Structural characterization of N-containing activated carbon fibers prepared from a low softening point petroleum pitch and a melamine resin

The incorporation of heteroatoms like N in activated carbons is of interest to modify the surface chemistry of the materials and, then, to improve their behavior as catalyst or catalyst support. In this work, N-containing activated carbon fibers have been prepared using a petroleum pitch with a low softening point and an N-containing resin. The novelty of the preparation method is that it involves the steps used in the synthesis of activated carbon fibers, i.e. spinning, stabilization, carbonization and activation. The materials have been characterized with techniques such as XPS and UPS, which allows us to follow the changes in both the chemical state of N species and the valence band structure of the carbon samples during the preparation steps.

[1]  I. Mochida,et al.  Roles of Surface Oxygen Groups on Poly(acrylonitrile)-Based Active Carbon Fibers in SO2 Adsorption , 1994 .

[2]  F. Carrasco-Marín,et al.  Activated carbons as adsorbents of sulfur dioxide in flowing air. Effect of their pore texture and surface basicity , 1993 .

[3]  Timothy D. Burchell,et al.  Carbon materials for advanced technologies , 1999 .

[4]  I. C. Lewis Chemistry of carbonization , 1982 .

[5]  Freek Kapteijn,et al.  Evolution of nitrogen functionalities in carbonaceous materials during pyrolysis , 1995 .

[6]  R. Schlögl,et al.  Influence of crystalline perfection and surface species on the X-ray photoelectron spectra of natural and synthetic graphites , 1983 .

[7]  J. G. Fripiat,et al.  3,5,11,13-tetraazacycl[3.3.3]azine: theoretical (ab initio) and experimental (X-ray and ultraviolet photoelectron spectroscopy) studies of the electronic structure , 1984 .

[8]  Charles Q. Yang,et al.  Infrared spectroscopy studies of the petroleum pitch carbon fiber—I. The raw materials, the stabilization, and carbonization processes , 1993 .

[9]  U. Wild,et al.  Structural and chemical characterization of N-doped nanocarbons , 1998 .

[10]  H. V. Bekkum,et al.  Amination and ammoxidation of activated carbons , 1994 .

[11]  J. Lahaye The chemistry of carbon surfaces , 1998 .

[12]  J. D. Lopez-Gonzalez,et al.  Study of oxygen-containing groups in a series of graphite oxides: Physical and chemical characterization , 1995 .

[13]  K. Thomas,et al.  Nitrogen release in the gasification of carbons , 1994 .

[14]  J. Bimer Modified active carbons from precursors enriched with nitrogen functions: Sulfur removal capabilities , 1998 .

[15]  D. Cazorla-Amorós,et al.  Factors controling the SO2 removal by porous carbons: relevance of the SO2 oxidation step , 2000 .

[16]  Ferrer,et al.  Separation of the sp3 and sp2 components in the C1s photoemission spectra of amorphous carbon films. , 1996, Physical Review B (Condensed Matter).

[17]  D. Cazorla-Amorós,et al.  Methane storage in activated carbon fibres , 1997 .

[18]  J. Lahaye,et al.  Porous structure and surface chemistry of nitrogen containing carbons from polymers , 1999 .

[19]  Diego Cazorla-Amorós,et al.  Fibras de carbón: preparación y aplicaciones , 1998 .

[20]  P. Oelhafen,et al.  Thermally induced structural changes in amorphous carbon films observed with ultraviolet photoelectron spectroscopy , 1997 .

[21]  J. Boudou,et al.  Structural Characterization of Nitrogen-Enriched Coals , 1998 .

[22]  A. Buckley Nitrogen functionality in coals and coal-tar pitch determined by X-ray photoelectron spectroscopy , 1994 .

[23]  I. Mochida,et al.  Marked increase of sulfur dioxide removal ability of poly(acrylonitrile)-based active carbon fiber by heat treatment at elevated temperatures , 1992 .

[24]  A. B. Fuertes,et al.  Treatments to enhance the SO2 capture by activated carbon fibres , 1998 .

[25]  D. A. Shirley,et al.  X-ray photoemission studies of diamond, graphite, and glassy carbon valence bands , 1974 .

[26]  D. Cazorla-Amorós,et al.  Preparation of general purpose carbon fibers from coal tar pitches with low softening point , 1997 .

[27]  K. J. Hüttinger,et al.  Carbon fibers, filaments, and composites , 1990 .

[28]  A. Bianconi,et al.  Photoemission studies of graphite high-energy conduction-band and valence-band states using soft-x-ray synchrotron radiation excitation , 1977 .

[29]  Robert Schlögl,et al.  Enhancement of the catalytic activity of activated carbons in oxidation reactions by thermal treatment with ammonia or hydrogen cyanide and observation of a superoxide species as a possible intermediate , 1991 .

[30]  T. Kyotani,et al.  Analysis of the Reaction of Carbon with NO/N2O Using Ab Initio Molecular Orbital Theory , 1999 .

[31]  J. Watts,et al.  X-ray photoelectron spectroscopy, X-ray excited Auger electron spectroscopy and time-of-flight secondary ion mass spectroscopy characterization of carbon fibres activated by d.c. corona discharge at ambient pressure and temperature , 1997 .

[32]  J. P. Eberhart,et al.  Structural and chemical analysis of materials , 1991 .

[33]  S. N. Kumar,et al.  Electronic and structural characterization of electrochemically synthesized conducting polyaniline from XPS studies , 1990 .

[34]  H. Güntherodt,et al.  Electronic and atomic structure of evaporated carbon films , 1996 .

[35]  A. Zunger Self-consistent LCAO calculation of the electronic properties of graphite. I. The regular graphite lattice , 1978 .

[36]  F. Carrasco-Marín,et al.  Adsorption of SO2 in flowing air onto activated carbons from olive stones , 1992 .

[37]  F. Kapteijn,et al.  The development of nitrogen functionality in model chars during gasification in CO2 and O2 , 1999 .

[38]  T. Cataldi,et al.  Remarks on the surface characterization of carbon fibres , 1992 .

[39]  M. Yoshikawa,et al.  Oxidative removal of SO2 and recovery of H2SO4 over poly(acrylonitrile)-based active carbon fiber , 1994 .

[40]  M. L. Gorbaty,et al.  Thermal Chemistry of Nitrogen in Kerogen and Low-Rank Coal , 1999 .