Ultrathin Graphdiyne Nanosheets Grown In Situ on Copper Nanowires and Their Performance as Lithium-Ion Battery Anodes.

A method is presented for the scalable preparation of high-quality graphdiyne nanotubes and ultrathin graphdiyne nanosheets (average thickness: ca. 1.9 nm) using Cu nanowires as a catalyst. For the storage of Li+ ions, the graphdiyne nanostructures show a high capacity of 1388 mAh g-1 and high rate performance (870 mA h g-1 at 10 A g-1 , and 449.8 mA h g-1 at 20 A g-1 ) with robust stability, demonstrating outstanding overall potential for its applications.

[1]  X. Lou,et al.  Rational Design of Three‐Layered TiO2@Carbon@MoS2 Hierarchical Nanotubes for Enhanced Lithium Storage , 2017, Advanced materials.

[2]  Dongdong Liu,et al.  Sandwiched Thin-Film Anode of Chemically Bonded Black Phosphorus/Graphene Hybrid for Lithium-Ion Battery. , 2017, Small.

[3]  Z. Zuo,et al.  A facile approach for graphdiyne preparation under atmosphere for an advanced battery anode. , 2017, Chemical communications.

[4]  Yuliang Li.  Design and self-assembly of advanced functional molecular materials—from low dimension to multi-dimension , 2017 .

[5]  Jing Li,et al.  A Tunable 3D Nanostructured Conductive Gel Framework Electrode for High‐Performance Lithium Ion Batteries , 2017, Advanced materials.

[6]  Z. Wen,et al.  Oxygen-Containing Amorphous Cobalt Sulfide Porous Nanocubes as High-Activity Electrocatalysts for the Oxygen Evolution Reaction in an Alkaline/Neutral Medium. , 2017, Angewandte Chemie.

[7]  Zhongfan Liu,et al.  Direct Synthesis of Graphdiyne Nanowalls on Arbitrary Substrates and Its Application for Photoelectrochemical Water Splitting Cell , 2017, Advanced materials.

[8]  San Ping Jiang,et al.  Prospects of Fuel Cell Technologies , 2017 .

[9]  K. Nagashio,et al.  Crystalline Graphdiyne Nanosheets Produced at a Gas/Liquid or Liquid/Liquid Interface. , 2017, Journal of the American Chemical Society.

[10]  Zaiping Guo,et al.  p-Type SnO thin layers on n-type SnS2 nanosheets with enriched surface defects and embedded charge transfer for lithium ion batteries , 2017 .

[11]  F. Marone,et al.  Quantifying microstructural dynamics and electrochemical activity of graphite and silicon-graphite lithium ion battery anodes , 2016, Nature Communications.

[12]  A. Manthiram,et al.  Combining Nitrogen-Doped Graphene Sheets and MoS2 : A Unique Film-Foam-Film Structure for Enhanced Lithium Storage. , 2016, Angewandte Chemie.

[13]  Jianjiang He,et al.  Graphdiyne applied for lithium-ion capacitors displaying high power and energy densities , 2016 .

[14]  Xu Wang,et al.  Layer-by-Layer Assembly of a Self-Healing Anticorrosion Coating on Magnesium Alloys. , 2015, ACS applied materials & interfaces.

[15]  Seok-Gwang Doo,et al.  Silicon carbide-free graphene growth on silicon for lithium-ion battery with high volumetric energy density , 2015, Nature Communications.

[16]  Gengmin Zhang,et al.  Synthesis of Graphdiyne Nanowalls Using Acetylenic Coupling Reaction. , 2015, Journal of the American Chemical Society.

[17]  G. Cui,et al.  Bulk graphdiyne powder applied for highly efficient lithium storage. , 2015, Chemical communications.

[18]  V. Chevrier,et al.  Alloy negative electrodes for Li-ion batteries. , 2014, Chemical reviews.

[19]  Bin Wang,et al.  Rational design of MoS2@graphene nanocables: towards high performance electrode materials for lithium ion batteries , 2014 .

[20]  Seongseop Kim,et al.  Advanced hybrid supercapacitor based on a mesoporous niobium pentoxide/carbon as high-performance anode. , 2014, ACS nano.

[21]  Junhong Chen,et al.  Facile one-pot, one-step synthesis of a carbon nanoarchitecture for an advanced multifunctonal electrocatalyst. , 2014, Angewandte Chemie.

[22]  Junhong Chen,et al.  Multilayered Si Nanoparticle/Reduced Graphene Oxide Hybrid as a High‐Performance Lithium‐Ion Battery Anode , 2014, Advanced materials.

[23]  J. Koo,et al.  Graphdiyne as a high-capacity lithium ion battery anode material , 2013 .

[24]  R. Li,et al.  Layer by layer assembly of sandwiched graphene/SnO2 nanorod/carbon nanostructures with ultrahigh lithium ion storage properties , 2013 .

[25]  Yi Cui,et al.  25th Anniversary Article: Understanding the Lithiation of Silicon and Other Alloying Anodes for Lithium‐Ion Batteries , 2013, Advanced materials.

[26]  Zheng Yan,et al.  Graphene nanoribbon and nanostructured SnO2 composite anodes for lithium ion batteries. , 2013, ACS nano.

[27]  Zhenan Bao,et al.  Stable Li-ion battery anodes by in-situ polymerization of conducting hydrogel to conformally coat silicon nanoparticles , 2013, Nature Communications.

[28]  Jaephil Cho,et al.  Catalyst-free direct growth of a single to a few layers of graphene on a germanium nanowire for the anode material of a lithium battery. , 2013, Angewandte Chemie.

[29]  Bruce Dunn,et al.  High-rate electrochemical energy storage through Li+ intercalation pseudocapacitance. , 2013, Nature materials.

[30]  R. Swathi,et al.  Rattling motion of alkali metal ions through the cavities of model compounds of graphyne and graphdiyne. , 2013, The journal of physical chemistry. A.

[31]  Yu‐Guo Guo,et al.  Binding SnO2 Nanocrystals in Nitrogen‐Doped Graphene Sheets as Anode Materials for Lithium‐Ion Batteries , 2013, Advanced materials.

[32]  B. Chowdari,et al.  Metal oxides and oxysalts as anode materials for Li ion batteries. , 2013, Chemical reviews.

[33]  Xin-bo Zhang,et al.  In situ fabrication of porous graphene electrodes for high-performance energy storage. , 2013, ACS nano.

[34]  Meng Zhang,et al.  Graphdiyne: A promising anode material for lithium ion batteries with high capacity and rate capability , 2013 .

[35]  Chenghua Sun,et al.  Lithium storage on graphdiyne predicted by DFT calculations , 2012 .

[36]  Yadong Li,et al.  Facile Shape Control of Co3O4 and the Effect of the Crystal Plane on Electrochemical Performance , 2012, Advanced materials.

[37]  Fan Zhang,et al.  Two-dimensional carbon-coated graphene/metal oxide hybrids for enhanced lithium storage. , 2012, ACS nano.

[38]  G. Yushin,et al.  A Major Constituent of Brown Algae for Use in High-Capacity Li-Ion Batteries , 2011, Science.

[39]  Hongyu Zhang,et al.  High Mobility and High Storage Capacity of Lithium in sp–sp2 Hybridized Carbon Network: The Case of Graphyne , 2011 .

[40]  Daoben Zhu,et al.  Architecture of graphdiyne nanoscale films. , 2010, Chemical communications.

[41]  M. Armand,et al.  Issues and challenges facing rechargeable lithium batteries , 2001, Nature.

[42]  Petr Novák,et al.  Insertion Electrode Materials for Rechargeable Lithium Batteries , 1998 .

[43]  A. Hagfeldt,et al.  Li+ Ion Insertion in TiO2 (Anatase). 2. Voltammetry on Nanoporous Films , 1997 .

[44]  L. Mai,et al.  Energy storage through intercalation reactions: electrodes for rechargeable batteries , 2017 .

[45]  P. Ajayan,et al.  A Bottom‐Up Approach to Build 3D Architectures from Nanosheets for Superior Lithium Storage , 2014 .

[46]  Huaihe Song,et al.  Two dimensional graphene–SnS2 hybrids with superior rate capability for lithium ion storage , 2012 .