Characterization of raw materials and manufactured binderless particleboard from oil palm biomass

The objective of this study was to examine the extractive, holocellulose, alpha cellulose, lignin, starch, and sugar contents of oil palm biomass and to evaluate its suitability in binderless particleboard production. In this study, bark, leaves, fronds, mid-parts and core-parts of the trunks were used to produce experimental binderless particleboard panels. Binderless particleboard panels were made with a target density of 0.80 g/cm 3 at a temperature of 180 C and a pressure of 12 MPa in a computer controlled hot press. The modulus of rupture, the internal bond strength, the thickness swelling and the water absorption of the panels were evaluated. Fourier transform infrared spectroscopy and field emission scanning electron microscopy were used to characterize the properties of the raw materials and the manufactured panels. The chemical composition of the oil palm biomass consisted of high holocellulose, lignin, starch and sugar contents that have been found to aid in the production of binderless particleboard. The core-part of the trunk contained the highest amount of starch and total sugar. Samples made from the core-parts and fronds had sufficient modulus of rupture and internal bond strength to meet the Japanese Industrial Standard. The internal bond strength of the mid-part panels also met the standard. However, binderless board prepared from bark and leaves showed poor modulus of rupture and internal bond strength. Samples from the core-parts had the lowest thickness swell and water absorption but did not meet the above standard. The Fourier transform infrared spectroscopy spectra did not show any substantial difference between the raw materials and the manufactured panels. Field emission scanning electron microscopy indicated that the compressed cells varied between raw material types and showed the presence of compressed cells with some starch granules that facilitated adhesion. Based on the findings of this study, oil palm has the potential to be used to manufacture binderless panel products, and further study is required to improve its dimensional stability.

[1]  I. Norli,et al.  EXTRACTABLE FORMALDEHYDE FROM WASTE MEDIUM DENSITY FIBREBOARD , 2009 .

[2]  Takashi Watanabe,et al.  Chemical changes in steam-pressed kenaf core binderless particleboard , 2005, Journal of Wood Science.

[3]  N. Yunus,et al.  Evaluation on the suitability of some adhesives for laminated veneer lumber from oil palm trunks , 2009 .

[4]  Zarita Zainuddin,et al.  Pulp from oil palm fronds by chemical processes , 2007 .

[5]  Abdul Manan Dos Mohd.,et al.  Physico‐chemical Properties of Oil Palm Trunk Starch , 1999 .

[6]  G. Tsoumis,et al.  Science and technology of wood : structure, properties, utilization , 1991 .

[7]  F. Smith,et al.  COLORIMETRIC METHOD FOR DETER-MINATION OF SUGAR AND RELATED SUBSTANCE , 1956 .

[8]  M. Jollands,et al.  Properties of hardwood saw mill residue-based particleboards as affected by processing parameters , 2009 .

[9]  M. Ansell,et al.  The effect of chemical treatment on the properties of hemp, sisal, jute and kapok for composite reinforcement , 1999 .

[10]  D. Montané,et al.  Binderless composites from pretreated residual softwood , 1999 .

[11]  K. G. Berger,et al.  Tocopherols of oil palm leaf1 , 1983 .

[12]  W. Sandermann,et al.  Studien über mineralgebundene Holzwerkstoffe , 1960 .

[13]  A. Polle,et al.  FTIR-ATR SPECTROSCOPIC ANALYSIS OF CHANGES IN FIBER PROPERTIES DURING INSULATING FIBERBOARD MANUFACTURE OF BEECH WOOD , 2008 .

[14]  S. F. Glassman SYSTEMATIC STUDIES IN THE LEAF ANATOMY OF PALM GENUS SYAGRUS , 1972 .

[15]  J. Kelly,et al.  A method for the determination of starch in wood , 1961 .

[16]  A. J. Bolton,et al.  Physico-Chemical and Structural Characterization of Alkali Lignins from Abaca Fibre , 1998 .

[17]  Masakazu Ike,et al.  Efficient Recovery of Glucose and Fructose via Enzymatic Saccharification of Rice Straw with Soft Carbohydrates , 2009, Bioscience, biotechnology, and biochemistry.

[18]  N. Okuda,et al.  Chemical changes of kenaf core binderless boards during hot pressing (II): effects on the binderless board properties , 2006, Journal of Wood Science.

[19]  A. Khairul,et al.  Chemical Composition, Morphological Characteristics, and Cell Wall Structure of Malaysian Oil Palm Fibers , 2008 .

[20]  Sabu Thomas,et al.  Oil palm fibers: Morphology, chemical composition, surface modification, and mechanical properties , 1997 .

[21]  L. E. Wise,et al.  A CHLORITE HOLOCELLULOSE, ITS FRACTIONATION AND BEARING ON SUMMATIVE WOOD ANALYSIS AND STUDIES ON THE HEMICELLULOSES , 1946 .

[22]  近藤 隆一郎,et al.  Characterization of the Oil Palm Trunk as a Material for Bio-Ethanol Production , 2009 .