论文信息 - Bis[2-(cyclopentyliminomethyl)-4-nitrophenolato-κ2 N 2,O]cobalt(II)

Bis[2-(cyclopentyliminomethyl)-4-nitrophenolato-κ2 N 2,O]cobalt(II)

In the title compound, [Co(C12H13N2O3)2], the CoII ion is situated on a twofold rotation axis and is coordinated by two N and two O atoms from two symmetry-related Schiff base 2-(cyclopentyliminomethyl)-4-nitrophenolate ligands (L) in a distorted tetrahedral geometry. The cyclopentyl ring in L is disordered over two conformations in a 0.640 (19):0.360 (19) ratio.

[1] G. Sheldrick. A short history of SHELX. , 2008, Acta crystallographica. Section A, Foundations of crystallography.

[2] H. Bahron,et al. Structures of bis(N-n-butylsalicylideneiminato)cobalt(II) and bis(N-tert-butylsalicylideneiminato)cobalt(II) complexes and reactivity towards oxygen and nitric oxide , 1994 .

[3] G. A. Kolawole,et al. Synthesis, characterization, antibacterial, and thermal studies of unsymmetrical Schiff-base complexes of cobalt(II) , 2010 .

[4] S. Kashanian,et al. DNA binding and DNA cleavage studies of a water soluble cobalt(II) complex containing dinitrogen Schiff base ligand: the effect of metal on the mode of binding. , 2010, European journal of medicinal chemistry.

[5] S. Salehzadeh,et al. Synthesis, characterization, and X-ray crystal structure analysis of Cd(ΙΙ) and Cu(II) complexes of an acyclic pentadentate Schiff base , 2010 .