Crystal growth, piezoelectric, non-linear optical and mechanical properties of lithium hydrogen oxalate monohydrate single crystal

Semi-organic lithium hydrogen oxalate monohydrate non-linear optical single crystals have been grown by slow evaporation solution growth technique at 35 °C. Single crystal X-ray diffraction study showed that the grown crystal belongs to the triclinic system with space group P1. The mechanical strength decreases with increasing load. The piezoelectric coefficient is found to be 1.41 pC/N. The nonlinear optical property was measured using Kurtz Perry powder technique and SHG efficiency was almost equal to that of KDP.

[1]  B. Kumar,et al.  Bulk crystal growth, optical, mechanical and ferroelectric properties of new semiorganic nonlinear optical and piezoelectric Lithium nitrate monohydrate oxalate single crystal , 2016 .

[2]  P. Ramasamy,et al.  Spectral, mechanical, thermal, optical and solid state parameters, of metal-organic bis(hydrogenmaleate)-CO(II) tetrahydrate crystal , 2015 .

[3]  N. Ahmad,et al.  Single crystal growth by gel technique and characterization of lithium hydrogen tartrate , 2015 .

[4]  B. Kumar,et al.  Structural, optical and dielectric studies of novel non-linear Bisglycine Lithium Nitrate piezoelectric single crystal , 2014 .

[5]  G. Hutchison,et al.  Piezoelectric hydrogen bonding: computational screening for a design rationale. , 2014, The journal of physical chemistry. A.

[6]  M. Binitha,et al.  Thermal degradation, dielectric and magnetic studies on copper tartrate trihydrate crystals , 2013, Journal of Thermal Analysis and Calorimetry.

[7]  P. Ramasamy,et al.  Unidirectional growth, improved structural perfection and physical properties of a semi-organic nonlinear optical dichlorobis(L-proline)zinc(II) single crystal , 2013 .

[8]  B. Kumar,et al.  Effect of rare earth ions on the properties of glycine phosphite single crystals , 2013 .

[9]  P. Ramasamy,et al.  Synthesis, growth and characterization of a novel semiorganic NLO crystal: Triglycine calcium dibromide , 2010 .

[10]  P. Ramasamy,et al.  Growth, thermal, dielectric and mechanical studies of triglycine zinc chloride, a semiorganic nonlinear optical material , 2010 .

[11]  S. Dhas,et al.  Growth and characterization of Lithium hydrogen oxalate monohydrate, a new semiorganic NLO material , 2008 .

[12]  S. Dhas,et al.  Growth and characterization of a new organic NLO material: Glycine nitrate , 2007 .

[13]  J. O. Thomas Hydrogen bond studies. LXI. An X-ray diffraction study of the isotope effect in lithium hydrogen oxalate monohydrate, LiHC2O4.H2O , 1972 .