A demonstration of the mechanical sensing capability of individually contacted vertical piezoelectric nanowires arranged in matrices

Abstract This paper reports the fabrication of arrays of vertical piezoelectric nanowires which are individually contacted at their base, and demonstrates that an electrical response to strain can be obtained from individual nanowires from the array, without external biasing exploiting the piezotronic effect. Such a technology could thus be used for the fabrication of self-powered sensors for mechanical strain mapping, where each individually contacted nanowire would act as the strain sensing equivalent of a pixel. Lateral mapping resolutions in the micrometer range can be obtained. Here, the hydrothermal method was used to grow vertical ZnO nanowires selectively between two electrodes that had been patterned beforehand. For the sake of demonstration, nanowires deflection was produced by subjecting the array of nanowires to an incident lateral gas flow of controlled rate, which was switched on and off repeatedly across the sample while electrical response was measured. Different experimental configurations were tested in terms of flow rate, flow orientation, or nanowire position with respect to tube outlet. Experiments were carried out with compressed nitrogen and air. The experimental results are fully consistent with the piezoelectric and piezotronic response which can be expected with this geometry. Moreover, it is shown that the electrical response under nitrogen flow is a linear function of flow rate and that its sign provides information about flow direction. These results demonstrate the very promising prospects of this new technology for high-resolution mapping, with potential applications in gas or liquid flow sensing, fingerprints detection or human-machine interfaces.

[1]  Zhong Lin Wang Piezopotential gated nanowire devices: Piezotronics and piezo-phototronics , 2010 .

[2]  Zhong Lin Wang,et al.  Power generation with laterally packaged piezoelectric fine wires. , 2009, Nature nanotechnology.

[3]  Horacio D Espinosa,et al.  Experimental-computational investigation of ZnO nanowires strength and fracture. , 2009, Nano letters.

[4]  Zhong Lin Wang,et al.  Self-powered nanowire devices. , 2010, Nature nanotechnology.

[5]  Yan Zhang,et al.  Surface free-carrier screening effect on the output of a ZnO nanowire nanogenerator and its potential as a self-powered active gas sensor , 2013, Nanotechnology.

[6]  Caofeng Pan,et al.  Flexible and Controllable Piezo‐Phototronic Pressure Mapping Sensor Matrix by ZnO NW/p‐Polymer LED Array , 2015 .

[7]  Zhong Lin Wang,et al.  Piezoelectric field effect transistor and nanoforce sensor based on a single ZnO nanowire. , 2006, Nano letters.

[8]  Zhong Lin Wang,et al.  Direct-Current Nanogenerator Driven by Ultrasonic Waves , 2007, Science.

[9]  M. Mouis,et al.  Modeling of semiconducting piezoelectric nanowires for mechanical energy harvesting and mechanical sensing , 2015 .

[10]  P. Servati,et al.  Dielectrophoresis-Assembled ZnO Nanowire Oxygen Sensors , 2011, IEEE Electron Device Letters.

[11]  Zhong Lin Wang,et al.  Piezoelectric Nanogenerators Based on Zinc Oxide Nanowire Arrays , 2006, Science.

[12]  Zhong Lin Wang,et al.  Functional electrical stimulation by nanogenerator with 58 V output voltage. , 2012, Nano letters.

[13]  Fang Zhang,et al.  Nano‐Newton Transverse Force Sensor Using a Vertical GaN Nanowire based on the Piezotronic Effect , 2013, Advanced materials.

[14]  M. Mouis,et al.  Performance of ZnO based piezo-generators under controlled compression , 2017 .

[15]  Zhong Lin Wang Piezotronic and Piezophototronic Effects , 2010 .

[16]  Zhong Lin Wang,et al.  Cellular level biocompatibility and biosafety of ZnO nanowires , 2008 .

[17]  Lianmao Peng,et al.  Quantitative Analysis of Current–Voltage Characteristics of Semiconducting Nanowires: Decoupling of Contact Effects , 2007 .

[18]  V. Consonni,et al.  Selective area growth of well-ordered ZnO nanowire arrays with controllable polarity. , 2014, ACS nano.

[19]  Weiguo Hu,et al.  Piezotronic Effect in Polarity-Controlled GaN Nanowires. , 2015, ACS nano.

[20]  M. Takata,et al.  Dependence of Electrical Conductivity of ZnO on Degree of Sintering , 1976 .

[21]  M. Nayak,et al.  Synthesis of ZnO nanorods on a flexible Phynox alloy substrate: influence of growth temperature on their properties , 2015 .

[22]  R. Hinchet,et al.  Scaling rules of piezoelectric nanowires in view of sensor and energy harvester integration , 2012, 2012 International Electron Devices Meeting.

[23]  Static Finite Element Modeling for Sensor Design and Processing of an Individually Contacted Laterally Bent Piezoelectric Nanowire , 2016, IEEE Transactions on Nanotechnology.

[24]  Vu Nguyen,et al.  Piezotronic Effect: An Emerging Mechanism for Sensing Applications , 2015, Sensors.

[25]  Wenjie Mai,et al.  Patterned growth of vertically aligned ZnO nanowire arrays on inorganic substrates at low temperature without catalyst. , 2008, Journal of the American Chemical Society.

[26]  F. Fan,et al.  Flexible Nanogenerators for Energy Harvesting and Self‐Powered Electronics , 2016, Advanced materials.

[27]  Young-Jun Park,et al.  Sound‐Driven Piezoelectric Nanowire‐Based Nanogenerators , 2010, Advanced materials.

[28]  Yucheng Ding,et al.  Self-powered flexible pressure sensors with vertically well-aligned piezoelectric nanowire arrays for monitoring vital signs , 2015 .

[29]  Integration of Piezoelectric Nanowires Matrix onto a Microelectronics Chip , 2016 .

[30]  Long Lin,et al.  Strain-gated piezotronic transistors based on vertical zinc oxide nanowires. , 2012, ACS nano.

[31]  Optimization of dielectric matrix for ZnO nanowire based nanogenerators , 2016 .

[32]  Mireille Mouis,et al.  Ultrathin Nanogenerators as Self‐Powered/Active Skin Sensors for Tracking Eye Ball Motion , 2014 .

[33]  Ningsheng Xu,et al.  Dissolving Behavior and Stability of ZnO Wires in Biofluids: A Study on Biodegradability and Biocompatibility of ZnO Nanostructures , 2006 .

[34]  M. Mouis,et al.  Unveiling the Influence of Surface Fermi Level Pinning on the Piezoelectric Response of Semiconducting Nanowires , 2018 .

[35]  Yue Zhang,et al.  Size effect in a cantilevered ZnO micro/nanowire and its potential as a performance tunable force sensor , 2013 .

[36]  Caofeng Pan,et al.  Piezotronic Effect on the Transport Properties of GaN Nanobelts for Active Flexible Electronics , 2012, Advanced materials.

[37]  Design of UV-crosslinked polymeric thin layers for encapsulation of piezoelectric ZnO nanowires for pressure-based fingerprint sensors , 2018 .

[38]  Zhong Lin Wang,et al.  Taxel-Addressable Matrix of Vertical-Nanowire Piezotronic Transistors for Active and Adaptive Tactile Imaging , 2013, Science.

[39]  Chia-Yen Lee,et al.  MEMS-based gas flow sensors , 2009 .

[40]  Wenbin Song,et al.  Patterned growth of ZnO nanowires on flexible substrates for enhanced performance of flexible piezoelectric nanogenerators , 2017 .