EFFECT OF CHEMICAL TREATMENT ON THE CONSTITUENTS AND TENSILE PROPERTIES OF OIL PALM LEAF FIBRE

The effect of chemical treatment on the constituents and tensile properties of oil palm leaf fiber was investigated. Oil palm leaves were cut and buried underground close to the stream, and were regularly wetted with water to ensure proper fermentation for 20 days. The fermented leaves were washed and sun dried. The dried oil palm leaf fibers obtained were mechanically treated with chemicals, while some were left as control (untreated). The fibers were then characterized in terms of their percentage constituents, and their tensile properties determined with Instron universal testing machine. The tensile properties studied were ultimate tensile strength (UTS), elongation at yield and at break, Young’s modulus of elasticity as well as resilience. The results show that chemical treatments enhanced the removal of lignin and hemicelluloses which are detrimental to the interfacial bond strength of composite produced from natural fibers, except the sample treated with alkaline peroxide. Tensile test results reveal that fiber sample treated sequentially with KOH, acetic acid, Nacl and Hcl produced the highest UTS, elongation at yield, elongation at break and resilience. This is attributed to the plasticizing effect of the chemical treatment. However, the untreated fiber sample exhibited the highest Young’s modulus of elasticity. This observation was attributed to the highly crystalline nature of unmodified cellulose.

[1]  K. Oksman,et al.  The influence of fibre microstructure on fibre breakage and mechanical properties of natural fibre reinforced polypropylene , 2009 .

[2]  M. Sain,et al.  Development and morphological characterization of wood pulp reinforced biocomposite fibers , 2009 .

[3]  A. Bessadok,et al.  Study of water sorption on modified Agave fibres , 2009 .

[4]  N. El-Tayeb Abrasive wear performance of untreated SCF reinforced polymer composite , 2008 .

[5]  M. Vignon,et al.  Morphological and structural study of seed pericarp of Opuntia ficus-indica prickly pear fruits , 2008 .

[6]  E. Frollini,et al.  Sisal fibers: surface chemical modification using reagent obtained from a renewable source; characterization of hemicellulose and lignin as model study. , 2007, Journal of agricultural and food chemistry.

[7]  E. Tronc,et al.  Blue agave fiber esterification for the reinforcement of thermoplastic composites , 2007 .

[8]  Manjusri Misra,et al.  Chopped glass and recycled newspaper as reinforcement fibers in injection molded poly(lactic acid) (PLA) composites: A comparative study , 2006 .

[9]  J. Kadla,et al.  Inorganic Reactions in Chlorine Dioxide Bleaching of Softwood Kraft Pulp , 2006 .

[10]  S. Grelier,et al.  Fiberboards Based on Sugarcane Bagasse Lignin and Fibers , 2006 .

[11]  Alfred C. Loos,et al.  Contributions of feather fibers and various cellulose fibers to the mechanical properties of polypropylene matrix composites , 2006 .

[12]  Kristiina Oksman,et al.  Mechanical Properties of Biodegradable Composites from Poly Lactic Acid (PLA) and Microcrystalline Cellulose (MCC) , 2005 .

[13]  L. Musa,et al.  Rice husk–polyester composites: The effect of chemical modification of rice husk on the mechanical and dimensional stability properties , 2005 .

[14]  E. Frollini,et al.  Thermoset phenolic matrices reinforced with unmodified and surface-grafted furfuryl alcohol sugar cane bagasse and curaua fibers: properties of fibers and composites. , 2005, Biomacromolecules.

[15]  J. Kadla,et al.  The role of non-phenolic lignin in chlorate-forming reactions during chlorine dioxide bleaching of softwood kraft pulp , 2005 .

[16]  L. Lucia,et al.  New Insights into Lignin Modification During Chlorine Dioxide Bleaching Sequences (I): Chlorine Dioxide Delignification , 2005 .

[17]  L. Lucia,et al.  New Insights into Lignin Modification During Chlorine Dioxide Bleaching Sequences (II): Modifications in Extraction (E) and Chlorine Dioxide Bleaching (D1) , 2005 .

[18]  N. Reddy,et al.  Biofibers from agricultural byproducts for industrial applications. , 2005, Trends in biotechnology.

[19]  E. Frollini,et al.  Sugar cane bagasse and curaua lignins oxidized by chlorine dioxide and reacted with furfuryl alcohol: characterization and stability , 2004 .

[20]  G. Jeronimidis,et al.  Wood pulp fiber reinforced melamine-formaldehyde composites , 2004 .

[21]  Yves Leterrier,et al.  Novel Pulp Fibre Reinforced Thermoplastic Composites , 2003 .

[22]  H. J. Woods Fibre Structure , 1964, Nature.