Dimethyl 3,4,5,5-tetraphenyl-1,3-thiazolidine-2,2-dicarboxylate and 3,3-dichloro-2,2,4,4,3'-pentamethyl-r-2',t-4'-diphenylcyclobutane-1-spiro-5'-1,3-thiazolidine.

The first of the title compounds, C31H27NO4S, (V), crystallizes in the monoclinic space group P21/c with two independent mol­ecules in the asymmetric unit, while the second, C23H27Cl2NS, (IX), crystallizes in the orthorhombic space group Pbca with one mol­ecule in the asymmetric unit. In both crystal structures, the 1,3-thia­zolidine ring adopts a half-chair conformation. The crystal structures are stabilized by weak C—H⋯O and C—H⋯Cl hydrogen bonds in (V) and (IX), respectively.

[1]  S. J. Grabowski,et al.  Crystal and molecular structure of (r-2, c-4)-3-benzyl-2,4,5,5-tetraphenyl1,3-thiazolidine, intramolecular C–H⋯S hydrogen bonds , 2004 .

[2]  A. Linden,et al.  New Studies on [2+3] Cycloadditions of Thermally Generated N‐Isopropyl‐ and N‐(4‐Methoxyphenyl)‐Substituted Azomethine Ylides , 2004 .

[3]  S. J. Grabowski,et al.  Role of C−H···S and C−H···N Hydrogen Bonds in Organic Crystal StructuresThe Crystal and Molecular Structure of 3-Methyl-2,4-diphenyl-(1,3)-thiazolidine-5-spiro-2‘-adamantane and 3-Methyl-2,4,5,5-tetraphenyl-(1,3)-thiazolidine , 2003 .

[4]  Myung-Jong Jin,et al.  ChemInform Abstract: Enantioselective Addition of Diethylzinc to Aldehydes with Easily Prepared Chiral Thiazolidine Catalysts. , 2002 .

[5]  A. Linden,et al.  Unexpected formation of dimethylthioketene cycloadducts in the reaction of 1,3-diphenylaziridine-2,2-dicarboxylate with cyclobutanethione derivatives , 2002 .

[6]  G. Mlostoń,et al.  1,3‐Thiazolidine‐dicarboxylates from Thioketones and Thermally Generated Azomethine Ylides , 2002 .

[7]  Gautam R. Desiraju,et al.  The Weak Hydrogen Bond: In Structural Chemistry and Biology , 1999 .

[8]  G. Crini,et al.  New Dipeptides Containing Thiazolidine-4-carboxylic Acid Derivatives : Synthesis and Characterization Using NMR Techniques and X-Ray Data , 1999 .

[9]  Z. Ciunik,et al.  Hybride interactions (stacking + H-bonds) between molecules bearing benzyl groups , 1998 .

[10]  Z. Ciunik,et al.  New aspects of weak CH⋯π bonds: intermolecular interactions between alicyclic and aromatic rings in crystals of small compounds, peptides and proteins , 1998 .

[11]  M. Nardelli Help for checking space-group symmetry , 1996 .

[12]  Gautam R. Desiraju,et al.  Supramolecular Synthons in Crystal Engineering—A New Organic Synthesis , 1995 .

[13]  Raymond E. Davis,et al.  Patterns in Hydrogen Bonding: Functionality and Graph Set Analysis in Crystals , 1995 .

[14]  Professor Dr. George A. Jeffrey,et al.  Hydrogen Bonding in Biological Structures , 1991, Springer Berlin Heidelberg.

[15]  Olga Kennard,et al.  Crystallographic evidence for the existence of CH.cntdot..cntdot..cntdot.O, CH.cntdot..cntdot..cntdot.N and CH.cntdot..cntdot..cntdot.Cl hydrogen bonds , 1982 .

[16]  D. Cremer,et al.  General definition of ring puckering coordinates , 1975 .

[17]  E. Adman,et al.  Crystal and molecular structure of cis-1,3-cyclobutanedicarboxylic acid , 1969 .

[18]  R. Bader Atoms in molecules : a quantum theory , 1990 .

[19]  Gautam R. Desiraju,et al.  Crystal engineering : the design of organic solids , 1989 .