Oxidative dehydrogenation of ethane: catalytic and mechanistic aspects and future trends.

Ethene is a commodity chemical of great importance for manufacturing diverse consumer products, whose synthesis via crude oil steam cracking is one of the most energy-intensive processes in the petrochemical industry. Oxidative dehydrogenation (ODH) of ethane is an attractive, low energy, alternative route to ethene which could reduce the carbon footprint for its production, however, the commercial implementation of ODH requires catalysts with improved selectivity. This review critically assesses recent developments in catalytic technologies for ethane ODH, and discusses how insight into proposed mechanisms from computational studies, and CO2 assisted ethane dehydrogenation (CO2-DHE), provide opportunities for economically viable processes to meet growing demands for ethene while reducing carbon emissions. Future trends and emerging technologies for ethane ODH are also discussed.

[1]  A. Lemonidou,et al.  CO2-oxidative ethane dehydrogenation over highly efficient carbon-resistant Fe-catalysts , 2020 .

[2]  Xiaodong Wang,et al.  Sulfate-Modified NiAl Mixed Oxides as Effective C–H Bond-Breaking Agents for the Sole Production of Ethylene from Ethane , 2020, ACS Catalysis.

[3]  J. Herrera,et al.  Generalized Mechanistic Framework for Ethane Dehydrogenation and Oxidative Dehydrogenation on Molybdenum Oxide Catalysts , 2020, ACS Catalysis.

[4]  Y. Sekine,et al.  Catalytic conversion of ethane to valuable products through non-oxidative dehydrogenation and dehydroaromatization , 2020, RSC advances.

[5]  Izabela A. Samek,et al.  Structure and activity of mixed VOx-CeO2 domains supported on alumina in cyclohexane oxidative dehydrogenation , 2020 .

[6]  D. Melzer,et al.  Intrinsic kinetic model for oxidative dehydrogenation of ethane over MoVTeNb mixed metal oxides: A mechanistic approach , 2020 .

[7]  K. Wilson,et al.  A spatially orthogonal hierarchically porous acid–base catalyst for cascade and antagonistic reactions , 2019, Nature Catalysis.

[8]  F. Jing,et al.  Improved Catalytic Performance of Ethane Dehydrogenation in the Presence of CO2 over Zr-Promoted Cr/SiO2 , 2019, ACS omega.

[9]  Jingguang G. Chen,et al.  Carbon dioxide reduction in tandem with light-alkane dehydrogenation , 2019, Nature Reviews Chemistry.

[10]  N. Browning,et al.  Design and synthesis of highly active MoVTeNb-oxides for ethane oxidative dehydrogenation , 2019, Nature Communications.

[11]  Fanxing Li,et al.  Intensified Ethylene Production via Chemical Looping through an Exergetically Efficient Redox Scheme , 2019, iScience.

[12]  Saeed Abbasizadeh,et al.  Present state of the art of and outlook on oxidative dehydrogenation of ethane: catalysts and mechanisms , 2019, Reviews in Chemical Engineering.

[13]  E. Rodríguez-Castellón,et al.  Support effects on NiO-based catalysts for the oxidative dehydrogenation (ODH) of ethane , 2019, Catalysis Today.

[14]  V. Svetlichnyi,et al.  Oxidative dehydrogenation of ethane with CO2 over CrOx catalysts supported on Al2O3, ZrO2, CeO2 and CexZr1-xO2 , 2019, Catalysis Today.

[15]  T. Kardash,et al.  NAP-XPS and in situ XRD study of the stability of Bi-modified MoVNbTeO catalysts for oxidative dehydrogenation of ethane , 2019, Applied Catalysis A: General.

[16]  A. Bhan,et al.  Pathways, mechanisms, and kinetics: a strategy to examine byproduct selectivity in partial oxidation catalytic transformations on reducible oxides , 2019, Reaction Chemistry & Engineering.

[17]  B. Liu,et al.  Modeling C–H Bond Activation and Oxidations of Alkanes over Cu–MOR Using First-Principles Methods , 2019, The Journal of Physical Chemistry C.

[18]  I. Rodushkin,et al.  Tellurium in the environment: current knowledge and identification of gaps , 2019, Environmental Chemistry.

[19]  Eunnyeong Heo,et al.  Effects of the shale boom on ethylene and propylene prices , 2019, Energy Sources, Part B: Economics, Planning, and Policy.

[20]  J. Védrine.  Metal Oxides in Heterogeneous Oxidation Catalysis: State of the Art and Challenges for a More Sustainable World. , 2019, ChemSusChem.

[21]  J. Nørskov,et al.  First principles micro-kinetic model of catalytic non-oxidative dehydrogenation of ethane over close-packed metallic facets , 2018, Journal of Catalysis.

[22]  J. Yi,et al.  Promoting effect of cerium on MoVTeNb mixed oxide catalyst for oxidative dehydrogenation of ethane to ethylene , 2018, Applied Catalysis B: Environmental.

[23]  Fanxing Li,et al.  Oxidative dehydrogenation of ethane using MoO3/Fe2O3 catalysts in a cyclic redox mode , 2018, Catalysis Today.

[24]  K. Wu,et al.  Metal–Organic Framework (MOF)-Derived Effective Solid Catalysts for Valorization of Lignocellulosic Biomass , 2018, ACS Sustainable Chemistry & Engineering.

[25]  Danfeng Shao,et al.  Progress in selective oxidative dehydrogenation of light alkanes to olefins promoted by boron nitride catalysts. , 2018, Chemical communications.

[26]  Yi Cheng,et al.  Catalytic performance of phase-pure M1 MoVNbTeOx/CeO2 composite for oxidative dehydrogenation of ethane , 2018, Journal of Catalysis.

[27]  Xiaodong Wang,et al.  Enhanced performance of boron nitride catalysts with induction period for the oxidative dehydrogenation of ethane to ethylene , 2018, Journal of Catalysis.

[28]  Fanxing Li,et al.  Manganese silicate based redox catalysts for greener ethylene production via chemical looping – oxidative dehydrogenation of ethane , 2018, Applied Catalysis B: Environmental.

[29]  F. Dong,et al.  Photocatalytic Oxidative Dehydrogenation of Ethane Using CO2 as a Soft Oxidant over Pd/TiO2 Catalysts to C2H4 and Syngas , 2018, ACS Catalysis.

[30]  Yong Lu,et al.  Low-temperature, highly selective, highly stable Nb2O5–NiO/Ni-foam catalyst for the oxidative dehydrogenation of ethane , 2018 .

[31]  Cheng Yanhu,et al.  Silica-doped TiO2 as support of gallium oxide for dehydrogenation of ethane with CO2 , 2018, Fuel Processing Technology.

[32]  Ming-Kang Tsai,et al.  Ethane oxidative dehydrogenation mechanism on MoO3(010) surface: A first-principle study using on-site Coulomb correction , 2018, Surface Science.

[33]  Meilin Liu,et al.  A novel low-thermal-budget approach for the co-production of ethylene and hydrogen via the electrochemical non-oxidative deprotonation of ethane , 2018 .

[34]  Atsushi Takagaki,et al.  Oxidative Dehydrogenation of Ethane Using Ball-milled Hexagonal Boron Nitride , 2018, Chemistry Letters.

[35]  S. Suib,et al.  Influence of Tight Confinement on Selective Oxidative Dehydrogenation of Ethane on MoVTeNb Mixed Oxides , 2018, ACS Catalysis.

[36]  C. Liu,et al.  SiO2-Modified Pt/Al2O3 for Oxidative Dehydrogenation of Ethane: A Preparation Method for Improved Catalytic Stability, Ethylene Selectivity, and Coking Resistance , 2018, Industrial & Engineering Chemistry Research.

[37]  V. V. Chesnokov,et al.  The oxidative dehydrogenation of ethane: Convectional vs microwave heating of Ba - containing catalysts , 2018, Chemical Engineering and Processing - Process Intensification.

[38]  U. Ozkan,et al.  Effect of lanthanum and chlorine doping on strontium titanates for the electrocatalytically-assisted oxidative dehydrogenation of ethane , 2018, Applied Catalysis B: Environmental.

[39]  Eric E Stangland,et al.  Shale Gas Implications for C2-C3 Olefin Production: Incumbent and Future Technology. , 2018, Annual review of chemical and biomolecular engineering.

[40]  Song Qiu,et al.  Hydrothermal synthesis of NiCeOx nanosheets and its application to the total oxidation of propane , 2018, Applied Catalysis B: Environmental.

[41]  J. Wiklund,et al.  Widespread Atmospheric Tellurium Contamination in Industrial and Remote Regions of Canada. , 2018, Environmental science & technology.

[42]  Changxi Miao,et al.  Oxidative Dehydrogenation of Ethane with CO2 over Au/CeO2 Nanorod Catalysts , 2018, Catalysis Letters.

[43]  Jingli Luo,et al.  Stable SrCo0.7Fe0.2Zr0.1O3-δ cathode material for proton conducting solid oxide fuel cell reactors , 2018 .

[44]  L. Kustov,et al.  Ethane oxidative dehydrogenation to ethylene in a membrane reactor with asymmetric ceramic membranes , 2018 .

[45]  M. Argyle,et al.  Low Temperature Oxidative Dehydrogenation of Ethane by Ce-Modified NiNb Catalysts , 2018 .

[46]  D. Iranshahi,et al.  Thermal Integration of Sulfuric Acid and Continuous Catalyst Regeneration of Naphtha Reforming Plants , 2018 .

[47]  M. Rønning,et al.  Influence of H2 on the Oxygen-Assisted Dehydrogenation of Ethane over Al2O3-supported Pt–Sn Catalysts , 2018, Catalysis Letters.

[48]  A. Corma,et al.  Synthesis and structure determination via ultra-fast electron diffraction of the new microporous zeolitic germanosilicate ITQ-62. , 2018, Chemical communications.

[49]  Fanxing Li,et al.  Alkali Metal-Promoted LaxSr2–xFeO4−δ Redox Catalysts for Chemical Looping Oxidative Dehydrogenation of Ethane , 2018 .

[50]  Yong Lu,et al.  Oxidative dehydrogenation of ethane to ethylene: A promising CeO2-ZrO2-modified NiO-Al2O3/Ni-foam catalyst , 2018 .

[51]  M. Haghighi,et al.  CO2/O2-enhanced ethane dehydrogenation over a sol–gel synthesized Ni/ZrO2–MgO nanocatalyst: Effects of Mgo, ZrO2,and NiO on the catalytic performance , 2018 .

[52]  Liu Wenbin,et al.  Synthesis of Three-Dimensionally Ordered Macroporous NiCe Catalysts for Oxidative Dehydrogenation of Propane to Propene , 2018 .

[53]  J. T. Grant,et al.  Aerobic Oxidations of Light Alkanes over Solid Metal Oxide Catalysts. , 2017, Chemical reviews.

[54]  J. Nieto,et al.  Gas phase heterogeneous partial oxidation reactions , 2018 .

[55]  Jingli Luo,et al.  Cogeneration of ethylene and energy in protonic fuel cell with an efficient and stable anode anchored with in-situ exsolved functional metal nanoparticles , 2018 .

[56]  F. Rezaei,et al.  Oxidative dehydrogenation of propane to propylene with carbon dioxide , 2018 .

[57]  E. Rodríguez-Castellón,et al.  Mixed oxide Ti Si O prepared by non-hydrolytic Xerogel method as a diluter of nickel oxide for the oxidative dehydrogenation of ethane , 2018 .

[58]  G. Giannakakis,et al.  Simulation-aided effective design of a catalytic reactor for ethane oxidative dehydrogenation over NiNbOx , 2018 .

[59]  Juan Zhou,et al.  Oxidative dehydrogenation of propane over three-dimensionally ordered macroporous VMgO catalysts with different vanadium doping , 2018, Journal of Porous Materials.

[60]  A. Lemonidou,et al.  Olefins from Biomass Intermediates: A Review , 2017 .

[61]  S. Razzak,et al.  Fluidized bed oxidative dehydrogenation of ethane to ethylene over VOx/Ce-γAl2O3 catalysts: Reduction kinetics and catalyst activity , 2017 .

[62]  J. Klemeš,et al.  Mechanisms and kinetics of CO2 hydrogenation to value-added products: A detailed review on current status and future trends , 2017 .

[63]  C. Baroi,et al.  Process economics and safety considerations for the oxidative dehydrogenation of ethane using the M1 catalyst , 2017 .

[64]  Yu Wang,et al.  Control of zeolite framework flexibility and pore topology for separation of ethane and ethylene , 2017, Science.

[65]  R. Bal,et al.  MoO3 Nanoclusters Decorated on TiO2 Nanorods for Oxidative dehydrogenation of ethane to ethylene , 2017 .

[66]  P. Avila,et al.  Novel Ni-Ce-Zr/Al2O3 Cellular Structure for the Oxidative Dehydrogenation of Ethane , 2017 .

[67]  E. Rodríguez-Castellón,et al.  Redox and Catalytic Properties of Promoted NiO Catalysts for the Oxidative Dehydrogenation of Ethane , 2017 .

[68]  J. Klemeš,et al.  Utilising a radial flow, spherical packed-bed reactor for auto thermal steam reforming of methane to achieve a high capacity of H-2 production , 2017 .

[69]  A. Ghorbel,et al.  Ethane Oxidative Dehydrogenation over ternary and binary mixtures of alkaline and alkaline earth chlorides supported on zeolites , 2017 .

[70]  Comparison of conventional and spherical reactor for the industrial auto-thermal reforming of methane to maximize synthesis gas and minimize CO2 , 2017 .

[71]  Fanxing Li,et al.  Effect of Promoters on Manganese-Containing Mixed Metal Oxides for Oxidative Dehydrogenation of Ethane via a Cyclic Redox Scheme , 2017 .

[72]  J. Fierro,et al.  Catalytic hydrodeoxygenation of anisole over Re-MoOx/TiO2 and Re-VOx/TiO2 catalysts , 2017 .

[73]  Ashutosh Kumar,et al.  Ethanol steam reforming for hydrogen production: Latest and effective catalyst modification strategies to minimize carbonaceous deactivation , 2017 .

[74]  Samrand Saeidi,et al.  Selective acid-functionalized mesoporous silica catalyst for conversion of glycerol to monoglycerides: state of the art and future prospects , 2017 .

[75]  A. Gaffney,et al.  Ethylene production via Oxidative Dehydrogenation of Ethane using M1 catalyst , 2017 .

[76]  Kevin Van Geem,et al.  New Trends in Olefin Production , 2017 .

[77]  M. D. Soriano,et al.  NiO diluted in high surface area TiO2 as an efficient catalyst for the oxidative dehydrogenation of ethane , 2017 .

[78]  M. Haghighi,et al.  Enhanced dispersion of Cr nanoparticles over nanostructured ZrO2-doped ZSM-5 used in CO2-oxydehydrogenation of ethane , 2017 .

[79]  T. Kardash,et al.  Effect of Bi on catalytic performance and stability of MoVTeNbO catalysts in oxidative dehydrogenation of ethane , 2017 .

[80]  R. Schlögl,et al.  Functional Analysis of Catalysts for Lower Alkane Oxidation , 2017 .

[81]  José Antonio Moya,et al.  Production costs of the chemical industry in the EU and other countries: Ammonia, methanol and light olefins , 2017 .

[82]  Danfeng Shao,et al.  Selective oxidative dehydrogenation of ethane to ethylene over a hydroxylated boron nitride catalyst , 2017 .

[83]  Jens K Nørskov,et al.  Understanding trends in C-H bond activation in heterogeneous catalysis. , 2017, Nature materials.

[84]  Yong Lu,et al.  Microstructured CeO2-NiO-Al2O3/Ni-foam catalyst for oxidative dehydrogenation of ethane to ethylene , 2017 .

[85]  Saad A. Al-Bogami,et al.  Crude oil to chemicals: light olefins from crude oil , 2017 .

[86]  S. Razzak,et al.  Phenomenologically based kinetics of ODH of ethane to ethylene using lattice oxygen of VOx/Al2O3–ZrO2 catalyst , 2017 .

[87]  J. Baltrusaitis,et al.  CH4 conversion to value added products: Potential, limitations and extensions of a single step heterogeneous catalysis , 2016 .

[88]  B. M. Reddy,et al.  CO2 as a soft oxidant for oxidative dehydrogenation reaction: An eco benign process for industry , 2016 .

[89]  J. Védrine.  Heterogeneous catalytic partial oxidation of lower alkanes (C1-C6) on mixed metal oxides , 2016 .

[90]  M. Haghighi,et al.  CO2-enhanced dehydrogenation of ethane over sonochemically synthesized Cr/clinoptilolite-ZrO2 nanocatalyst: Effects of ultrasound irradiation and ZrO2 loading on catalytic activity and stability. , 2016, Ultrasonics sonochemistry.

[91]  S. Pratsinis,et al.  Silica is preferred over various single and mixed oxides as support for CO2-assisted cobalt-catalyzed oxidative dehydrogenation of ethane , 2016 .

[92]  Fanxing Li,et al.  Oxidative Dehydrogenation of Ethane: A Chemical Looping Approach , 2016 .

[93]  A. Gaffney,et al.  Techno-Economic Analysis of Oxidative Dehydrogenation Options , 2016, Topics in Catalysis.

[94]  S. Mandal,et al.  Lower alkanes dehydrogenation: Strategies and reaction routes to corresponding alkenes , 2016 .

[95]  Avelino Corma,et al.  Ultrafast Electron Diffraction Tomography for Structure Determination of the New Zeolite ITQ-58 , 2016, Journal of the American Chemical Society.

[96]  N. Browning,et al.  Atomic-Scale Determination of Active Facets on the MoVTeNb Oxide M1 Phase and Their Intrinsic Catalytic Activity for Ethane Oxidative Dehydrogenation. , 2016, Angewandte Chemie.

[97]  M. Haghighi,et al.  C2H6/CO2 oxidative dehydrogenation (ODH) reaction on nanostructured CrAPSO-34 catalyst: One-pot hydrothermal vs. conventional hydrothermal/impregnation catalyst synthesis , 2016, Korean Journal of Chemical Engineering.

[98]  Qinglong Liu,et al.  Promoted catalytic performances of highly dispersed V-doped SBA-16 catalysts for oxidative dehydrogenation of ethane to ethylene , 2016 .

[99]  A. Yaroslavtsev,et al.  Effect of the composition of (Mo, Nb, V, Ti)/γ-Al2O3 surface oxide structures on the oxidative dehydrogenation of ethane to ethylene , 2016, Russian Journal of Applied Chemistry.

[100]  M. D. Soriano,et al.  Nickel oxide supported on porous clay heterostructures as selective catalysts for the oxidative dehydrogenation of ethane , 2016 .

[101]  M. Haghighi,et al.  Impregnation vs. coprecipitation dispersion of Cr over TiO2 and ZrO2 used as active and stable nanocatalysts in oxidative dehydrogenation of ethane to ethylene by carbon dioxide , 2016 .

[102]  J. Radnik,et al.  Oxidative dehydrogenation of ethane to ethylene over Ni–Nb–M–O catalysts: Effect of promoter metal and CO2-admixture on the performance , 2016 .

[103]  M. Harb,et al.  Ni–M–O (M = Sn, Ti, W) Catalysts Prepared by a Dry Mixing Method for Oxidative Dehydrogenation of Ethane , 2016 .

[104]  T. Kardash,et al.  Effect of K and Bi doping on the M1 phase in MoVTeNbO catalysts for ethane oxidative conversion to ethylene , 2016 .

[105]  Jingli Luo,et al.  Double-Layered Perovskite Anode with in Situ Exsolution of a Co–Fe Alloy To Cogenerate Ethylene and Electricity in a Proton-Conducting Ethane Fuel Cell , 2016 .

[106]  Qinglong Liu,et al.  Oxidative dehydrogenation of ethane to ethylene over Mo-incorporated mesoporous SBA-16 catalysts: The effect of MoOx dispersion , 2016 .

[107]  S. Razzak,et al.  Reduction kinetics and catalytic activity of VOx/γ-Al2O3-ZrO2 for gas phase oxygen free ODH of ethane , 2016 .

[108]  P. Alphonse,et al.  Co–Mn-oxide spinel catalysts for CO and propane oxidation at mild temperature , 2016 .

[109]  K. Boubaker,et al.  Structural, optical, vibrational and photoluminescence studies of Sn-doped MoO3 sprayed thin films , 2015 .

[110]  M. Haghighi,et al.  The beneficial utilization of natural zeolite in preparation of Cr/clinoptilolite nanocatalyst used in CO2-oxidative dehydrogenation of ethane to ethylene , 2015 .

[111]  F. López-Isunza,et al.  Modeling of oxidative dehydrogenation of ethane to ethylene on a MoVTeNbO/TiO2 catalyst in an industrial-scale packed bed catalytic reactor , 2015 .

[112]  Cheng Yanhu,et al.  Ga2O3/HSSZ-13 for dehydrogenation of ethane: Effect of pore geometry of support , 2015 .

[113]  Yi Cheng,et al.  Valence variation of phase-pure M1 MoVNbTe oxide by plasma treatment for improved catalytic performance in oxidative dehydrogenation of ethane , 2015 .

[114]  S. Razzak,et al.  Fluidized bed ODH of ethane to ethylene over VOx–MoOx/γ-Al2O3 catalyst: Desorption kinetics and catalytic activity , 2015 .

[115]  A. Chieregato,et al.  Mixed-oxide catalysts with vanadium as the key element for gas-phase reactions , 2015 .

[116]  W. Goddard,et al.  In Silico Design of Highly Selective Mo-V-Te-Nb-O Mixed Metal Oxide Catalysts for Ammoxidation and Oxidative Dehydrogenation of Propane and Ethane. , 2015, Journal of the American Chemical Society.

[117]  D. Anjum,et al.  Ni–Ta–O mixed oxide catalysts for the low temperature oxidative dehydrogenation of ethane to ethylene , 2015 .

[118]  Yi Cheng,et al.  A self-redox phase-pure M1 MoVNbTeOx/CeO2nanocomposite as a highly active catalyst on oxidative dehydrogenation of ethane , 2015 .

[119]  M. Hedhili,et al.  A high-throughput reactor system for optimization of Mo–V–Nb mixed oxide catalyst composition in ethane ODH , 2015 .

[120]  Cheng Yanhu,et al.  Oxidative dehydrogenation of ethane with CO2 over Cr supported on submicron ZSM-5 zeolite , 2015 .

[121]  Yi Cheng,et al.  Performance of phase-pure M1 MoVNbTeOx catalysts by hydrothermal synthesis with different post-treatments for the oxidative dehydrogenation of ethane , 2015 .

[122]  Mohammad Reza Rahimpour,et al.  Recent advances in reactors for low-temperature Fischer-Tropsch synthesis: process intensification perspective , 2015 .

[123]  M. Omidkhah,et al.  Phenomenological modeling and analysis of gas transport in polyimide membranes for propylene/propane separation , 2015 .

[124]  A. Lohi,et al.  A comparative thermodynamic analysis and experimental studies on hydrogen synthesis by supercritical water gasification of glucose , 2015, Clean Technologies and Environmental Policy.

[125]  D. Anjum,et al.  Green synthesis of Ni-Nb oxide catalysts for low-temperature oxidative dehydrogenation of ethane. , 2015, ChemSusChem.

[126]  H. Metiu,et al.  Molten LiCl Layer Supported on MgO: Its Possible Role in Enhancing the Oxidative Dehydrogenation of Ethane , 2015 .

[127]  Avtar S. Matharu,et al.  The importance of elemental sustainability and critical element recovery , 2015 .

[128]  K. Wilson,et al.  Facile route to conformal hydrotalcite coatings over complex architectures: a hierarchically ordered nanoporous base catalyst for FAME production , 2015 .

[129]  A. Lemonidou,et al.  A study by electrical conductivity measurements of the semiconductive and redox properties of Nb-doped NiO catalysts in correlation with the oxidative dehydrogenation of ethane. , 2015, Physical chemistry chemical physics : PCCP.

[130]  C. H. Bartholomew,et al.  Heterogeneous Catalyst Deactivation and Regeneration: A Review , 2015 .

[131]  A. Lemonidou,et al.  On ethane ODH mechanism and nature of active sites over NiO-based catalysts via isotopic labeling and methanol sorption studies , 2015 .

[132]  Xinbin Ma,et al.  Selective oxidation of methanol to dimethoxymethane on V2O5–MoO3/γ-Al2O3 catalysts , 2014 .

[133]  G. Tonetto,et al.  Ni–Nb mixed oxides: One-pot synthesis and catalytic activity for oxidative dehydrogenation of ethane , 2014 .

[134]  C. Castillo-Araiza,et al.  Kinetic modeling of the oxidative dehydrogenation of ethane to ethylene over a MoVTeNbO catalytic system , 2014 .

[135]  R. Schloegl,et al.  Critical Literature Review of the Kinetics for the Oxidative Dehydrogenation of Propane over Well-Defined Supported Vanadium Oxide Catalysts , 2014 .

[136]  A. V. van Veen,et al.  Oxidative dehydrogenation of ethane on dynamically rearranging supported chloride catalysts. , 2014, Journal of the American Chemical Society.

[137]  B. Weckhuysen,et al.  Catalytic dehydrogenation of light alkanes on metals and metal oxides. , 2014, Chemical reviews.

[138]  P. Concepción,et al.  Promoted NiO Catalysts for the Oxidative Dehydrogenation of Ethane , 2014, Topics in Catalysis.

[139]  J. Millet,et al.  Influence of the Content and Distribution of Vanadium in the M1 Phase of the MoVTe(Sb)NbO Catalysts on their Catalytic Properties in Light Alkanes Oxidation , 2014, Topics in Catalysis.

[140]  Haibo Zhu,et al.  Metal oxides modified NiO catalysts for oxidative dehydrogenation of ethane to ethylene , 2014 .

[141]  Valerie Dupont,et al.  Hydrogen production from simple alkanes and oxygenated hydrocarbons over ceria–zirconia supported catalysts: Review , 2014 .

[142]  J. Nieto,et al.  Chemical, Structural, and Morphological Changes of a MoVTeNb Catalyst during Oxidative Dehydrogenation of Ethane , 2014 .

[143]  S. Ishikawa,et al.  Heptagonal channel micropore of orthorhombic Mo3VOx as catalysis field for the selective oxidation of ethane , 2014 .

[144]  J. Nieto,et al.  Oxidative dehydrogenation of ethane: A study over the structure and robustness of Ni–W–O catalysts , 2014 .

[145]  A. Lemonidou,et al.  Study by electrical conductivity measurements of semiconductive and redox properties of M-doped NiO (M = Li, Mg, Al, Ga, Ti, Nb) catalysts for the oxidative dehydrogenation of ethane. , 2014, Physical chemistry chemical physics : PCCP.

[146]  A. Lemonidou,et al.  A study of Ni–Al–O mixed oxides as catalysts for the oxidative conversion of ethane to ethylene , 2014 .

[147]  R. Quintana-Solórzano,et al.  Kinetic Study of Oxidative Dehydrogenation of Ethane over MoVTeNb Mixed-Oxide Catalyst , 2014 .

[148]  Samrand Saeidi,et al.  Progress in Reactors for High-Temperature Fischer–Tropsch Process: Determination Place of Intensifier Reactor Perspective , 2014 .

[149]  H. Metiu,et al.  Ethane Activation by Nb-Doped NiO , 2013 .

[150]  J. Lercher,et al.  Oxidative Dehydrogenation of Ethane: Common Principles and Mechanistic Aspects , 2013 .

[151]  K. P. Jong,et al.  Catalysts for Production of Lower Olefins from Synthesis Gas: A Review , 2013 .

[152]  O. Safonova,et al.  Redox State Dynamics at the Surface of MoVTe(Sb)NbO M1 Phase in Selective Oxidation of Light Alkanes , 2013, Topics in Catalysis.

[153]  J. Rodríguez,et al.  Fundamental studies of well-defined surfaces of mixed-metal oxides: special properties of MO(x)/TiO2(110) {M = V, Ru, Ce, or W}. , 2013, Chemical reviews.

[154]  Paco Laveille,et al.  A high-throughput study of the redox properties of Nb-Ni oxide catalysts by low temperature CO oxidation: Implications in ethane ODH , 2013 .

[155]  Mohammad. M. Hossain,et al.  Kinetic Modeling of Ethane Oxidative Dehydrogenation over VOx/Al2O3 Catalyst in a Fluidized-Bed Riser Simulator , 2013 .

[156]  P. S. Prasad,et al.  Selective oxidative dehydrogenation of ethane over MoO3/V2O5–Al2O3 catalysts: Heteropolymolybdate as a precursor for MoO3 , 2013 .

[157]  L. Gutierrez,et al.  Synthesis of Ni/Al2O3 and Ni–Co/Al2O3 coatings onto AISI 314 foams and their catalytic application for the oxidative dehydrogenation of ethane , 2013 .

[158]  K. Nowiǹska,et al.  Oxydehydrogenation of C2–C4 hydrocarbons over Fe-ZSM-5 zeolites with N2O as an oxidant , 2013 .

[159]  Mohammad. M. Hossain,et al.  VOx/c-Al2O3 catalyst for oxidative dehydrogenation of ethane to ethylene: Desorption kinetics and catalytic activity , 2013 .

[160]  S. Ishikawa,et al.  An orthorhombic Mo3VOx catalyst most active for oxidative dehydrogenation of ethane among related complex metal oxides , 2013 .

[161]  A. Lemonidou,et al.  Investigation of engineering aspects in ethane ODH over highly selective Ni0.85Nb0.15Ox catalyst , 2012 .

[162]  P. Concepción,et al.  Selective oxidative dehydrogenation of ethane over SnO2-promoted NiO catalysts , 2012 .

[163]  Mohd Bismillah Ansari,et al.  Carbon dioxide utilization as a soft oxidant and promoter in catalysis , 2012 .

[164]  A. Lemonidou,et al.  Unraveling the contribution of structural phases in Ni–Nb–O mixed oxides in ethane oxidative dehydrogenation , 2012 .

[165]  C. Pham‐Huu,et al.  Catalytic performance of MoVTeNbO catalyst supported on SiC foam in oxidative dehydrogenation of ethane and ammoxidation of propane , 2012 .

[166]  Zhonglai Wang,et al.  A novel BaCl2–TiO2–SnO2 catalyst for the oxidative dehydrogenation of ethane , 2012 .

[167]  K. Routray,et al.  Catalysis Science of Bulk Mixed Oxides , 2012 .

[168]  J. Millet,et al.  Optimizing the efficiency of MoVTeNbO catalysts for ethane oxidative dehydrogenation to ethylene , 2012 .

[169]  H. Metiu,et al.  Chemistry of Lewis Acid–Base Pairs on Oxide Surfaces , 2012 .

[170]  Yiming He,et al.  Preparation and characterization of Ni–Zr–O nanoparticles and its catalytic behavior for ethane oxidative dehydrogenation , 2012 .

[171]  G. Xiao,et al.  Coking- and Sintering-Resistant Palladium Catalysts Achieved Through Atomic Layer Deposition , 2012, Science.

[172]  F. Dorado,et al.  Simultaneous production of H2 and C2 hydrocarbons by gas phase electrocatalysis , 2012 .

[173]  P. Concepción,et al.  Oxidative dehydrogenation of ethane over NiO–CeO2 mixed oxides catalysts , 2012 .

[174]  Miao Sun,et al.  Nb effect in the nickel oxide-catalyzed low-temperature oxidative dehydrogenation of ethane , 2012 .

[175]  J. M. Serra,et al.  Optimization of ODHE membrane reactor based on mixed ionic electronic conductor using soft computing techniques , 2011 .

[176]  G. Hutchings,et al.  Controlling vanadium phosphate catalyst precursor morphology by adding alkane solvents in the reduction step of VOPO4·2H2O to VOHPO4·0.5H2O , 2011 .

[177]  J. M. Serra,et al.  High Ethylene Production through Oxidative Dehydrogenation of Ethane Membrane Reactors Based on Fast Oxygen‐Ion Conductors , 2011 .

[178]  R. Bulánek,et al.  Activity of the Ni–Al Mixed Oxides Prepared from Hydrotalcite-Like Precursors in the Oxidative Dehydrogenation of Ethane and Propane , 2011 .

[179]  M. Chi,et al.  Novel Pt/Mg(In)(Al)O catalysts for ethane and propane dehydrogenation , 2011 .

[180]  A. Baiker,et al.  Selective Conversion of Ethane to Ethene via Oxidative Dehydrogenation Over Ca-doped ThO2 Using CO2 as Oxidant , 2011 .

[181]  S. Najari,et al.  Dynamics of intraparticle desorption and chemical reaction in fixed-beds using inert core spherical particles , 2011 .

[182]  M. W. Roberts,et al.  Oxygen transient states in catalytic oxidation at metal surfaces , 2011 .

[183]  M. Baik,et al.  Room temperature dehydrogenation of ethane to ethylene. , 2011, Journal of the American Chemical Society.

[184]  C. Leclerc,et al.  Support Effects on the Oxidative Dehydrogenation of Ethane to Ethylene over Platinum Catalysts , 2011 .

[185]  D. Borio,et al.  Reactor Designs for Ethylene Production via Ethane Oxidative Dehydrogenation: Comparison of Performance , 2011 .

[186]  E. Kondratenko,et al.  Investigation of the electrical and catalytic properties of materials with Csx(Mo,Nb)5O14 composition , 2011 .

[187]  S. Loridant,et al.  Ni-Nb-O catalysts for ethane oxidative dehydrogenation , 2010 .

[188]  A. Lemonidou,et al.  Oxidative dehydrogenation of ethane to ethylene in a membrane reactor: A theoretical study , 2010 .

[189]  G. Russo,et al.  Olefins production by catalytic partial oxidation of ethane and propane over Pt/LaMnO3 catalyst , 2010 .

[190]  F. Cavani.  Catalytic selective oxidation: The forefront in the challenge for a more sustainable chemical industry , 2010 .

[191]  Huixin Wan,et al.  Oxidative dehydrogenation of ethane to ethene over a superbase supported LiCl system , 2010 .

[192]  M. Chi,et al.  Synthesis and characterization of a new catalyst Pt/Mg(Ga)(Al)O for alkane dehydrogenation , 2010 .

[193]  V. Galvita,et al.  Catalyst performance of novel Pt/Mg(Ga)(Al)O catalysts for alkane dehydrogenation , 2010 .

[194]  K. Poeppelmeier,et al.  Oxidative dehydrogenation of ethane with oxygen catalyzed by K–Y zeolite supported first-row transition metals , 2010 .

[195]  V. Galvita,et al.  Ethane dehydrogenation on Pt/Mg(Al)O and PtSn/Mg(Al)O catalysts , 2010 .

[196]  Jingli Luo,et al.  Y-doped BaCeO3−δ nanopowders as proton-conducting electrolyte materials for ethane fuel cells to co-generate ethylene and electricity , 2010 .

[197]  S. F. Håkonsen,et al.  Ethene production by oxidative dehydrogenation of ethane at short contact times over Pt-Sn coated monoliths , 2010 .

[198]  A. Lemonidou,et al.  Ni-Me-O mixed metal oxides for the effective oxidative dehydrogenation of ethane to ethylene - Effect of promoting metal Me , 2010 .

[199]  T. Kardash,et al.  M5O14-like V–Mo–Nb oxide catalysts: Structure and catalytic performance , 2010 .

[200]  Mohammad. M. Hossain,et al.  Kinetics and mechanism of partial oxidation of ethane to ethylene and acetic acid over MoV type catalysts , 2010 .

[201]  C. Copéret.  C-H bond activation and organometallic intermediates on isolated metal centers on oxide surfaces. , 2010, Chemical reviews.

[202]  M. V. Ganduglia-Pirovano,et al.  Role of ceria in oxidative dehydrogenation on supported vanadia catalysts. , 2010, Journal of the American Chemical Society.

[203]  Kentaro Nakamura,et al.  Oxidative dehydrogenation of ethane over NiO-loaded high surface area ZrO2 catalysts , 2010 .

[204]  Jingli Luo,et al.  Fabrication of bi-layered proton conducting membrane for hydrocarbon solid oxide fuel cell reactors , 2010 .

[205]  Changwei Hu,et al.  Na2WO4/Mn/SiO2 catalyst for oxidative dehydrogenation of ethane using CO2 as oxidant , 2009 .

[206]  N. Bahlawane,et al.  Catalytic oxidation of hydrocarbons over Co3O4 catalyst prepared by CVD , 2009 .

[207]  Xin Zhang.  Hydrothermal synthesis and catalytic performance of high-surface-area mesoporous nanocrystallite MgAl2O4 as catalyst support , 2009 .

[208]  N. Y. Usachev,et al.  Oxidative processing of light alkanes: State-of-the-art and prospects , 2009 .

[209]  H. Wan,et al.  Oxidative Dehydrogenation of Ethane to Ethylene over Mesoporous Ni-Based Catalysts , 2009 .

[210]  L. Čapek,et al.  V(V) species in supported catalysts: Analysis and performance in oxidative dehydrogenation of ethane , 2009 .

[211]  S. Deng,et al.  Oxidative Dehydrogenation of Ethane to Ethylene with CO2 over Fe-Cr/ZrO2 Catalysts , 2009 .

[212]  K. Poeppelmeier,et al.  Oxidative dehydrogenation (ODH) of ethane with O2 as oxidant on selected transition metal-loaded zeolites , 2009 .

[213]  F. Cavani,et al.  Sustainability in catalytic oxidation: an alternative approach or a structural evolution? , 2009, ChemSusChem.

[214]  U. Ozkan,et al.  Oxygen and Nitrous Oxide as Oxidants: Implications for Ethane Oxidative Dehydrogenation over Silica−Titania-Supported Molybdenum , 2009 .

[215]  J. Nieto,et al.  Selective oxidation of ethane: Developing an orthorhombic phase in Mo―V―X (X = Nb, Sb, Te) mixed oxides , 2009 .

[216]  E. Bordes-Richard,et al.  MoOx-based catalysts for the oxidative dehydrogenation (ODH) of ethane to ethylene: Influence of vanadium and phosphorus on physicochemical and catalytic properties , 2009 .

[217]  P. Concepción,et al.  Supported Ni–W–O Mixed Oxides as Selective Catalysts for the Oxidative Dehydrogenation of Ethane , 2009 .

[218]  L. Kustov,et al.  Interaction of vanadium containing catalysts with microwaves and their activation in oxidative dehydrogenation of ethane , 2009 .

[219]  Weiming Hua,et al.  Dehydrogenation of ethane to ethylene over a highly efficient Ga2O3/HZSM-5 catalyst in the presence of CO2 , 2009 .

[220]  A. Lemonidou,et al.  Study of a multitubular fixed-bed reactor for ethylene production via ethane oxidative dehydrogenation , 2008 .

[221]  Shengfu Ji,et al.  Oxidative Dehydrogenation of Ethane with CO 2 over Novel Cr/SBA-15/Al 2 O 3 /FeCrAl Monolithic Catalysts , 2008 .

[222]  U. Olsbye,et al.  Kinetic and Isotopic Study of Ethane Dehydrogenation over a Semicommercial Pt,Sn/Mg(Al)O Catalyst , 2008 .

[223]  R. Bulánek,et al.  Oxidative dehydrogenation of ethane over vanadium supported on mesoporous materials of M41S family , 2008 .

[224]  N. R. Shiju,et al.  The role of surface basal planes of layered mixed metal oxides in selective transformation of lower alkanes: propane ammoxidation over surface ab planes of Mo-V-Te-Nb-O M1 phase. , 2008, Journal of the American Chemical Society.

[225]  G. Russo,et al.  Optimization of Ethylene Production via Catalytic Partial Oxidation of Ethane on Pt–LaMnO3 Catalyst , 2008 .

[226]  Zhi-Pan Liu,et al.  Oxidative Dehydrogenation of Ethane over V2O5 (001): A Periodic Density Functional Theory Study , 2008 .

[227]  Bin Yang,et al.  Multi-scale modeling of microstructured reactors for the oxidative dehydrogenation of ethane to ethylene , 2008 .

[228]  J. Sauer,et al.  Oxidative conversion of C1–C3 alkanes by vanadium oxide catalysts. DFT results and their accuracy† , 2008 .

[229]  P. Concepción,et al.  Selective oxidation of propane and ethane on diluted Mo-V-Nb-Te mixed-oxide catalysts , 2007 .

[230]  F. Cavani,et al.  Oxidative dehydrogenation of ethane and propane : How far from commercial implementation? , 2007 .

[231]  T. Dogu,et al.  Oxidative Dehydrogenation of Ethane over Chromium−Vanadium Mixed Oxide and Chromium Oxide Catalysts , 2007 .

[232]  T. Müller,et al.  Kinetics and mechanism of the oxidative dehydrogenation of ethane over Li/Dy/Mg/O/(Cl) mixed oxide catalysts , 2007 .

[233]  E. Bordes-Richard,et al.  Oxidative dehydrogenation of ethane to ethene on alumina-supported molybdenum-based catalysts modified by vanadium and phosphorus , 2007 .

[234]  M. V. Ganduglia-Pirovano,et al.  Oxygen vacancies in transition metal and rare earth oxides: Current state of understanding and remaining challenges , 2007 .

[235]  A. Lemonidou,et al.  HRTEM characterization of the nanostructural features formed in highly active Ni–Nb–O catalysts for ethane ODH , 2007 .

[236]  G. Deo,et al.  Steady state kinetic parameters of bulk V2O5 for ethane and propane oxidation reactions , 2007 .

[237]  J. Lercher,et al.  Oxidative dehydrogenation of ethane over Dy2O3/MgO supported LiCl containing eutectic chloride catalysts , 2007 .

[238]  Bo-Qing Xu,et al.  Oxidative dehydrogenation of ethane over Co–BaCO3 catalysts using CO2 as oxidant: effects of Co promoter , 2007 .

[239]  J. Sauer,et al.  Oxidative dehydrogenation of propane by monomeric vanadium oxide sites on silica support , 2007 .

[240]  S. F. Håkonsen,et al.  Oxidative dehydrogenation of ethane on Pt–Sn impregnated monoliths , 2007 .

[241]  R. Schlögl,et al.  In situ XPS investigation of Pt(Sn)/Mg(Al)O catalysts during ethane dehydrogenation experiments , 2007 .

[242]  Kentaro Nakamura,et al.  Oxidative dehydrogenation of ethane to ethylene over NiO loaded on high surface area MgO , 2006 .

[243]  J. Fierro,et al.  Oxidative dehydrogenation of ethane to ethylene over alumina-supported vanadium oxide catalysts: Relationship between molecular structures and chemical reactivity , 2006 .

[244]  J. Nieto.  The selective oxidative activation of light alkanes. From supported vanadia to multicomponent bulk V-containing catalysts , 2006 .

[245]  S. Oyama,et al.  Oxidative dehydrogenation of ethane over Cr/ZSM-5 catalysts using CO2 as an oxidant. , 2006, The journal of physical chemistry. B.

[246]  T. García,et al.  Molybdenum–vanadium supported on mesoporous alumina catalysts for the oxidative dehydrogenation of ethane , 2006 .

[247]  Xiaolai Wang,et al.  Oxidative dehydrogenation of ethane to ethylene by carbon dioxide over Cr/TS-1 catalysts , 2006 .

[248]  Wenning Wang,et al.  Periodic density functional theory study of propane oxidative dehydrogenation over V2O5(001) surface. , 2006, Journal of the American Chemical Society.

[249]  M. Lemos,et al.  Activation of C2–C4 alkanes over acid and bifunctional zeolite catalysts , 2006 .

[250]  B. Grzybowska,et al.  Effect of additives on properties of V2O5/SiO2 and V2O5/MgO catalysts: I. Oxidative dehydrogenation of propane and ethane , 2006 .

[251]  R. Grabowski.  Kinetics of Oxidative Dehydrogenation of C2‐C3 Alkanes on Oxide Catalysts , 2006 .

[252]  M. Kacimi,et al.  Cobalt speciation in cobalt oxide-apatite materials: structure–properties relationship in catalytic oxidative dehydrogenation of ethane and butan-2-ol conversion , 2006 .

[253]  M. Sinev.  Free radicals as intermediates in catalytic oxidation of light alkanes: new opportunities , 2006 .

[254]  Ejm Emiel Hensen,et al.  Chemistry of N2O decomposition on active sites with different nature : Effect of high-temperature treatment of Fe/ZSM-5 , 2006 .

[255]  Suttichai Assabumrungrat,et al.  Catalytic steam reforming of ethane and propane over CeO2-doped Ni/Al2O3 at SOFC temperature: Improvement of resistance toward carbon formation by the redox property of doping CeO2 , 2006 .

[256]  P. Concepción,et al.  Selective oxidative dehydrogenation of ethane over MoVSbO mixed oxide catalysts , 2006 .

[257]  Mark E. Davis,et al.  Partially reduced heteropolyanions for the oxidative dehydrogenation of ethane to ethylene and acetic acid at atmospheric pressure , 2005 .

[258]  R. Grabowski,et al.  Kinetics of oxidative dehydrogenation of propane and ethane on VOx/SiO2 pure and with potassium additive , 2005 .

[259]  B. Weckhuysen,et al.  Mechanistic Insight in the Ethane Dehydrogenation Reaction over Cr/Al2O3 Catalysts , 2005 .

[260]  J. Iqbal,et al.  Recent advances in transition metal catalyzed oxidation of organic substrates with molecular oxygen. , 2005, Chemical reviews.

[261]  A. Lemonidou,et al.  Oxidative dehydrogenation of ethane and propane over vanadia and molybdena supported catalysts , 2005 .

[262]  F. Pinzari,et al.  Vanadium-metal(IV)phosphates as catalysts for the oxidative dehydrogenation of ethane , 2005 .

[263]  J. Lange,et al.  Oxycracking of hydrocarbons: chemistry, technology and economic potential , 2005 .

[264]  K. Wilson,et al.  Investigation of Ni-based alumina-supported catalysts for the oxidative dehydrogenation of ethane to ethylene: structural characterization and reactivity studies , 2005 .

[265]  Xin Xu,et al.  Mechanisms of methane activation and transformation on molybdenum oxide based catalysts. , 2005, Journal of the American Chemical Society.

[266]  V. C. Corberán.  Novel approaches for the improvement of selectivity in the oxidative activation of light alkanes , 2005 .

[267]  V. Choudhary,et al.  Oxidative conversion of ethane to ethylene over supported SrO-promoted Er2O3 catalyst , 2004 .

[268]  A. Holmen,et al.  Oxidative dehydrogenation of ethane and propane at short contact time , 2004 .

[269]  M. Sierka,et al.  Catalytic dehydrogenation of ethane over mononuclear Cr(III) surface sites on silica. part I. C—H activation by σ-bond metathesis† , 2004 .

[270]  M. Bañares,et al.  Structure–activity relationships in alumina-supported molybdena–vanadia catalysts for propane oxidative dehydrogenation , 2004 .

[271]  Alexis T. Bell,et al.  Oxidative dehydrogenation of propane over vanadia-based catalysts supported on high-surface-area mesoporous MgAl2O4 , 2004 .

[272]  L. Madeira,et al.  Nickel Molybdate Catalysts and Their Use in the Selective Oxidation of Hydrocarbons , 2004 .

[273]  M. Kacimi,et al.  Cobalt-exchanged hydroxyapatite catalysts: Magnetic studies, spectroscopic investigations, performance in 2-butanol and ethane oxidative dehydrogenations , 2004 .

[274]  L. Lisi,et al.  Effect of the support on the surface composition of vanadium phosphate catalysts in the oxidative dehydrogenation of ethane , 2004 .

[275]  L. Lisi,et al.  An XPS study of titania-supported vanadyl phosphate catalysts for the oxidative dehydrogenation of ethane , 2004 .

[276]  J. Nieto,et al.  Selective oxidative dehydrogenation of ethane on MoVTeNbO mixed metal oxide catalysts , 2004 .

[277]  F. Pinzari,et al.  Effect of the preparation technique on the catalytic performances of TiO2 supported vanadium phosphate in the oxidative dehydrogenation of ethane , 2004 .

[278]  P. Concepción,et al.  Oxidative dehydrogenation of ethane on Te-containing MoVNbO catalysts , 2004 .

[279]  F. Donsì,et al.  Catalyst investigation for applications of oxidative dehydrogenation of ethane in short contact time reactors , 2004 .

[280]  A. Lemonidou,et al.  Role of preparation parameters on the structure–selectivity properties of MoO3/Al2O3 catalysts for the oxidative dehydrogenation of ethane , 2004 .

[281]  A. Kaddouri.  CH bond activation in the presence or absence of oxygen or nitrous oxide , 2004 .

[282]  Shaobin Wang,et al.  Catalytic Conversion of Alkanes to Olefins by Carbon Dioxide Oxidative Dehydrogenation-A Review , 2004 .

[283]  E. Ruckenstein,et al.  Noncatalytic and catalytic conversion of ethane over VMg oxide catalysts prepared via solid reaction or mesoporous precursors , 2004 .

[284]  P. Concepción,et al.  Preparation, characterization and reactivity of V- and/or Co-containing AlPO-18 materials (VCoAPO-18) in the oxidative dehydrogenation of ethane , 2004 .

[285]  S. Guan,et al.  Discovery from combinatorial heterogeneous catalysis: A new class of catalyst for ethane oxidative dehydrogenation at low temperatures , 2003 .

[286]  T. Dogu,et al.  Oxidative dehydrogenation of ethane over a monolith coated by molybdenum-vanadium-niobium mixed-oxide catalyst , 2003 .

[287]  A. Holmen,et al.  Low-temperature oxidation reactions of ethane over a Pt/Al2O3 catalyst , 2003 .

[288]  L. Lisi,et al.  Vanadyl phosphate dihydrate supported on oxides for the catalytic conversion of ethane to ethylene , 2003 .

[289]  Khalid Karim,et al.  Oxidative dehydrogenation of ethane over movmnw oxide catalysts , 2003 .

[290]  J. Nieto,et al.  Oxidative dehydrogenation of ethane on promoted VPO catalysts , 2003 .

[291]  J. Lercher,et al.  Oxidative Dehydrogenation of Ethane Over Novel Li/Dy/Mg Mixed Oxides: Structure–Activity Study , 2003 .

[292]  Manfred Baerns,et al.  Fundamental insights into the oxidative dehydrogenation of ethane to ethylene over catalytic materials discovered by an evolutionary approach , 2003 .

[293]  R. T. Yang,et al.  Zeolites and Molecular Sieves , 2003 .

[294]  E. Ruckenstein,et al.  A Comparison of Catalytic Oxidative Dehydrogenation of Ethane Over Mixed V-Mg Oxides and Over Those Prepared via a Mesoporous V-Mg-O Pathway , 2003 .

[295]  A. Lemonidou,et al.  Surface Properties and Reactivity of Al2O3-Supported MoO3 Catalysts in Ethane Oxidative Dehydrogenation , 2003 .

[296]  M. Massucci,et al.  Alumina-supported vanadyl phosphates catalysts for the oxidative dehydrogenation of ethane: an XPS characterisation , 2003 .

[297]  T. Ando,et al.  The Role of Chemisorbed Oxygen on Diamond Surfaces for the Dehydrogenation of Ethane in the Presence of Carbon Dioxide , 2003 .

[298]  Z. Sobalík,et al.  Redox catalysis over metallo-zeolites Contribution to environmental catalysis , 2003 .

[299]  A. Martínez-Arias,et al.  Mo–V–Nb mixed oxides as catalysts in the selective oxidation of ethane , 2003 .

[300]  Yi Jing,et al.  Support effects on the catalytic behavior of NiO/Al2O3 for oxidative dehydrogenation of ethane to ethylene , 2003 .

[301]  G. Russo,et al.  Evaluating the Catalytic Performances of SAPO-34 Catalysts for the Oxidative Dehydrogenation of Ethane , 2003 .

[302]  R. Grasselli,et al.  Fundamental Principles of Selective Heterogeneous Oxidation Catalysis , 2002 .

[303]  B. Grzybowska-Świerkosz.  Effect of Additives on the Physicochemical and Catalytic Properties of Oxide Catalysts in Selective Oxidation Reactions , 2002 .

[304]  P. Ciambelli,et al.  VOPO4⋅2H2O and Fe(H2O)x(VO)1-xPO4⋅2H2O Supported on TiO2 as Catalysts for Oxidative Dehydrogenation of Ethane , 2002 .

[305]  W. Ueda,et al.  Hydrothermal Synthesis of Mo-Based Oxide Catalysts and Selective Oxidation of Alkanes , 2002 .

[306]  R. Bulánek,et al.  Oxidative dehydrogenation and ammoxidation of ethane and propane over pentasil ring Co-zeolites , 2002 .

[307]  P. Botella,et al.  The selective oxidative dehydrogenation of ethane over hydrothermally synthesised MoVTeNb catalysts. , 2002, Chemical communications.

[308]  S. Al-Khowaiter,et al.  RECENT ADVANCES AND FUTURE ASPECTS IN THE LOW-TEMPERATURE CONVERSION OF SATURATED HYDROCARBONS , 2002 .

[309]  F. Donsì,et al.  Oxidative Dehydrogenation of Ethane over a Perovskite-Based Monolithic Reactor , 2002 .

[310]  Haihui Wang,et al.  High selectivity of oxidative dehydrogenation of ethane to ethylene in an oxygen permeable membrane reactor. , 2002, Chemical communications.

[311]  G. Russo,et al.  Acid SAPO-34 Catalysts for Oxidative Dehydrogenation of Ethane , 2002 .

[312]  K. Murata,et al.  High-performance Cr/H-ZSM-5 catalysts for oxidative dehydrogenation of ethane to ethylene with CO2 as an oxidant , 2002 .

[313]  Zhongmin Liu,et al.  Crystallization and Si incorporation mechanisms of SAPO-34 , 2002 .

[314]  M. Argyle,et al.  Ethane oxidative dehydrogenation pathways on vanadium oxide catalysts , 2002 .

[315]  M. Baerns,et al.  A comparative study on non-catalytic and catalytic oxidative dehydrogenation of ethane to ethylene , 2002 .

[316]  G. Russo,et al.  Oxidative dehydrogenation of ethane on γ-Al2O3 supported vanadyl and iron vanadyl phosphates: Physico-chemical characterisation and catalytic activity , 2002 .

[317]  Alexis T. Bell,et al.  Oxidative Dehydrogenation of Propane over Vanadia–Magnesia Catalysts Prepared by Thermolysis of OV(OtBu)3 in the Presence of Nanocrystalline MgO , 2002 .

[318]  C. Au,et al.  Ethane Oxidative Dehydrogenation over Halogenated Bi2Sr2CaCu2O8-δ Catalysts , 2002 .

[319]  David Linke,et al.  Catalytic Partial Oxidation of Ethane to Acetic Acid over Mo1V0.25Nb0.12Pd0.0005Ox: II. Kinetic Modelling , 2002 .

[320]  J. Rabo,et al.  Early discoveries in zeolite chemistry and catalysis at Union Carbide, and follow-up in industrial catalysis , 2001 .

[321]  P. Concepción,et al.  Novel synthesis of a vanadium–cobalt aluminophosphate molecular sieve of AEI structure (VCoAPO-18) and its catalytic behaviour for the ethane oxidation , 2001 .

[322]  P. R. Pujadó,et al.  Dehydrogenation and oxydehydrogenation of paraffins to olefins , 2001 .

[323]  W. Ueda,et al.  Hydrothermal synthesis of novel crystalline Mo-V-M-O (M = Al, Ga, Fe) mixed oxide in the presence of triethylammonium chloride and their catalytic performance for selective ethane oxidation , 2001 .

[324]  F. Rey,et al.  Vanadium Oxide Supported on Mesoporous MCM-41 as Selective Catalysts in the Oxidative Dehydrogenation of Alkanes , 2001 .

[325]  L. Lisi,et al.  XPS characterisation of iron-modified vanadyl phosphate catalysts , 2001 .

[326]  Qinghong Zhang,et al.  Vanadium-Containing MCM-41 for Partial Oxidation of Lower Alkanes , 2001 .

[327]  M. Kacimi,et al.  Titania-Supported Cobalt and Cobalt–Phosphorus Catalysts: Characterization and Performances in Ethane Oxidative Dehydrogenation , 2001 .

[328]  C. Au,et al.  Halo-oxide ACuO2−δXσ (A=Sr0.63Ca0.27, X=F, Cl) catalysts active and durable for ethane selective oxidation to ethene , 2001 .

[329]  R. Grasselli.  Genesis of site isolation and phase cooperation in selective oxidation catalysis , 2001 .

[330]  A. Lemonidou,et al.  Oxidative dehydrogenation and cracking of ethane and propane over LiDyMg mixed oxides , 2001 .

[331]  W. Ueda,et al.  Catalytic oxidative activation of light alkanes over Mo–V-based oxides having controlled surface , 2001 .

[332]  A. Solbes,et al.  Nanostructured ceria-based catalysts for oxydehydrogenation of ethane with CO2 , 2001 .

[333]  P. Forzatti,et al.  High-Temperature and Short-Contact-Time Oxidative Dehydrogenation of Ethane in the Presence of Pt/Al2O3 and BaMnAl11O19 Catalysts , 2001 .

[334]  C. Au,et al.  Halide-doped perovskite-type AMn1−xCuxO3−δ (A = La0.8Ba0.2) catalysts for ethane-selective oxidation to ethene , 2001 .

[335]  Shaobin Wang,et al.  Effect of promoters on catalytic performance of Cr/SiO2 catalysts in oxidative dehydrogenation of ethane with carbon dioxide , 2001 .

[336]  M. Kacimi,et al.  Oxidative dehydrogenation of ethane and propane over magnesium–cobalt phosphates CoxMg3−x(PO4)2 , 2001 .

[337]  L. Lisi,et al.  Comparative study of catalytic behaviour of bulk-like and highly dispersed supported vanadyl orthophosphate catalysts in the oxidative dehydrogenation of ethane , 2001 .

[338]  N. Mizuno,et al.  Iron as an effective additive for enhancement of catalytic performance of cesium hydrogen salt of molybdophosphoric acid for selective oxidation of isobutane, propane, and ethane under oxygen-rich and -poor conditions and the catalyst design , 2001 .

[339]  Shaobin Wang,et al.  Selective oxidation of ethane and propane over sulfated zirconia-supported nickel oxide catalysts , 2001 .

[340]  P. Forzatti,et al.  Oxidative dehydrogenation of light paraffins in novel short contact time reactors. Experimental and theoretical investigation , 2001 .

[341]  M. Baerns,et al.  Autothermal Oxidative Dehydrogenation of Ethane to Ethylene Using SrxLa1.0Nd1.0Oy Catalysts as Ignitors , 2001 .

[342]  P. Concepción,et al.  On the nature of V and Mg ions in V, Mg-containing AlPO4-5 catalysts , 2000 .

[343]  M. Allendorf,et al.  Understanding Homogeneous and Heterogeneous Contributions to the Platinum-Catalyzed Partial Oxidation of Ethane in a Short-Contact-Time Reactor , 2000 .

[344]  C. Au,et al.  A comparison of nanoscale and large-size BaCl2-modified Er2O3 catalysts for the selective oxidation of ethane to ethylene , 2000 .

[345]  G. Russo,et al.  TiO2 supported vanadyl phosphate as catalyst for oxidative dehydrogenation of ethane to ethylene , 2000 .

[346]  Manfred Baerns,et al.  Ethylene and propene by oxidative dehydrogenation of ethane and propane: ‘Performance of rare-earth oxide-based catalysts and development of redox-type catalytic materials by combinatorial methods’ , 2000 .

[347]  W. Ueda,et al.  Selective oxidation of light alkanes over hydrothermally synthesized Mo-V-M-O (M=Al, Ga, Bi, Sb, and Te) oxide catalysts , 2000 .

[348]  P. Ruiz,et al.  Physico-chemical properties of V-Sb-oxide systems and their catalytic behaviour in oxidative dehydrogenation of light paraffins , 2000 .

[349]  G. Russo,et al.  Comparison of behaviour of rare earth containing catalysts in the oxidative dehydrogenation of ethane , 2000 .

[350]  Yide Xu,et al.  Selective oxidehydrogenation of ethane with CO2 over CeO2-based catalysts , 2000 .

[351]  B. Delmon,et al.  New results on the oxidative dehydrogenation of ethane to ethylene promoting catalytic performance of Mo-V- and Ni-V-oxide by alpha-Sb2O4 , 2000 .

[352]  C. Au,et al.  Raman spectroscopic and EPR investigations of oxygen species on SrCl2-promoted Ln2O3 (Ln=Sm and Nd) catalysts for ethane-selective oxidation to ethene , 2000 .

[353]  C. Au,et al.  Halogenated La1.6Sr.04CuO4 catalysts active for ethane selective oxidation to ethene , 2000 .

[354]  C. Au,et al.  YBa2Cu3O7−δXσ (X=F and CI): Highly Active and Durable Catalysts for the Selective Oxidation of Ethane to Ethene , 2000 .

[355]  T. Nenoff,et al.  Oxidation reactions of ethane over Ba–Ce–O based perovskites , 2000 .

[356]  J. Weitkamp.  Zeolites and catalysis , 2000 .

[357]  V. Choudhary,et al.  Coupling of exothermic and endothermic reactions in oxidative conversion of ethane to ethylene over alkaline earth promoted La2O3 catalysts in presence of limited O2 , 2000 .

[358]  Ioannis P. Androulakis,et al.  The Contribution of Gas-Phase Reactions in the Pt-Catalyzed Conversion of Ethane-Oxygen Mixtures , 2000 .

[359]  Shaobin Wang,et al.  Dehydrogenation of ethane with carbon dioxide over supported chromium oxide catalysts , 2000 .

[360]  A. Jiménez-lópez,et al.  Oxidative dehydrogenation of ethane on Cr, mixed Al/Cr and mixed Ga/Cr oxide pillared zirconium phosphate materials , 2000 .

[361]  P. Zavalij,et al.  Structural chemistry of vanadium oxides with open frameworks. , 1999, Acta crystallographica. Section B, Structural science.

[362]  L. Schmidt,et al.  High selectivities to ethylene by partial oxidation of ethane , 1999, Science.

[363]  F. Cavani,et al.  Selective oxidation of light alkanes: interaction between the catalyst and the gas phase on different classes of catalytic materials , 1999 .

[364]  M. Menéndez,et al.  Oxidative Dehydrogenation of Alkanes over V-based Catalysts: Influence of Redox Properties on Catalytic Performance , 1999 .

[365]  M. Bañares.  Supported metal oxide and other catalysts for ethane conversion: a review , 1999 .

[366]  B. Weckhuysen,et al.  Alkane dehydrogenation over supported chromium oxide catalysts , 1999 .

[367]  R. Grasselli.  Advances and future trends in selective oxidation and ammoxidation catalysis , 1999 .

[368]  Shaobin Wang,et al.  Excellent performance of lithium doped sulfated zirconia in oxidative dehydrogenation of ethane , 1999 .

[369]  M. Kacimi,et al.  Oxidative dehydrogenation of ethane over Cr/TiO2 modified by phosphorus , 1998 .

[370]  M. Baerns,et al.  Simple chemical processes based on low molecular-mass alkanes as chemical feedstocks , 1998 .

[371]  Toshimitsu Suzuki,et al.  Dehydrogenation of ethane over gallium oxide in the presence of carbon dioxide , 1998 .

[372]  T. Blasco,et al.  Oxidative dyhydrogenation of short chain alkanes on supported vanadium oxide catalysts , 1997 .

[373]  F. Cavani,et al.  Some aspects that affect the selective oxidation of paraffins , 1997 .

[374]  B. Gates,et al.  Activation of ethane in the presence of solid acids: Sulfated zirconia, iron- and manganese-promoted sulfated zirconia, and zeolites , 1997 .

[375]  W. Ueda,et al.  Highly selective oxidative dehydrogenation of ethane to ethene over layered complex metal chloride oxide catalysts , 1997 .

[376]  Y. Schuurman,et al.  Low temperature oxidative dehydrogenation of ethane over catalysts based on group VIII metals , 1997 .

[377]  F. Cavani,et al.  Key Aspects of Catalyst Design for the Selective Oxidation of Paraffins , 1996 .

[378]  A. Auroux,et al.  Active Sites of V2O5/γ-Al2O3Catalysts in the Oxidative Dehydrogenation of Ethane , 1996 .

[379]  A. Corma,et al.  Selective oxidation of hydrocarbons on V- and/or Co-containing aluminophosphate (MeAPO-5) using molecular oxygen , 1996 .

[380]  P. Concepción,et al.  On the influence of the acid-base character of catalysts on the oxidative dehydrogenation of alkanes , 1996 .

[381]  J. Moffat,et al.  Partial oxidation of ethane on silica-supported 12-molybdophosphoric acid in the presence of tetrachloromethane , 1996 .

[382]  R. Burch,et al.  CH bond activation in hydrocarbon oxidation on solid catalysts , 1995 .

[383]  F. Cavani,et al.  The oxidative dehydrogenation of ethane and propane as an alternative way for the production of light olefins , 1995 .

[384]  J. Lunsford,et al.  The Effect of Chloride Ions on a Li+-MgO Catalyst for the Oxidative Dehydrogenation of Ethane , 1995 .

[385]  G. Martin,et al.  Low temperature oxidative dehydrogenation of ethane over Ni-based catalysts , 1994 .

[386]  K. Dooley,et al.  Stable Nickel-Containing Catalysts for the Oxidative Coupling of Methane , 1994 .

[387]  L. Schmidt,et al.  Ethylene formation by oxidative dehydrogenation of ethane over monoliths at very short contact times , 1993 .

[388]  J. Ross,et al.  The oxidative coupling of methane and the oxidative dehydrogenation of ethane over a niobium promoted lithium doped magnesium oxide catalyst , 1993 .

[389]  K. Seshan,et al.  Influence of preparation method on the performance of vanadia-niobia catalysts for the oxidative dehydrogenation of propane , 1993 .

[390]  G. Somorjai,et al.  Oxydehydrogenation of ethane over ZSM-5 zeolite catalysts: Effect of steam , 1993 .

[391]  M. Baerns,et al.  Role of surface acidity on vanadia/silica catalysts used in the oxidative dehydrogenation of ethane , 1992 .

[392]  F. Solymosi,et al.  Partial oxidation of ethane over silica-supported alkali metal molybdate catalysts , 1992 .

[393]  F. Solymosi,et al.  Oxidation of ethane over silica-supported alkali metal vanadate catalysts , 1991 .

[394]  G. Somorjai,et al.  Kinetics of ethane oxidation on vanadium oxide , 1990 .

[395]  H. Bosch,et al.  Selective oxidation of methane to ethane and ethylene over various oxide catalysts , 1987 .

[396]  J. Lunsford,et al.  Partial oxidation of ethane to ethylene and acetaldehyde over a supported molybdenum catalyst , 1985 .

[397]  J. Haber,et al.  Oxygen in Catalysis on Transition Metal Oxides , 1979 .

[398]  P. H. Kasai,et al.  The oxidative dehydrogenation of ethane over catalysts containing mixed oxides of molybdenum and vanadium , 1978 .

[399]  D. Mears,et al.  Tests for Transport Limitations in Experimental Catalytic Reactors , 1971 .

[400]  J. H. Jones,et al.  Oxidation and Oxidative Dehydrogenation of Ethane and Propane , 1969 .

[401]  G. K. Boreskov.  Forms of oxygen bonds on the surface of oxidation catalysts , 1966 .

[402]  R. Grasselli,et al.  A selectivity factor in vapor‐phase hydrocarbon oxidation catalysis , 1963 .