Thermal Stability of SiO 2 Doped Ge 2 Sb 2 Te 5 for Application in Phase Change Random Access Memory

Thermal stability of Ge 2 Sb 2 Te 5 (GST) and SiO 2 doped GST (SGST) films for phase change random access memory applications was investigated by observing the change of surface roughness, layer density and composition of both films after isothermal annealing. After both GST and SGST films were annealed at 325°C for 20 min, root mean square (RMS) surface roughness of GST was increased from 1.9 to 35.9 nm but that of SGST was almost unchanged. Layer density of GST also steeply decreased from 72.48 to 68.98 g/cm 2 and composition was largely varied from Ge : Sb : Te = 22.3 : 22.1 : 55.6 to 24.2 : 22.7 : 53.1, while those of SGST were almost unchanged. It was confirmed that the addition of a small amount of SiO 2 into GST film restricted the deterioration of physical and chemical properties of GST film, resulting in the better thermal stability after isothermal annealing.

[1]  Aaas News,et al.  Book Reviews , 1893, Buffalo Medical and Surgical Journal.

[2]  S.O. Park,et al.  Highly scalable on-axis confined cell structure for high density PRAM beyond 256Mb , 2005, Digest of Technical Papers. 2005 Symposium on VLSI Technology, 2005..

[3]  Byung Joon Choi,et al.  SiO2 Incorporation Effects in Ge2Sb2Te5 Films Prepared by Magnetron Sputtering for Phase Change Random Access Memory Devices , 2006 .

[4]  Matthias Wuttig,et al.  Density changes upon crystallization of Ge2Sb2.04Te4.74 films , 2002 .

[5]  Y. K. Kim,et al.  Changes in the electronic structures and optical band gap of Ge2Sb2Te5 and N-doped Ge2Sb2Te5 during phase transition , 2007 .

[6]  C. Cabral,et al.  Evidence for segregation of Te in Ge2Sb2Te5 films: Effect on the “phase-change” stress , 2007 .

[7]  M. Breitwisch,et al.  Ultra-Thin Phase-Change Bridge Memory Device Using GeSb , 2006, 2006 International Electron Devices Meeting.

[8]  Jie Feng,et al.  Effects of Si Doping on Phase Transition of Ge2Sb2Te5 Films by in situ Resistance Measurements , 2006 .

[9]  Andrew G. Glen,et al.  APPL , 2001 .

[10]  Jung-Sub Wi,et al.  Phase separation behavior of Ge2Sb2Te5 line structure during electrical stress biasing , 2008 .

[11]  Kinam Kim,et al.  Phase-Change Behavior of Stoichiometric Ge2Sb2Te5 in Phase-Change Random Access Memory , 2007 .

[12]  S. Lai,et al.  Current status of the phase change memory and its future , 2003, IEEE International Electron Devices Meeting 2003.

[13]  Se-Ho Lee,et al.  SiO2 doped Ge2Sb2Te5 thin films with high thermal efficiency for applications in phase change random access memory , 2011, Nanotechnology.

[14]  Woo-Young Choi,et al.  Design of 250-Mb/s Low-Power Fiber Optic Transmitter and Receiver ICs for POF Applications , 2011 .

[15]  S.Y. Lee,et al.  Writing current reduction for high-density phase-change RAM , 2003, IEEE International Electron Devices Meeting 2003.

[17]  Ravi M. Todi,et al.  Comparison of the agglomeration behavior of thin metallic films on SiO2 , 2005 .

[18]  Tae-Yon Lee,et al.  Separate domain formation in Ge2Sb2Te5–SiOx mixed layer , 2006 .

[19]  D. Ielmini,et al.  Reliability study of phase-change nonvolatile memories , 2004, IEEE Transactions on Device and Materials Reliability.

[20]  M. Wuttig,et al.  Sb-Se-based phase-change memory device with lower power and higher speed operations , 2006, IEEE Electron Device Letters.

[21]  Yoonjin Kim Reconfigurable Multi-Array Architecture for Low- Power and High-Speed Embedded Systems , 2011 .

[22]  B. Johnson,et al.  Overview of Phase-Change Chalcogenide Nonvolatile Memory Technology , 2004 .

[23]  Byung Joon Choi,et al.  Phase transformation behaviors of SiO2 doped Ge2Sb2Te5 films for application in phase change random access memory , 2008 .