Effects of torrefaction process parameters on biomass feedstock upgrading

Abstract Biomass is a primary source of renewable carbon that can be utilized as a feedstock for biofuels or biochemicals production in order to achieve energy independence. The low bulk density, high moisture content, degradation during storage and low energy density of raw lignocellulosic biomass are all significant challenges in supplying agricultural residues as a cellulosic feedstock. Torrefaction is a thermochemical process conducted in the temperature range between 200 and 300 °C under an inert atmosphere which is currently being considered as a biomass pretreatment. Competitiveness and quality of biofuels and biochemicals may be significantly increased by incorporating torrefaction early in the production chain while further optimization of the process might enable its autothermal operation. In this study, torrefaction process parameters were investigated in order to improve biomass energy density and reduce its moisture content. The biomass of choice (corn stover) was torrefied at three moisture content levels (30%, 45% and 50%), three different temperatures (200, 250 and 300 °C), and three unique reaction times (10, 20 and 30 min). Solid, gaseous, and liquid products were analyzed, and the mass and energy balance of the reaction was quantified. An overall increase in energy density (2–19%) and decrease in mass and energy yield (3–45% and 1–35% respectively) was observed with the increase in process temperature. Mass and energy losses also increased with an increase in the initial biomass moisture content.

[1]  Victor R. Vasquez,et al.  Thermal pretreatment of lignocellulosic biomass , 2009 .

[2]  Jenny M. Jones,et al.  Torrefaction of reed canary grass, wheat straw and willow to enhance solid fuel qualities and combustion properties , 2008 .

[3]  Kj Krzysztof Ptasinski,et al.  Torrefaction of wood: Part 2. Analysis of products , 2006 .

[4]  Mj Mark Prins,et al.  Thermodynamic analysis of biomass gasification and torrefaction , 2005 .

[5]  A. Corma,et al.  Synthesis of transportation fuels from biomass: chemistry, catalysts, and engineering. , 2006, Chemical reviews.

[6]  Carl A Haroian,et al.  Energy Independence and Security Act of 2007 Lighting Mandate Analysis , 2012 .

[7]  P.C.A. Bergman,et al.  Torrefaction for biomass co-firing in existing coal-fired power stations BIOCOAL , 2005 .

[8]  M. Muthukumar,et al.  Optimization of mix proportions of mineral aggregates using Box Behnken design of experiments , 2003 .

[9]  J. Azevedo,et al.  Estimating the higher heating value of biomass fuels from basic analysis data , 2005 .

[10]  S. Salvador,et al.  Impact of torrefaction on syngas production from wood , 2009 .

[11]  D. G. Christian,et al.  Biomass for Renewable Energy, Fuels, and Chemicals , 2000 .

[12]  John Vogler Energy and Climate Policy , 2013 .

[13]  L. Matuana,et al.  Modeling and optimization of formaldehyde‐free wood composites using a Box‐Behnken design , 2006 .

[14]  D. Klass Biomass for Renewable Energy, Fuels, and Chemicals , 1998 .

[15]  Kj Krzysztof Ptasinski,et al.  Torrefaction of wood: Part 1. Weight loss kinetics , 2006 .

[16]  J. J. Pis,et al.  Influence of torrefaction on the grindability and reactivity of woody biomass , 2008 .

[17]  M. Dietenberger,et al.  Wood Products: Thermal Degradation and Fire , 2001 .