Stimuli-Responsive Smart Polymeric Coatings: An Overview

Coatings are an important topic within the scientific community, spanning from the ancient to the modern world. Coatings are not only used for decorative purposes but also for functionality, for example, coatings that are resistant to the effects of weathering (i.e., rain, UV light, etc.). Up until present, several coating materials were developed using various types of natural and synthetic materials. The scientific improvements of the modern era have made it easy to create novel coating formulations by mimicking ancient pathways. Recently nonstick, self-cleaning, self-healing, and stimuli-responsive surfaces have attracted special interest in the formulation of smart coating materials. Several attempts were made to synthesize and develop highly efficient smart polymeric coatings from the practical point of view due to the increasing need for smart coatings in modern technologies and industrial applications. Stimuli-responsive smart coatings are also very useful in extending the life of final products, which is also a reason to develop a variety of new coating formulations for industrial purpose. On the other hand, the synthesis of stimuli-responsive smart coatings and maintaining the stability of the coated surfaces under major environmental changes were quite difficult, which necessitated careful selection and synthesis of the coating materials. The applicability of stable stimuli-responsive smart polymeric coating can be extended into various industrial and commercial applications. This chapter covers the stimuli responsiveness of smart polymeric coatings in various applications and their future outlooks within the coating industry as well as present practical applications and necessities of the stimuli-responsive smart polymeric coatings for other industrial applications.

[1]  M. Vallet‐Regí,et al.  Revisiting silica based ordered mesoporous materials: medical applications , 2006 .

[2]  Helmuth Möhwald,et al.  Monodisperse Polymeric Core–Shell Nanocontainers for Organic Self‐Healing Anticorrosion Coatings , 2014 .

[3]  Andrew G. Gillies,et al.  Optically-and Thermally-responsive Programmable Materials Based on Carbon Nanotube-hydrogel Polymer Composites , 2022 .

[4]  Chengzhong Yu,et al.  Functionalized large pore mesoporous silica nanoparticles for gene delivery featuring controlled release and co-delivery. , 2014, Journal of materials chemistry. B.

[5]  E. K. Hussmann Sol-Gel Coatings on Large Glass Substrates for Multilayer Interference Systems , 1998 .

[6]  Zhijun Hu,et al.  Fabrication of highly ordered/switchable polymer nanogratings for nano-actuators using nanoimprint lithography , 2014, Nanotechnology.

[7]  W. Freeman,et al.  Porous silicon in drug delivery devices and materials. , 2008, Advanced drug delivery reviews.

[8]  Li Yuan,et al.  Preparation of pH-Responsive Mesoporous Silica Nanoparticles and Their Application in Controlled Drug Delivery , 2011 .

[9]  M. Groenewolt Highly scratch resistant coatings for automotive applications , 2008 .

[10]  Younan Xia,et al.  Photonic Papers and Inks: Color Writing with Colorless Materials , 2003 .

[11]  Tao Chen,et al.  An intelligent anticorrosion coating based on pH-responsive supramolecular nanocontainers , 2012, Nanotechnology.

[12]  S. Park,et al.  Bio-inspired, multi-purpose and instant superhydrophobic–superoleophilic lotus leaf powder hybrid micro–nanocomposites for selective oil spill capture , 2013 .

[13]  Lifeng Chi,et al.  Transparent superhydrophobic/superhydrophilic TiO2-based coatings for self-cleaning and anti-fogging , 2012 .

[14]  M. Rosseinsky,et al.  Multi-responsive polymer-stabilized magnetic engineered emulsions as liquid-based switchable magneto-responsive actuators , 2011 .

[15]  T. Bein,et al.  Biotin-avidin as a protease-responsive cap system for controlled guest release from colloidal mesoporous silica. , 2009, Angewandte Chemie.

[16]  J. Mano Stimuli‐Responsive Polymeric Systems for Biomedical Applications , 2008 .

[17]  Xufeng Zhou,et al.  Highly ordered mesoporous bioactive glasses with superior in vitro bone-forming bioactivities. , 2004, Angewandte Chemie.

[18]  Dirk J. Broer,et al.  Stimuli-responsive photonic polymer coatings. , 2014, Chemical communications.

[19]  T. Kokubo,et al.  Apatite formation on PDMS-modified CaO-SiO2-TiO2 hybrids prepared by sol-gel process. , 1999, Biomaterials.

[20]  Din-Guo Chen,et al.  Anti-reflection (AR) coatings made by sol–gel processes: A review , 2001 .

[21]  C. Ha,et al.  Emerging trends in superhydrophobic surface based magnetic materials: fabrications and their potential applications , 2015 .

[22]  S. Park,et al.  Recent advances in superhydrophobic nanomaterials and nanoscale systems. , 2014, Journal of nanoscience and nanotechnology.

[23]  Myung-Haing Cho,et al.  Mannosylated polyethylenimine coupled mesoporous silica nanoparticles for receptor-mediated gene delivery. , 2008, International journal of pharmaceutics.

[24]  M. Javed,et al.  One-pot synthesis of redox-responsive polymers-coated mesoporous silica nanoparticles and their controlled drug release. , 2013, Macromolecular rapid communications.

[25]  Wen‐Chang Chen,et al.  Synthesis, properties, and anti-reflective applications of new colorless polyimide-inorganic hybrid optical materials , 2010 .

[26]  Juan L. Vivero-Escoto,et al.  Mesoporous silica nanoparticles as controlled release drug delivery and gene transfection carriers. , 2008, Advanced drug delivery reviews.

[27]  A. Schenning,et al.  Humidity-responsive liquid crystalline polymer actuators with an asymmetry in the molecular trigger that bend, fold, and curl. , 2014, Journal of the American Chemical Society.

[28]  J. Kim,et al.  Broadband antireflection coating covering from visible to near infrared wavelengths by using multilayered nanoporous block copolymer films. , 2010, Langmuir : the ACS journal of surfaces and colloids.

[29]  Ton Peijs,et al.  Humidity-responsive bilayer actuators based on a liquid-crystalline polymer network. , 2013, ACS applied materials & interfaces.

[30]  B. Catargi,et al.  Glucose-responsive microgels with a core-shell structure. , 2008, Journal of Colloid and Interface Science.

[31]  Juan L. Vivero-Escoto,et al.  Mesoporous silica nanoparticles for intracellular controlled drug delivery. , 2010, Small.

[32]  M. C. Stuart,et al.  Emerging applications of stimuli-responsive polymer materials. , 2010, Nature materials.

[33]  Sergiy Minko,et al.  Stimuli-responsive nanoparticles, nanogels and capsules for integrated multifunctional intelligent systems , 2010 .

[34]  Ying Yang,et al.  Self-repairable polyurethane networks by atmospheric carbon dioxide and water. , 2014, Angewandte Chemie.

[35]  Bo-Tau Liu,et al.  Antireflective surface fabricated from colloidal silica nanoparticles , 2010 .

[36]  L. Andrzejewski,et al.  Relation between the size of fog droplets and their contact angles with CR39 surfaces , 2004 .

[37]  Sunghoon Kwon,et al.  Water-Responsive Polymer Composites on the Move , 2013, Science.

[38]  K. Sapag,et al.  Nature and Location of Copper Nanospecies in Mesoporous Molecular Sieves , 2010 .

[39]  Xin Li,et al.  Fabrication of smart nanocontainers with a mesoporous core and a pH-responsive shell for controlled uptake and release , 2009 .

[40]  Pingyun Feng,et al.  Responsive polymer-coated mesoporous silica as a pH-sensitive nanocarrier for controlled release. , 2011, Langmuir : the ACS journal of surfaces and colloids.

[41]  Saji George,et al.  Polyethyleneimine coating enhances the cellular uptake of mesoporous silica nanoparticles and allows safe delivery of siRNA and DNA constructs. , 2009, ACS nano.

[42]  Yang-Yen Yu,et al.  High transparent polyimide/titania multi-layer anti-reflective hybrid films , 2011 .

[43]  Chi-Jung Chang,et al.  Fabrications and Applications of Stimulus-Responsive Polymer Films and Patterns on Surfaces: A Review , 2014, Materials.

[44]  Larry A. Sklar,et al.  Control of Molecular Transport Through Stimuli‐Responsive Ordered Mesoporous Materials , 2003 .

[45]  Jeffrey S. Meth,et al.  Tailoring and probing particle–polymer interactions in PMMA/silica nanocomposites , 2011 .

[46]  L. Ionov,et al.  Surface functionalization by smart coatings: Stimuli-responsive binary polymer brushes , 2006 .

[47]  W. Huck Responsive polymers for nanoscale actuation , 2008 .

[48]  Marc Behl,et al.  Temperature-memory polymer actuators , 2013, Proceedings of the National Academy of Sciences.

[49]  Robert Pelton,et al.  Charge-switching, amphoteric glucose-responsive microgels with physiological swelling activity. , 2008, Biomacromolecules.

[50]  Wen‐Chang Chen,et al.  New photosensitive colorless polyimide-silica hybrid optical materials: Synthesis, properties and patterning , 2011 .

[51]  J. Youngblood,et al.  Self‐Cleaning and Anti‐Fog Surfaces via Stimuli‐Responsive Polymer Brushes , 2007 .

[52]  J. Benoit,et al.  Progress in developing cationic vectors for non-viral systemic gene therapy against cancer. , 2008, Biomaterials.

[53]  Victor S-Y Lin,et al.  A polyamidoamine dendrimer-capped mesoporous silica nanosphere-based gene transfection reagent. , 2004, Journal of the American Chemical Society.

[54]  Yang Wang,et al.  Bioresponsive Controlled Drug Release Based on Mesoporous Silica Nanoparticles Coated with Reductively Sheddable Polymer Shell , 2013 .

[55]  Feng Shi,et al.  pH-responsive on-off motion of a superhydrophobic boat: towards the design of a minirobot. , 2014, Small.

[56]  Ying Wang,et al.  Acid and alkaline dual stimuli-responsive mechanized hollow mesoporous silica nanoparticles as smart nanocontainers for intelligent anticorrosion coatings. , 2013, ACS nano.

[57]  M. Vallet‐Regí,et al.  Phosphorous-doped MCM-41 as bioactive material , 2005 .

[58]  Akira Harada,et al.  Redox-generated mechanical motion of a supramolecular polymeric actuator based on host-guest interactions. , 2013, Angewandte Chemie.

[59]  S. Minko Responsive Polymer Brushes , 2006 .

[60]  Hsian-Rong Tseng,et al.  An operational supramolecular nanovalve. , 2004, Journal of the American Chemical Society.

[61]  Shun Yang,et al.  Visible-light degradable polymer coated hollow mesoporous silica nanoparticles for controlled drug release and cell imaging. , 2013, Journal of materials chemistry. B.

[62]  Samuel Ibekwe,et al.  A review of stimuli-responsive polymers for smart textile applications , 2012 .

[63]  Yanchun Han,et al.  Intelligent reversible nanoporous antireflection film by solvent-stimuli-responsive phase transformation of amphiphilic block copolymer. , 2012, Langmuir : the ACS journal of surfaces and colloids.

[64]  Qiang Zhao,et al.  An instant multi-responsive porous polymer actuator driven by solvent molecule sorption , 2014, Nature Communications.

[65]  Garikoitz Beobide,et al.  Using scanning probe microscopy to study the effect of molecular weight of poly(3-hexylthiophene) on the performance of poly(3-hexylthiophene):TiO2 nanorod photovoltaic devices , 2009 .

[66]  María Vallet-Regí,et al.  Ordered Mesoporous Bioactive Glasses for Bone Tissue Regeneration , 2006 .

[67]  Monty Liong,et al.  Multifunctional inorganic nanoparticles for imaging, targeting, and drug delivery. , 2008, ACS nano.