3-D Microscopic Measurement and Analysis of Chemical Flow and Transport in Porous Media

Chemical flow and transport have been studied at the pore-scale in an experimental porous medium. Measurements have been taken using a novel nonintrusive fluorescence imaging technique. The experimental setup consists of a cylindrical column carved out of a clear plastic block, packed with clear beads of the same material. A refractive index-matched fluid was pumped under laminar, slow-flow conditions through the column. The fluid was seeded with tracer particles or a solute organic dye for flow and chemical transport measurements, respectively. The system is automated to image through the porous medium for collecting microscopic values of velocity, concentration, and pore geometry at high-accuracy and high-resolution. Various geometric, flow, and transport quantities have been obtained in a full three-dimensional volume within the porous medium. These include microscopic (pore-scale) medium geometry, velocity and concentration fields, dispersive solute fluxes, and reasonable estimates ofa representative elementary volume (REV) for the porous medium.

[1]  Thomas J. Kulp,et al.  Measurement of porous medium velocity fields and their volumetric averaging characteristics using particle tracking velocimetry , 1995 .

[2]  Warren E. Stewart,et al.  Optical measurements of porosity and fluid motion in packed beds , 1986 .

[3]  Mehdi Rashidi,et al.  Experimental analysis of pore-scale flow and transport in porous media , 1996 .

[4]  R. V. Edwards,et al.  A New Look at Porous Media Fluid Mechanics — Darcy to Turbulent , 1984 .

[5]  D. U. Rosenberg,et al.  A Mathematical and Experimental Examination of Transverse Dispersion Coefficients , 1968 .

[6]  John C. Slattery,et al.  Flow of viscoelastic fluids through porous media , 1967 .

[7]  Michael A. Celia,et al.  MICROMODEL STUDIES OF THREE-FLUID POROUS MEDIA SYSTEMS : PORE-SCALE PROCESSES RELATING TO CAPILLARY PRESSURE-SATURATION RELATIONSHIPS , 1993 .

[8]  J. Seymour,et al.  Visualization of flow patterns of cellulose fiber suspensions by NMR imaging , 1994 .

[9]  George F. Pinder,et al.  Direct measurement of interstitial velocity field variations in a porous medium using fluorescent-particle image velocimetry , 1993 .

[10]  Ruben G. Carbonell,et al.  Longitudinal and lateral dispersion in packed beds: Effect of column length and particle size distribution , 1985 .

[11]  Philippe C. Baveye,et al.  The Operational Significance of the Continuum Hypothesis in the Theory of Water Movement Through Soils and Aquifers , 1984 .

[12]  Johnson,et al.  Onset and Stability of Convection in Porous Media: Visualization by Magnetic Resonance Imaging. , 1995, Physical review letters.

[13]  William G. Gray,et al.  Photoluminescent volumetric imaging: a technique for the exploration of multiphase flow and transport in porous media , 1995 .

[14]  J. M. Smith,et al.  Flow Distribution in Packed Beds , 1953 .

[15]  D. Klotz,et al.  Dispersivity and velocity relationship from laboratory and field experiments , 1980 .

[16]  Donald R. F. Harleman,et al.  Longitudinal and lateral dispersion in an isotropic porous medium , 1963, Journal of Fluid Mechanics.

[17]  K. R. Jolls,et al.  Transition to turbulence for flow through a dumped bed of spheres , 1966 .

[18]  K. R. Jolls,et al.  Use of electrochemical techniques to study mass transfer rates and local skin friction to a sphere in a dumped bed , 1969 .

[19]  J. Andrew Derbyshire,et al.  Rapid three-dimensional velocimetry by nuclear magnetic resonance imaging , 1994 .

[20]  William G. Gray,et al.  General conservation equations for multi-phase systems: 1. Averaging procedure , 1979 .

[21]  J. Bear Dynamics of Fluids in Porous Media , 1975 .

[22]  John L. Wilson,et al.  Visualization of the role of the gas‐water interface on the fate and transport of colloids in porous media , 1994 .

[23]  Stephen Whitaker,et al.  ADVANCES IN THEORY OF FLUID MOTION IN POROUS MEDIA , 1969 .

[24]  J. Thovert,et al.  Flow along porous media by partical image velocimetry , 1993 .

[25]  R. C. Givler,et al.  A determination of the effective viscosity for the Brinkman–Forchheimer flow model , 1994, Journal of Fluid Mechanics.

[26]  Non Invasive Measurement Techniques in Porous Media , 1991 .

[27]  Thomas J. Hanratty,et al.  Visual studies of flow in a regular array of spheres , 1971 .

[28]  S. Whitaker Diffusion and dispersion in porous media , 1967 .

[29]  W. E. Soll,et al.  A modified percolation approach to simulating three-fluid capillary pressure-saturation relationships , 1993 .

[30]  W. G. Gray,et al.  A derivation of the equations for multi-phase transport , 1975 .

[31]  M. Rashidi,et al.  Turbulence structure in free‐surface channel flows , 1988 .