Ozone detection in air using SmFeO3 gas sensor

Abstract The conductance changes of SmFeO 3 based p-type gas sensor with ozone in air with and without VOCs were examined. The conductance for this sensor was responsible in sub-ppm levels ozone at the temperatures above 240 °C and the sensitivity decreased with an increase in the working temperature. It is expected that the sensitivity in 0.01 ppm ozone estimated to be ca. 10 at 290 °C. The sensing characteristic is promising to monitor the environmental air quality regarding with ozone. The conductance for ozone was decreased by the contamination of same levels VOCs. This is mainly due to the decrease in actual concentration of ozone by the reaction with contaminated VOCs. The developed sensor is a very promising candidate for the detection of ozone in sub-ppm levels and for the contaminated levels with several VOCs in monitoring environment.

[1]  Giuliano Martinelli,et al.  Gas-sensitive electrical properties of perovskite-type SmFeO3 thick films , 1998 .

[2]  Gualtiero Gusmano,et al.  Design of Ceramic Materials for Chemical Sensors: SmFeO3 Thick Films Sensitive to NO2 , 1999 .

[3]  Jun Akikusa,et al.  Characterization of solid oxide fuel cell using doped lanthanum gallate , 2000 .

[4]  Matteo Ferroni,et al.  Screen-printed perovskite-type thick films as gas sensors for environmental monitoring , 1999 .

[5]  Enrico Traversa,et al.  Crystallographic characterization and NO2 gas sensing property of LnFeO3 prepared by thermal decomposition of LnFe hexacyanocomplexes, Ln[Fe(CN)6]·nH2O, Ln = La, Nd, Sm, Gd, and Dy , 2003 .

[6]  M. Sakamoto,et al.  NO2-sensitive LaFeO3film prepared by thermal decomposition of the heteronuclear complex, {La[Fe(CN)6]·5H2O}x , 1993 .

[7]  E. Traversa,et al.  NO2 sensitive LaFeO3 thin films prepared by r.f. sputtering , 1995 .

[8]  Giuliano Martinelli,et al.  Thick-Film Gas Sensors Based on Nano-Sized Semiconducting Oxide Powders , 1999 .

[9]  J. Shiokawa,et al.  CO gas sensitivities of reduced perovskite oxide LaCoO3 − x☆ , 1988 .

[10]  E. Traversa,et al.  Design of ceramic materials for chemical sensors : Effect of SmFeO3 processing on surface and electrical properties , 2004 .

[11]  Yoshinobu Matsuura,et al.  Metal oxide semiconductor NO2 sensor , 1995 .

[12]  N. Minh Ceramic Fuel Cells , 1993 .

[13]  H. Wise,et al.  Perovskite catalysts for methane combustion , 1990 .

[14]  Satoshi Okano,et al.  Air quality prediction by using semiconducting gas sensor with newly fabricated SmFeO3 film , 2004 .

[15]  Yasuhiro Shimizu,et al.  Enhancement of humidity sensitivity for Perovskite-type oxides having semiconductivity. , 1985 .

[16]  M. Carotta,et al.  Microstructural evolution of nanosized LaFeO3 powders from the thermal decomposition of a cyano-complex for thick film gas sensors , 1997 .

[17]  Roy M. Harrison,et al.  Understanding our environment : an introduction to environmental chemistry and pollution , 1992 .