Effects of long-term aging on the properties of asphalt binder containing diatoms

Abstract Diatomite modified asphalts were prepared by melt blending with different contents of diatomite and hydrophobic diatomite. The effects of long-term aging on physical properties and chemical structure of the diatomite modified asphalts were investigated. The results show that the viscosity aging index and the increment in the softening point of the modified asphalts decrease significantly with increasing diatomite contents. The retained penetration increases after the introduction of diatomite. The chemical structures of the aged asphalts were evaluated using FTIR. The increased extent of the C O and S O bands areas of the modified asphalt is smaller than that of pure asphalt. The aging resistances of the modified asphalts are much better than that of pure asphalt, because they can efficiently prevent the oxygen, which attribute to the honeycomb silica structure in the modified asphalts. Compared with diatomite modified asphalt, the oxygen dispersion in hydrophobic diatomite modified asphalt was harder, which means the oxidative aging resistance of hydrophobic diatomite modified asphalt was better.

[1]  Yong Zhang,et al.  Improving the aging resistance of asphalt by addition of Zinc dialkyldithiophosphate , 2006 .

[2]  P. Marchal,et al.  Asphalt rheology evolution through thermo-oxidation (aging) in a rheo-reactor , 2008 .

[3]  Ulf Isacsson,et al.  Chemical and rheological evaluation of ageing properties of SBS polymer modified bitumens , 1998 .

[4]  M. Scarsella,et al.  Improving the ageing resistance of straight-run bitumens by addition of phosphorus compounds , 1995 .

[5]  P. Cong,et al.  Physical and rheological properties of asphalt binders containing various antiaging agents , 2012 .

[6]  Huaxin Chen,et al.  Effects of diatomite on the properties of asphalt binder , 2012 .

[7]  J. Lamontagne,et al.  Direct and continuous methodological approach to study the ageing of fossil organic material by infrared microspectrometry imaging: application to polymer modified bitumen , 2001 .

[8]  Virginie Mouillet,et al.  The influence of UV aging of a Styrene/Butadiene/Styrene modified bitumen: Comparison between laboratory and on site aging , 2007 .

[9]  Virginie Mouillet,et al.  Comparison by Fourier transform infrared (FTIR) spectroscopy of different ageing techniques: application to road bitumens , 2001 .

[10]  A. Yilmaz,et al.  Use of diatomite as partial replacement for Portland cement in cement mortars , 2009 .

[11]  M. Siddiqui,et al.  Studies on the aging behavior of the Arabian asphalts , 1999 .

[12]  R N Traxler,et al.  RELATION BETWEEN ASPHALT COMPOSITION AND HARDENING BY VOLATILIZATION AND OXIDATION , 1961 .

[13]  Yong Zhang,et al.  Improving the aging resistance of styrene-butadiene-styrene tri-block copolymer modified asphalt by addition of antioxidants , 2006 .

[14]  H. Bianchetto,et al.  Effect of the thermal degradation of SBS copolymers during the ageing of modified asphalts , 2004 .

[15]  Richard R. Davison,et al.  The effect of long-term oxidation on the rheological properties of polymer modified asphalts☆ , 2003 .

[16]  D. Anderson,et al.  Glass transition behaviour and physical hardening of asphalt binders , 1993 .

[17]  Huaxin Chen,et al.  Preparation and properties of bitumen modified with the maleic anhydride grafted styrene-butadiene-styrene triblock copolymer , 2011 .