Evidence for Water Ice Near Mercury’s North Pole from MESSENGER Neutron Spectrometer Measurements

Wet Mercury Radar observations of Mercury's poles in the 1990s revealed regions of high backscatter that were interpreted as indicative of thick deposits of water ice; however, other explanations have also been proposed (see the Perspective by Lucey). MESSENGER neutron data reported by Lawrence et al. (p. 292, published online 29 November) in conjunction with thermal modeling by Paige et al. (p. 300, published online 29 November) now confirm that the primary component of radar-reflective material at Mercury's north pole is water ice. Neumann et al. (p. 296, published online 29 November) analyzed surface reflectance measurements from the Mercury Laser Altimeter onboard MESSENGER and found that while some areas of high radar backscatter coincide with optically bright regions, consistent with water ice exposed at the surface, some radar-reflective areas correlate with optically dark regions, indicative of organic sublimation lag deposits overlying the ice. Dark areas that fall outside regions of high radio backscatter suggest that water ice was once more widespread. Spacecraft data and a thermal model show that water ice and organic volatiles are present at Mercury’s north pole. [Also see Perspective by Lucey] Measurements by the Neutron Spectrometer on the MErcury Surface, Space ENvironment, GEochemistry, and Ranging (MESSENGER) spacecraft show decreases in the flux of epithermal and fast neutrons from Mercury’s north polar region that are consistent with the presence of water ice in permanently shadowed regions. The neutron data indicate that Mercury’s radar-bright polar deposits contain, on average, a hydrogen-rich layer more than tens of centimeters thick beneath a surficial layer 10 to 30 cm thick that is less rich in hydrogen. Combined neutron and radar data are best matched if the buried layer consists of nearly pure water ice. The upper layer contains less than 25 weight % water-equivalent hydrogen. The total mass of water at Mercury’s poles is inferred to be 2 × 1016 to 1018 grams and is consistent with delivery by comets or volatile-rich asteroids.

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