The Effect of Stoichiometry on Mechanical Properties of Boron Carbide

The present investigation of the mechanical properties of chemically vapor-deposited boron carbides with varying B/C ratios has given attention to maximum hardness and fracture toughness values at near-stoichiometric composition. In the cases of nonstoichiometric boron carbides with B/C ratios greater than 4, these two values decreased with increasing B content, suggesting that excess B decreases the B4C structure's bond strength. Hardness and fracture toughness values at B/C ratios lower than 4 decrease, perhaps due to free carbon in the microstructure. 18 references.