Contribution of bottom-emitted radicals to the deposition of a film on the SiO2 sidewall during CHF3 plasma etching

The contribution of radicals emitted from the bottom of an etched pattern to the deposition of a film on the sidewall in a CHF3 plasma was investigated using a specially designed experimental system. In the experimental system, a target (1), simulating the bottom of an etched pattern, emits various types of radicals after collision with incident ions. Among the radicals and ions that are incident on a target (2), which is located in close proximity to the target (1), to simulate the sidewall of an etched pattern, ions were prevented from arriving at the surface by placing a double grid structure in front of the target (2). The deposition rate and the composition of the film formed on the target (2) were measured for the cases where the target (1) was made of different materials and subject to impingement by ions at different bias voltages. In another set of experiments, a rectangular tube of a predetermined length was located in front of the target (2) for the purpose of estimating the probability of radi...

[1]  E. Aydil,et al.  Measurement of absolute radical densities in a plasma using modulated-beam line-of-sight threshold ionization mass spectrometry , 2004 .

[2]  Sung-ki Park,et al.  Effects of CH 2 F 2 Addition on a High Aspect Ratio Contact Hole Etching in a C 4 F 6 / O 2 / Ar Plasma , 2003 .

[3]  K. Sasaki,et al.  Laser desorption time-of-flight mass spectrometry of fluorocarbon films synthesized by C4F8/H2 plasmas , 2003 .

[4]  S. Moon,et al.  Trajectories of ions inside a Faraday cage located in a high density plasma etcher , 2003 .

[5]  William B. Knowlton,et al.  Polymer Thickness Effects on Bosch Etch Profiles , 2002 .

[6]  Gilles Cartry,et al.  Selective and deep plasma etching of SiO2: Comparison between different fluorocarbon gases (CF4, C2F6, CHF3) mixed with CH4 or H2 and influence of the residence time , 2002 .

[7]  Y. Horiike,et al.  Behavior of fluorocarbon species near temperature controlled and radio frequency biased metal plate in C4F8 plasma , 2002 .

[8]  M. Sekine,et al.  Planar Laser-Induced Fluorescence of Fluorocarbon Radicals in Oxide Etch Process Plasma , 2002 .

[9]  Sang Heup Moon,et al.  Angular dependence of SiO2 etching in a fluorocarbon plasma , 2000 .

[10]  Kunihide Tachibana,et al.  Radical kinetics for polymer film deposition in fluorocarbon (C4F8, C3F6 and C5F8) plasmas , 2000 .

[11]  D. Graves,et al.  Atomistic simulation of silicon bombardment by energetic CF3+: product distributions and energies , 2000 .

[12]  J. Cecchi,et al.  Fluorocarbon polymer deposition kinetics in a low-pressure, high-density, inductively coupled plasma reactor , 2000 .

[13]  K. Karahashi,et al.  Desorption species from fluorocarbon film by Ar+ ion beam bombardment , 2000 .

[14]  M. Hori,et al.  Precursors of fluorocarbon film growth studied by mass spectrometry , 2000 .

[15]  S. Samukawa,et al.  High-performance silicon dioxide etching for less than 0.1-μm-high-aspect contact holes , 2000 .

[16]  M. Hori,et al.  Study on polymeric neutral species in high-density fluorocarbon plasmas , 2000 .

[17]  Neal R. Rueger,et al.  Effect of capacitive coupling on inductively coupled fluorocarbon plasma processing , 1999 .

[18]  J. Coburn,et al.  Mass spectrometric detection of reactive neutral species: Beam-to-background ratio , 1999 .

[19]  N. R. Rueger,et al.  Selective etching of SiO2 over polycrystalline silicon using CHF3 in an inductively coupled plasma reactor , 1999 .

[20]  J. Booth,et al.  CF2 PRODUCTION AND LOSS MECHANISMS IN FLUOROCARBON DISCHARGES : FLUORINE-POOR CONDITIONS AND POLYMERIZATION , 1999 .

[21]  K. Sasaki,et al.  Surface productions of CF and CF2 radicals in high-density fluorocarbon plasmas , 1998 .

[22]  G. Kroesen,et al.  Production and destruction of CFx radicals in radio‐frequency fluorocarbon plasmas , 1996 .

[23]  M. Horie Plasma‐structure dependence of the growth mechanism of plasma‐polymerized fluorocarbon films with residual radicals , 1995 .

[24]  H. Toyoda,et al.  Cross Section Measurements for Electron-Impact Dissociation of C 4F 8 into Neutral and Ionic Radicals , 1994 .

[25]  Ying Zhang,et al.  Fluorocarbon high‐density plasmas. I. Fluorocarbon film deposition and etching using CF4 and CHF3 , 1994 .

[26]  H. Sugai,et al.  Cross section measurements for electron-impact dissociation of SiF4 into neutral radicals , 1993 .

[27]  H. Toyoda,et al.  Appearance mass spectrometry of neutral radicals in radio frequency plasmas , 1992 .

[28]  R. D'agostino,et al.  Mechanisms of etching and polymerization in radiofrequency discharges of CF4–H2, CF4–C2F4, C2F6–H2, C3F8–H2 , 1983 .

[29]  E. Kay,et al.  Difluorocarbene Emission Spectra from Fluorocarbon Plasmas and Its Relationship to Fluorocarbon Polymer Formation , 1982 .