Monolith Glass , 1995 .

[30]  David J. Hagan,et al.  Direct measurements of nonlinear absorption and refraction in solutions of phthalocyanines , 1992 .

[31]  Wei Ji,et al.  Broadband optical limiting with multiwalled carbon nanotubes , 1998 .

[32]  Kenneth A. Smith,et al.  Reversible sidewall functionalization of buckytubes , 1999 .

[33]  Christopher E. Bunker,et al.  C70 in solvent mixtures , 1993, Nature.

[34]  M. Itkis,et al.  Dissolution of Single‐Walled Carbon Nanotubes , 1999 .

[35]  T. F. Boggess,et al.  A review of optical limiting mechanisms and devices using organics, fullerenes, semiconductors and other materials , 1993 .

[36]  P. Seta,et al.  Optical limiting behaviour of the water-soluble C60/γ-cyclodextrin complex , 2000 .

[37]  S. Mishra,et al.  Nonlinear refraction in aqueous colloidal gold , 1997 .

[38]  Ya‐Ping Sun,et al.  Photoinduced intramolecular n-pi* electron transfer in aminofullerene derivatives , 1998 .

[39]  Jacques A. Delaire,et al.  Optical Limitation induced by Gold Clusters. 1. Size Effect , 2000 .

[40]  S. Iijima Helical microtubules of graphitic carbon , 1991, Nature.

[41]  B. Tang,et al.  Preparation, Alignment, and Optical Properties of Soluble Poly(phenylacetylene)-Wrapped Carbon Nanotubes† , 1999 .

[42]  Robert H. Hauge,et al.  Solvation of Fluorinated Single-Wall Carbon Nanotubes in Alcohol Solvents , 1999 .

[43]  Wei Ji,et al.  Electronic Structure and Optical Limiting Behavior of Carbon Nanotubes , 1999 .

[44]  Jason E. Riggs,et al.  Optical Limiting Properties of [60]Fullerene and Methano[60]fullerene Derivative in Solution versus in Polymer Matrix: The Role of Bimolecular Processes and a Consistent Nonlinear Absorption Mechanism , 1999 .

[45]  Michael Hanack,et al.  Effect of Axial Substitution on the Optical Limiting Properties of Indium Phthalocyanines , 2000 .

[46]  Boris I. Yakobson,et al.  FULLERENE NANOTUBES : C1,000,000 AND BEYOND , 1997 .

[47]  Wei Ji,et al.  Nonlinear optical properties of some polymer/multi-walled carbon nanotube composites , 2000 .

[48]  G. Hartland,et al.  Picosecond Dynamics of Silver Nanoclusters. Photoejection of Electrons and Fragmentation , 1998 .

[49]  Karen M. Nashold,et al.  Investigations of optical limiting mechanisms in carbon particle suspensions and fullerene solutions , 1995 .

[50]  Jason E. Riggs,et al.  Strong Optical Limiting of Silver-Containing Nanocrystalline Particles in Stable Suspensions , 1999 .

[51]  Andrew F. Clements,et al.  Time-resolved shadowgraphic imaging of the response of dilute suspensions to laser pulses , 1998 .

[52]  T K Dougherty,et al.  Optical limiting with C(60) in polymethyl methacrylate. , 1993, Optics letters.