Dissociative electron attachment to hydrogen

Using two different crossed-beams high-resolution electron attachment instruments (employing either a trochoidal electron monochromator or a hemispherical electron monochromator) we have determined the cross section curve for H- production from H2 via the 4 eV resonance at two different temperatures. These relative partial cross sections have been calibrated by comparing present values for the 14 eV resonance with absolute total cross sections determined previously. Taking into account the experimental energy distribution and the rotational excitation and its influence on the cross section shape we obtain very good agreement with theoretical predictions in terms of both the shape and magnitude of this resonance peak.

[1]  T. Märk,et al.  The working principle of the trochoidal electron monochromator revisited 2 2 Dedicated to Professor Aleksandar Stamatovic on the occasion of his 60th birthday. , 2001 .

[2]  T. Märk,et al.  Dissociative electron attachment to CF2Cl2 , 1999 .

[3]  J. Horáček,et al.  Nuclear dynamics of the H collision complex beyond the local approximation: associative detachment and dissociative attachment to rotationally and vibrationally excited molecules , 1998 .

[4]  T. Märk,et al.  Dissociative electron attachment to CO and NO: the O− production threshold revisited , 1998 .

[5]  T. Märk,et al.  Dissociative electron attachment cross section to CHCl3 using a high resolution crossed beams technique , 1997 .

[6]  G. Gallup,et al.  Nonlocal theory of dissociative electron attachment to H 2 and HF molecules , 1997 .

[7]  R. Hall,et al.  The influence of a thin gold film on vibrational excitation of hydrogen molecules , 1997 .

[8]  Stampfli,et al.  Vibrationally Resolved Electron Attachment to Oxygen Clusters. , 1996, Physical review letters.

[9]  T. Märk,et al.  Absolute partial and total cross‐section functions for the electron impact ionization of C60 and C70 , 1996 .

[10]  R. Hall,et al.  THE FORMATION OF VIBRATIONALLY EXCITED HYDROGEN MOLECULES ON CARBON SURFACES , 1996 .

[11]  W. Graham The kinetics of negative hydrogen ions in discharges , 1995 .

[12]  R. Hall,et al.  Highly excited hydrogen molecules desorbed from a surface: Experimental results , 1994 .

[13]  D. Popović,et al.  Hydrogen recombination on metals: vibrational excitation of desorbed molecules , 1993 .

[14]  Robicheaux Driving nuclei with resonant electrons: Ab initio study of (e+H2) 2 Sigma u+ , 1991, Physical review. A, Atomic, molecular, and optical physics.

[15]  Hickman Dissociative attachment of electrons to vibrationally excited H2. , 1991, Physical review. A, Atomic, molecular, and optical physics.

[16]  Wadehra,et al.  Nonlocal effects in dissociative electron attachment to H2. , 1990, Physical review. A, Atomic, molecular, and optical physics.

[17]  D. Popović,et al.  Detection and measurement of ro-vibrational populations in molecular hydrogen , 1990 .

[18]  R. Hall,et al.  Dissociative electron attachment to vibrationally excited H2 and D2 molecules: the 14 eV process , 1988 .

[19]  Berman,et al.  Nuclear dynamics in resonant electron-molecule scattering beyond the local approximation: Vibrational excitation and dissociative attachment in H2 and D2. , 1985, Physical review. A, General physics.

[20]  H. P. Gauyacq Dissociative attachment in e--H2 collisions , 1985 .

[21]  J. M. Wadehra,et al.  Vibrational- and rotational-state dependence of dissociative attachment in e-H/sub 2/ collisions , 1978 .

[22]  S. Wong,et al.  Effect of vibrational and rotational excitation on dissociative attachment in hydrogen , 1978 .

[23]  M. Bacal,et al.  Equilibrium density of h- in a low pressure hydrogen plasma , 1977 .

[24]  G. Schulz,et al.  ISOTOPE EFFECT IN THE DISSOCIATIVE ATTACHMENT IN H2 AT LOW ENERGY. , 1967 .

[25]  G. Schulz,et al.  FORMATION OF H(-) BY ELECTRON IMPACT ON H2 AT LOW ENERGY , 1965 .

[26]  T. E. Sharp,et al.  Large Isotope Effect in the Formation of H − or D − by Electron Impact on H 2 , HD, and D 2 , 1965 .

[27]  G. Schulz,et al.  Formation of H - Ions by Electron Impact on H 2 , 1959 .